Continuous Flow Fabrication of Block Copolymer–Grafted Silica Micro‐Particles in Environmentally Friendly Water/Ethanol Media

Polymer‐grafted inorganic particles (PGIPs) are attractive building blocks for numerous chemical and material applications. Surface‐initiated controlled radical polymerization (SI‐CRP) is the most feasible method to fabricate PGIPs. However, a conventional in‐batch reaction still suffers from several disadvantages, including time‐consuming purification processes, low grafting efficiency, and possible gelation problems. Herein, a facile method is demonstrated to synthesize block copolymer–grafted inorganic particles, that is, poly(poly(ethylene glycol) methyl ether methacrylate) (PPEGMEMA)‐b‐poly(N‐isopropylacrylamide) (PNIPAM)–grafted silica micro‐particles using continuous flow chemistry in an environmentally friendly aqueous media. Immobilizing the chain transfer agent and subsequent SI‐CRP can be accomplished sequentially in a continuous flow system, avoiding multi‐step purification processes in between. The chain length (MW) of the grafted polymers is tunable by adjusting the flow time or monomer concentration, and the narrower molar mass dispersity (Р< 1.4) of the grafted polymers reveals the uniform polymer chains on the particles. Moreover, compared with the in‐batch reaction at the same condition, the continuous system also suppresses possible gelation problems.     

锂-二氧化碳电池阴极催化剂的研究进展

锂-二氧化碳电池通过捕获、转化二氧化碳为储能物质，既可以减少二氧化碳排放量又可以作为创新的储能装置，引起了研究者们的广泛关注。本文简单介绍了锂-二氧化碳电池的工作机理、发展历程和目前研究存在的难题，通过对研究工作的总结、电池性能的对比，将不同类型的催化剂进行了系统的分类和简单的概括，综述了催化剂的设计理念和研究现状，提出了催化剂目前存在的难题与挑战，并展望了催化剂未来的发展方向。本文主要针对锂-二氧化碳电池阴极催化剂的最新研究进展进行了详细的阐述，指出高效的阴极催化剂是促进锂-二氧化碳电池电化学反应动力学、降低充电平台和过电势的关键所在。     

Effects of malondialdehyde-induced protein oxidation on the structural characteristics of rice protein

Malondialdehyde (MDA) was selected to represent a secondary by-product of lipid peroxidation during rice ageing. This study aimed to investigate the effects of MDA modification on the structural characteristics of rice protein. The results showed that as MDA concentration increased, rice protein carbonyl and disulphide groups increased, but sulphydryl content decreased. The blue shift of maximum fluorescence peak, the decrease of rice protein intrinsic fluorescence intensity and the reduction of surface hydrophobicity indicated the formation of protein aggregates caused by MDA oxidative modification. The results of molecular weight distribution and particle size distribution showed that MDA modification resulted in the formation of soluble protein aggregates, and the decrease of rice protein solubility indicated that insoluble protein aggregates were formed. Results of protein electrophoresis showed that MDA modification contributed to rice protein aggregation via non-disulphide covalent bonds. The results showed that rice protein gradually aggregated with increasing MDA concentration.     

电动平衡重式叉车轮胎设计特点及发展趋势

介绍电动平衡重式叉车的市场发展趋势，并根据其使用工况特点，提出电动平衡重式叉车轮胎在规格选取、负荷能力及滚动阻力等方面的设计要求，并给出相应的技术设计、花纹设计及施工设计等方面的建议。指出电动平衡重式叉车轮胎的发展方向。     

基于6Li+CdTe的新型中子探测器的优化设计研究

面对~3He气体资源严重短缺的国际形势,2018年基于~6Li+CdTe新型中子探测器方案被提了出来,其具备热中子探测效率高、γ灵敏度低及可与~3He气体中子探测器相比拟的特点,有很好的应用前景。本文分析~6Li+CdTe中子探测器的结构和工作原理,采用MCNP6软件对~6Li+CdTe中子探测器进行物理建模并且对其物理性能、结构参数、中子慢化体设计等进行模拟计算,并就该探测器在特殊核材料监测系统中的应用开展了探索研究。结果显示:CdTe吸收层的最佳厚度为10μm;当6层~6Li+CdTe的中子探测单元叠加时,~6Li转化层的最佳厚度为60μm,此时热中子探测效率超过50%;探测系统的尺寸达到4 m×32 cm时,可以满足特殊核物质监测的要求。整个模拟研究获得了探测器最佳工作参数以及辐射监测系统设计方案,对特殊核材料在线中子监测装置的实验研究具有指导意义。     

气体裂变产物88Kr半衰期测量

为准确测定气体裂变产物⁸⁸Kr的半衰期，本工作从辐照铀靶中分离得到3个放化纯的⁸⁸Kr气体测量源。以⁸⁵Kr作内标监督源，¹³⁷Cs或⁵⁷Co作外标监督源，使用多个HPGe探测器分别采用单探测器位置接力法和双探测器位置接力法跟踪测量⁸⁸Kr 196.3 keV能量的特征γ射线，跟踪时间均在8个半衰期以上，以获得其半衰期数据。对3次独立测量数据用多种方法进行处理，最终得到⁸⁸Kr半衰期测定结果为（2.796±0.015） h。     

无人机在输电线路巡检中的多种应用

无人机技术目前的快速发展使得我们国家输电线路自身的巡检能力得到了持续的提升,基于此本文在对无人机技术给予认识的情况下,在了解了输电线路巡检过程中的使用优势之后,还总结了无人机技术在当前我国线路巡检过程中的应用路径以及应用方法;之后使用案例分析的方式分析了无人机技术在当前输电线路巡检过程中的应用方法。