An alternative model for positive shifts in shallow-marine carbonate δ13C and δ18O

Abstract Positive shifts in global seawater δ¹³C_DIC are related to changes in the ratio of organic relative to inorganic carbon burial in oceanic basins, whereas factors such as climatic cooling and the accumulation of polar ice are known to cause positive shifts in δ¹⁸O. Here, an alternative model is proposed for the formation of local positive isotope shifts in shallow-marine settings. The model involves geochemically altered platform-top water masses and the effects of early meteoric diagenesis on carbonate isotopic composition. Both mechanisms are active on modern (sub)tropical carbonate platforms and result in low carbonate δ¹³C and δ¹⁸O relative to typical oceanic values. During high-amplitude transgressive events, the impact of isotopically light meteoric fluids on the carbonate geochemistry is much reduced, and ¹³C-depleted platform-top water mixes with open oceanic water masses having higher isotope values. Both factors are recorded as a transient increase in carbonate ¹³C and ¹⁸O relative to low background values. These processes must be taken into consideration when interpreting the geochemical record of ancient epeiric seas.     

A crystal-chemical investigation of Cr substitution in muscovite by XANES spectroscopy

 This work introduces a novel procedure to fit the scattering features of XANES spectra. The procedure was applied and validated on a chromium-containing muscovite for which structural and crystal-chemical characterization is available from literature. The simulation, which involved clusters formed by up to 90 atoms, proved to be effective in representing the Cr local environment, even if the system is characterized by a very low metal content, as demonstrated by the extremely good correspondence with experimental data. Received: 23 May 2002 / Accepted: 6 November 2002     

On core-collapse supernovae in normal and in Seyfert galaxies

This paper estimates the relative frequency of different types of core-collapse supernovae, in terms of the ratio between the number of Type Ib–Ic and of Type II supernovae. We estimate independently for all normal and Seyfert galaxies whose radial velocity is ≤14 000 km s⁻¹, and which had at least one supernova event recorded in the Asiago catalogue from 1986 January to 2000 August. We find that the ratio is  ≈0.23±0.05  in normal galaxies. This value is consistent with constant star formation rate and with a Salpeter initial mass function and an average binary rate ≈50 per cent. On the contrary, Seyfert galaxies exceed the ratio in normal galaxies by a factor ≈4 at a confidence level ≳2 σ . A caveat is that the numbers for Seyferts are still small (six of Type Ib–Ic and six of Type II supernovae discovered as yet). Assumed to be real, this excess of Type Ib/c supernovae may indicate a burst of low-age star formation  ( τ ≲20 Myr)  , a high incidence of binary systems in the inner regions  ( r ≲0.4 R ₂₅)  of Seyfert galaxies, or a top-loaded mass function.     

GIS morphometric indicators for the analysis of sediment dynamics in mountain basins

Watershed management and headwater reconstruction programs require a reliable knowledge of sediment dynamics. Geographical Information Systems (GIS) provide the framework for the implementation of different complex techniques for the assessment of shallow landsliding and erosion processes in mountain basins. This paper presents some morphometric indicators aimed at erosion and sediment delivery analysis. The proposed indicators can be easily derived from medium to fine resolution Digital Elevation Models (DEM). Applications conducted in Eastern Italian Alps have shown the adequateness of the proposed approach to address erosion and sediment-related problems. The analysis considered the classification of sediment source areas with regard to their activity, the comparison between drainage basins having different morphological characteristics and the topographic control on sediment transport capacity, with a particular attention to the identification of channel reaches characterised by a low sediment transport capacity.     

A Mössbauer and FTIR study of synthetic amphiboles along the magnesioriebeckite – ferri-clinoholmquistite join

A series of amphiboles along the magnesioriebeckite—Na₂Mg₃Fe³⁺ ₂Si₈O₂₂(OH)₂– ferri-clinoholmquistite—Li₂Mg₃Fe³⁺ ₂Si₈O₂₂(OH)2 - join, defined by the ^BLi^B Na_–1 exchange vector, were hydrothermally synthesized at 700°C, 0.4 GPa, NNO + 1 redox conditions. Powder XRD and SEM-EDAX showed a very high (> 90%) amphibole yield for all samples. X-ray patterns were indexed in the C2/m space group; refined cell-parameters show a linear decrease of a and as a function of chemistry. IR spectra in the OH-stretching region show four main and rather sharp bands; these are assigned to Mg and Fe²⁺ at M(1,3), and indicate that the obtained amphiboles depart from the nominal octahedral composition (^M1,3Mg₃). The IR spectra also show that there is an increasing filling-up of the A-site for increasing Na in the system (increasing solid-solution toward, arfvedsonite). Mössbauer spectra show four well-defined quadrupole doublets which are assigned to Fe³⁺ at M2 and to Fe²⁺ at M1, M3 and M4, respectively. The Fe³⁺/Fe²⁺ content derived from fitted peak areas show variable Fe³⁺ concentration along the series. Mössbauer spectra also show a distinct alteration of ⁵⁷Fe hyperfine parameters with changing Na–Li at M4. The most evident variation is observed for the quadrupole splitting of Fe³⁺ at M2, which increases by 50% from ferri-clinoholmquistite to magnesio-riebeckite; this suggest that the M2 octahedron in ferri-clinoholmquistite is much closer to the ideal geometry than the M2 octahedron in magnesio-riebeckite. Mössbauer spectra show also a well-defined increase in the Fe²⁺ quadrupole splitting of the M1 and M3 octahedra, which is attributed to the Na–Li distribution at the B-sites.     

Coronal abundance of elements and a model of the quiet Sun from radio observations

It is shown that the combined use of radio observations of the quiet Sun and UV line intensities allows to compute the absolute coronal abundance of the elements. The abundances found by this method agree very well with the most recent determinations. A model of the transition region and corona in hydrostatic equilibrium is also presented. Similarities and differences with models based on UV observations are discussed.     

Elastic–plastic analysis of geotechnical problems by mathematical programming

A numerical technique, based on a mathematical programming algorithm, is presented for the solution of geotechnical problems where elastic-plastic material behaviour is considered. The proposed approach can be adopted for geotechnical media characterized by any suitable yield condition, accounting, if necessary, for workhardening behaviour. The loading process is subdivided into a series of steps applied to a finite element mesh with geometry and material properties constant along each step, but with possible changes between subsequent steps. As an application some typical geotechnical problems are analysed by means of the proposed algorithm and a comparison is made between the available in situ measurements and the numerical results.     

Seasonal changes and biochemical composition of the labile organic matter flux in the Cretan Sea

Downward fluxes of labile organic matter (lipids, proteins and carbohydrates) at 200 (trap A) and 1515 m depth (trap B), measured during a 12 months sediment trap experiment, are presented, together with estimates of the bacterial and cyanobacterial biomasses associated to the particles. The biochemical composition of the settling particles was determined in order to provide qualitative and quantitative information on the flux of readily available organic carbon supplying the deep-sea benthic communities of the Cretan Sea. Total mass flux and labile carbon fluxes were characterised by a clear seasonality. Higher labile organic fluxes were reported in trap B, indicating the presence of resuspended particles coming from lateral inputs. Particulate carbohydrates were the major component of the flux of labile compounds (on annual average about 66% of the total labile organic flux) followed by lipids (20%) and proteins (13%). The biopolymeric carbon flux was very low (on annual average 0.9 and 1.2 gC m⁻² y⁻¹, at trap A and B). Labile carbon accounted for most of the OC flux (on annual average 84% and 74% in trap A and B respectively). In trap A, highest carbohydrate and protein fluxes in April and September, corresponded to high faecal pellet fluxes. The qualitative composition of the organic fluxes indicated a strong protein depletion in trap B and a decrease of the bioavailability of the settling particles as a result of a higher degree of dilution with inorganic material. Quantity and quality of the food supply to the benthos displayed different temporal patterns. Bacterial biomass in the sediment traps (on average 122 and 229 μgC m⁻² d⁻¹ in trap A and B, respectively) was significantly correlated to the flux of labile organic carbon, and particularly to the protein and carbohydrate fluxes. Cyanobacterial flux (on average, 1.1 and 0.4 μgC m⁻² d⁻¹, in trap A and B, respectively) was significantly correlated with total mass and protein fluxes only in trap A. Bacterial carbon flux, equivalent to 84.2 and 156 mgC m⁻² y⁻¹, accounted for 5–6.5% of the labile carbon flux (in trap A and B respectively) and for 22–41% protein pool of the settling particles. These results suggest that in the Cretan Sea, bacteria attached to the settling particles represent a potential food source of primary importance for deep-sea benthic communities.