Low-temperature synthesis in vacuum of c-axis oriented ferroelectric YMnO3 thin films using alkoxy-derived precursors

Abstract

Hexagonal YMnO₃ thin films were prepared on Pt(111)/TiO_x/SiO₂/Si and Pt(111)/Al₂O₃(0001) substrates using alkoxy-derived precursor solutions. The films were prepared by spin coating the YMnO₃ precursor solutions and then, the films were calcined and crystallized via rapid thermal annealing in oxygen or vacuum ambient. The annealing conditions and substrates were critical for crystallization of ferroelectric YMnO₃ films. When annealed in vacuum, the films both on Pt(111)/TiO_x/SiO₂/Si and Pt(111)/Al₂O₃(0001) substrates crystallized to hexagonal YMnO₃ and the orientation depended on the substrates. The film on Pt(111)/Al₂O₃(0001) had c-axis orientation and the film on Pt(111)/TiO_x/SiO₂/Si had no preferred orientation. In addition, it was found that crystallization behavior, orientation and morphology of YMnO₃ films on Pt(111)/TiO_x/SiO₂/Si substrates depended on the annealing condition. The heat-treatment in vacuum at initial stage for crystallization affected the restraint of perovskite phase and formation of hexagonal phase. The following heat-treatment in oxygen promoted the c-axis orientation and grain growth. The optimum annealing procedure for crystallization of the c-axis oriented YMnO₃ films on Pt(111)/TiO_x/SiO₂/Si was addressed.     

Thermodynamic analysis of load-leveling hyper energy converting and utilization system

Load-leveling hyper energy converting and utilization system (LHECUS) is a hybrid cycle which utilizes ammonia–water mixture as the working fluid in a combined power generation and refrigeration cycle. The power generation cycle functions as a Kalina cycle and an absorption refrigeration cycle is combined with it as a bottoming cycle. LHECUS is designed to utilize the waste heat from industry to produce cooling and power simultaneously. The refrigeration effect can be either transported to end-use sectors by means of a solution transportation absorption chiller (STA) as solution concentration difference or stored for demand load leveling.     

Safety performance of the 4S reactor on the ATWS events – statistical estimation of uncertainty

4S reactor is a sodium-cooled fast reactor developed as a small-decentralized power supply. The name of “4S” in this reactor stands for Super-Safe, Small and Simple, and they show representative features of the reactor.

The purpose of the present work is to evaluate quantitatively the super-safety of 4S reactor, and the safety performance is analyzed with ARGO-3, which is a plant dynamics code of a sodium-cooled fast reactor.

In this evaluation, some events, such as Unprotected Loss of Flow (ULOF) and Unprotected Transient Overpower (UTOP), are selected as typical cases from various transients and accidents. After metrics concerned with safety design is defined for each event, it is evaluated with statistical methods whether each metric satisfies acceptance criteria in a given criteria level.

Result about ULOF is as follows. The coolant temperature in the nominal hottest assembly outlet, “T_c” is selected as metric, and the upper side value of 95% confidential section in T_c is below 900 °C that is acceptance criteria. Also in UTOP, it is shown that the fuel maximum temperature in the nominal hottest assembly, “T_f” satisfies acceptance criteria. This result shows that 4S reactor has margin for safety acceptance criteria.     

船用柴油机NOx等有害排放气体的评价及处理研究--燃料喷射系统对乳化燃料在船用柴油机上使用的影响及脱硝装置的适用性

对原试验用柴油机的燃料喷射系统进行了改造。改造后的燃料喷射系统不仅可降低 NOx 的排放 ,而且使高加水率乳化燃料的使用成为可能。但另一方面 ,在低负荷时 ,使用乳化燃料不但不能获得预期的降低 NOx 排放效果 ,反而使其它有害排放增加。所以 ,也对降低 NOx 排放方法之一的脱硝装置进行了探讨 ,对其在船用柴油机上的适用性进行了试验 ,并获得了较好的效果     

Review of advanced absorption cycles: performance improvement and temperature lift enhancement

The objective of this study is to propose and evaluate advanced absorption cycles for the coefficient of performance (COP) improvement and temperature lift enhancement applications. The characteristics of each cycle are assessed from the viewpoints of the ideal cycle COP and its applications. The advanced cycles for the COP improvement are categorized according to their heat recovery method: condensation heat recovery, absorption heat recovery, and condensation/absorption heat recovery. In H₂O–LiBr systems, the number of effects and the number of stages can be improved by adding a third or a fourth component to the solution pairs. The performance of NH₃–H₂O systems can be improved by internal heat recovery due to their thermal characteristics such as temperature gliding. NH₃–H₂O cycles can be combined with adsorption cycles and power generation cycles for waste heat utilization, performance improvement, panel heating and low temperature applications. The H₂O–LiBr cycle is better from the high COP viewpoints for the evaporation temperature over 0°C while the NH₃–H₂O cycle is better from the viewpoint of low temperature applications. This study suggests that the cycle performance would be significantly improved by combining the advanced H₂O–LiBr and NH₃–H₂O cycles.     

Analytical investigation of two different absorption modes: falling film and bubble types

The objectives of this paper are to analyze a combined heat and mass transfer for an ammonia–water absorption process, and to carry out the parametric analysis to evaluate the effects of important variables such as heat and mass transfer areas on the absorption rate for two different absorption modes — falling film and bubble modes. A plate heat exchanger with an offset strip fin (OSF) in the coolant side was used to design the falling film and the bubble absorber. It was found that the local absorption rate of the bubble mode was always higher than that of the falling film model leading to about 48.7% smaller size of the heat exchanger than the falling film mode. For the falling film absorption mode, mass transfer resistance was dominant in the liquid flow while both heat and mass transfer resistances were considerable in the vapor flow. For the bubble absorption mode, mass transfer resistance was dominant in the liquid flow while heat transfer resistance was dominant in the vapor region. Heat transfer coefficients had a more significant effect on the heat exchanger size (absorption rate) in the falling film mode than in the bubble mode, while mass transfer coefficients had a more significant effect in the bubble mode than in the falling film mode.     

Preparation of micron-scale monodisperse oil-in-water microspheres by microchannel emulsification

Micron-scale monodisperse oil-in-water (O/W) micropheres (MS) were prepared using a novel microchannel (MC) emulsification technique. The characteristics of the MS preparation and the O/W-MS prepared were studied. Soybean oil and medium-chain triacyglycerol (MCT) were used as the disprrsed phase, and physiological saline was used as the continuous phase. Silicon MC with 1 to 3μm-equivalent channel diameters were employed. A novel MC module was devised to easily recover the O/W-MS prepared. The effects of the channel shape on the behavior of MS formation, on the MS size, and on the distribution were investigated. An MC with a terrace at the MC outlet stably yielded micron-scale monodisperse O/W-MS; the MS had diameters of about 5 μm, and their coefficients of variation were below 9%. Monodisperse food-grade O/W-MS with diameters of about 4 μm could be obtained by using polyglycerol fatty acid ester as the surfactant. The size and size distribution of the recovered O/W-MS remained almost constant over 60 d, demonstrating their long-term stability.     

Lethal effect of the expression of a killer gene SMK1 in Saccharomyces cerevisiae

Expression of the SMK1 gene which encodes the yeast killer toxinSMKT is lethal in Saccharomyces cerevisiae. Effects of deletionand site-directed mutagenesis of SMK1 on the lethality and thesecretion of the gene products were examined. Deletion of theinterstitial     

A new model of DLA under high magnetic field

A new Monte Carlo model is introduced to describe diffusion-limited aggregation (DLA) with extra forces arising from Lorentz's and/or Coulomb forces. Furthermore, we simulate a behavior of multiparticle diffusive aggregation to examine the resultant pattern of crystal in electrochemical deposition. Different patterns grown under various external forces are produced by Monte Carlo simulations. In the present model, the basic movement of particles is a random walk, with different transition probabilities in different directions, which characterizes stochastically the effect of extra forces. In case of assuming a high magnetic field, pattern formations which are qualitatively different from the standard DLA model are observed and they are successfully compared with preexisting experiments (Mogi et al., 1991). The present numerical results of electrochemical deposition show that the generated patterns strongly depend on the force acting on ions and their concentration (Sawada et al., 1986).     

Effect of mixing ratio of anionic and nonionic emulsifiers on the kinetic behavior of methyl methacrylate emulsion polymerization

Emulsion polymerization of methyl methacrylate was carried out using a mixture of anionic emulsifier, sodium dodecyl sulfate (SDS) and nonionic emulsifier, poly(oxy ethylene) nonyl phenyl ether with an average of 40 oxy ethylene units per molecule (NP-40). The rate of polymerization and the number of polymer particles produced both increased with increasing the amount of NP-40 initially charged, when NP-40 was used as the sole emulsifier. Interestingly, however, both the rate of polymerization and the number of polymer particles produced was found to decrease, when the amount of NP-40 added to the fixed amount of SDS is increased in the mixed emulsifier. On the contrary, they both increased when the amount of SDS added to the fixed amount of NP-40 is increased in the mixed emulsifier. The mixed emulsifier did not affect the number of the radicals per polymer particle at a certain number of polymer particles, but affected the number of polymer particles, thus the rate of polymerization.