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21.
Paola Cristina Cajas Daza Rodrigo Arbey Muñoz Meneses Ana Candida Martins Rodrigues Cosme Roberto Moreira da Silva 《Ceramics International》2018,44(12):13699-13705
Doped CeGdO and codoped CeGdOSmO compositions were synthesized, giving rise to nanoparticulate powders. Ionic conductivities at bulk and grain boundaries of the sintered samples were determined, exhibiting increased conductivity in the samaria-codoped samples. Scanning electron microscopy (SEM) showed a significant reduction in the grain size of samaria-codoped electrolytes. This reduced grain size of the codoped samples caused a reduction in Schottky barrier height, increasing oxygen vacancy concentration in the space-charge layer of the grain boundary and culminating in greater ionic conductivity in the boundary region. For the gadolinium doped samples, high resolution transmission electron microscopy images at grains showed the presence of large cluster of defects (nanodomains), hindering the movement of charge carriers and reducing ionic conductivity. However, the samaria-codoped system displayed better homogeneity at atomic level, resulting in reduced oxygen vacancy ordering and, consequently, smaller nanodomains and higher bulk (grain) conductivity. The reduced grain sizes and smaller nanodomains caused by codoping favor the ionic conductivity of ceria-based ceramics, doped with gadolinia and codoped with samaria. 相似文献
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Meza-Espinoza Libier de los Ángeles Vivar-Vera María de Lourdes García-Magaña María Sáyago-Ayerdi Sonia G. Chacón-López Alejandra Becerrea-Verdín Eduardo M. Montalvo-González Efigenia 《Food science and biotechnology》2018,27(2):509-517
Food Science and Biotechnology - The enzymatic activity and partial characterization of proteases from Bromelia karatas fruits were evaluated and compared with Bromelia pinguin proteases. The... 相似文献
25.
We demonstrate that alkali-halide salts, particularly potassium bromide, can reduce the photothermal emission (PTE) from single walled carbon nanotubes (SWNT). PTE is a prominent spectral feature in Raman spectroscopy when a near infrared laser is used to analyze a dark colored sample. We subsequently show that trapping salts inside SWNT and coating SWNT with the salt has a more pronounced impact on not only reducing PTE, but also enhancing the intensity of the Raman spectral features. The effect, which we have called nanotube enhanced Raman spectroscopy (NERS), has differences and similarities to the widely studied surface enhanced Raman spectroscopy (SERS). 相似文献
26.
Recently, preemption techniques have attracted considerable attention as a means to provide differentiated quality of service
in optical burst switching (OBS) networks. This paper is focused on the analysis of preemption probabilities for bursts within
the same priority class. As proposed by Vokkarane and Jue ((2003)* IEEE J Select Areas Commun 21(7): 1198–1209) an incoming
burst will preempt the burst in service, within the same priority class, if the residual length of the burst in service is
smaller than the incoming burst length. For a general case with wavelength conversion, the preemption probability of contending
bursts with a generic service distribution, not necessarily exponential, is analyzed. First, we show that the size distribution
for the preempting bursts is shifted to larger values, in comparison to the original burst size distribution. Second, we obtain
an upper and lower bound for the preemption probability. Finally, the asymptotic behavior of the OBS switch is analyzed showing
that preemption will always occur for a very large number of wavelengths. 相似文献
27.
Various influence diagnostics in Multiple Discriminant Analysis can be found in the literature. Almost all of them are based
on the overall probability of misclassification. Two case-deletion diagnostics which evaluate the effect of the omission on
the linear functions which determine Fisher’s Linear Discriminant Rule are proposed in this paper. Both measures are based
on the L
2-norm: The first diagnostic is calculated from the data set and the second diagnostic is calculated in the minimum hypercube
which covers it. 相似文献
28.
The hydrolysis and condensation reactions of γ-APS have been studied in different acid content aqueous solution by using Fourier
Transform infrared (FT-IR) spectroscopy. The hydrolysis of γ-APS under the studied conditions can be followed by the increase
of the ethanol band located at 882 cm−1 and the decrease of the band due to the ρ(CH3) of γ-APS molecules located at 959 cm−1. Hydrolysis reaction is faster by increasing both H2O and acid concentrations, and it is completed when 3 moles of H2O per mole of γ-APS are used. The increase of the vibrational band located at 1146 cm−1 shows that condensation of the hydrolysed γ-APS molecules take place forming linear chains in poorly cross-linked structures.
Besides, both 8-membered cyclic siloxane formations and poorly cross-linked structures are formed and increase as the water
and acid content are increased. On the other hand, highly connected cross-linked structures do not appear due to the steric
hindrance of the non-hydrolysable aminopropyl group. The silanol band shows that hydrolysis is faster than condensation except
for samples with the lowest H2O content. 相似文献
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Amanda Alliband Daniel W. Lenz Laura E. Stevenson Travis Whitmer Rex Cash Dennis Burns Sarah Hall William T.K. Stevenson 《Progress in Organic Coatings》2008
A model has been proposed to explain the failure of the original BMS10-39 epoxy paint on upper vertical surfaces in B-52 fuel tanks. The model involves interaction of the paint with DIEGME, a fuel system ice inhibitor (FSII) in jet fuel, that is distilled from the liquid fuel. In this communication, distillation experiments used to support the model are refined to better match the mass transfer of vapor from fuel in a B-52 fuel tank at close to room temperature. The interaction of these lower temperature distillates with the paint affirms the earlier model. On the basis of these experiments it is proposed that paint failure may be controlled or eliminated by reducing the level of DIEGME in the fuel. Proposed changes in military jet fuel composition are detailed. 相似文献