湖南锡田云英岩-石英脉型钨锡矿的形成时代及其 赋矿花岗岩锆石SHRIMP U-Pb 定年

[摘 要] 具超大型规模远景的湖南锡田钨锡多金属矿床是1999 年开始的新一轮国土资源大调查的重大发现之一。矿床产于锡田复式花岗岩体与碳酸盐岩接触带及岩体内部。矿床类型主要为矽卡岩型,其次为破碎带蚀变岩型和云英岩-石英脉型。采用石英流体包裹体Rb-Sr 法和锆石SHRIMP U-Pb法分别获得:云英岩-石英脉型钨锡矿形成年龄为153±12Ma(MSWD=0.80),其赋矿花岗岩形成年龄为147±3Ma(MSWD= 0.90),加权平均年龄为147郾0依3郾5 Ma(MSWD =0郾23),两者在误差范围内一致;并进一步证实,锡田钨锡多金属矿的主成矿期是燕山早期。     

粤北连平地区钨锡多金属矿床成矿时代研究

粤北连平地区钨锡多金属矿床类型主要为石英脉型.采用云母Ar-Ar法和石英包裹体Rb-Sr法.分别获得:锯板坑含钨锡石英脉中的云母Ar-Ar坪年龄为(139.2±1.5)Ma(等时线年龄为143.6±3.9 Ma,MSWD:0.30):鸡啼石含钨石英脉中石英包裹体Rb-Sr等时线年龄为(155.4±5.1)Ma(MSWD=2.1).结果表明该区存在燕山早期和燕山早晚过渡期两期钨锡多金属成矿作用,并且认为:(1)鸡啼石钨矿为南岭地区中生代大规模成岩成矿作用高峰期(150～160 Ma)的产物;(2)南岭地区140 Ma左右也有大型钨锡多金属矿的形成.这一成果为研究区域成矿规律,指导区域找矿提供了重要同位素年代学依据.     

广西珊瑚钨锡矿床成矿年代学研究及其地质意义

珊瑚钨锡矿床位于富贺钟钨锡多金属成矿集中区的中部,是南岭钨锡多金属成矿带内典型的热液石英脉型矿床之一。本文采用白云母~(40)Ar-~(39)Ar法和石英流体包裹体Rb-Sr法,对矿床V32号含矿石英脉进行精细年代学研究,获得石英脉中白云母~(40)Ar-~(39)Ar坪年龄为101.7±0.7 Ma(MSWD=0.34),正等时线年龄为102.0±1.0 Ma(MSWD=1.17);石英流体包裹体Rb-Sr等时线年龄为106.4±3.5 Ma(MSWD=0.83)。它们在误差范围内一致,是华南地区燕山晚期成岩成矿高峰期的产物。同时通过石英包裹体H-O同位素组成的初步分析,认为成矿流体属于"再平衡岩浆水",主要来自岩浆,在矿床深部可能存在隐伏花岗岩体。该成果对研究区域成矿规律,指导类似地区的找矿勘查工作具有重要意义。     

湖南东坡矿田金船塘、红旗岭锡多金属矿床Rb-Sr、Sm-Nd同位素年代学研究

与千里山岩体有密切时空联系的东坡矿田是我国主要钨锡多金属矿产资源基地之一。在前人对千里山复式岩体成岩时代和金船塘与千里山岩体第一期似斑状花岗岩侵入活动有关的成矿作用研究的基础上,笔者选择金船塘及红旗岭矿床含矿石英脉中的石英和金船塘矿床矽卡岩矿石中的单矿物,进行石英流体包裹体Rb-Sr和矽卡岩矿物(包括符山石和石榴石)Sm-Nd同位素年代学研究,得出金船塘及红旗岭矿床石英流体包裹体Rb-Sr等时线年龄分别为133.4±5.9 Ma(MSWD=1.3)和143.1±8.7 Ma(MSWD=47),金船塘矿床矽卡岩矿物Sm-Nd等时线年龄为141±11 Ma(MSWD=0.27)。同位素年代学研究表明金船塘矿床至少存在164 Ma±、133~141 Ma两期成矿作用,在测定误差范围内,它们分别与千里山岩体第一期似斑状花岗岩(152 Ma)和第二期等粒黑云母花岗岩(136~137Ma)的侵入活动有关,而红旗岭矿床的成矿作用与千里山岩体第二期岩浆侵入活动有关。     

广西都庞岭李贵福钨锡多金属矿Re-Os同位素定年研究

李贵福钨锡多金属矿赋存于都庞岭复式花岗岩体东部。矿床类型主要为云英岩-石英脉型。通过对矿石中辉钼矿Re-Os同位素测年,获得等时线年龄为(211.9±6.4)Ma(n=7,MSWD=4.1),模式年龄的加权平均值为(213.3±2.9)Ma(MSWD=4.0)。结果显示成矿作用发生在印支期,表明都庞岭地区存在早中生代钨锡多金属成矿事件。     

湘南红旗岭锡多金属矿床地质特征及Ar-Ar同位素年代学研究

红旗岭锡多金属矿床是湖南东坡矿田代表性的脉状矿床,亦是湖南省最大的脉状锡矿,并与同一断裂带上相邻的枞树板和南风坳等脉状铅锌银矿构成了一套Sn-W-Pb-Zn-Ag矿床组合。在已有研究的基础上,我们对该矿床进行了高精度白云母Ar-Ar测年,获得坪年龄为153.3±1.0Ma,相应的等时线年龄为153.6±1.5Ma(MSWD=0.55),反等时线年龄为153.5±1.5Ma(MSWD=2.1)。这些年龄数据明显早于相同矿石类型石英流体包裹体的Rb-Sr等时线年龄(143.1±8.7Ma)及相伴产出的花岗斑岩钾长石40Ar-39Ar年龄(144±3Ma),而与千里山岩体主体相锆石SHRIMPU-Pb年龄(155～151Ma)及与之相关的柿竹园矿床(151.0±3.5Ma)和金船塘矿床(158.8±6.6Ma)矽卡岩型矿床的Re-Os等时线年龄在误差范围内相一致,指示区内脉状矿床亦与千里山岩体存在密切的时空关系。综合已有的研究认为,高热花岗岩浆的高分异演化是区内多金属元素巨量堆积成矿的物质基础,不同的围岩性质及构造条件则可能制约了不同的矿化过程,从而形成不同的矿床组合。当围岩为泥盆系碳酸盐岩时,形成一套接触带矽卡岩-云英岩-大理岩型钨锡钼铋铅锌矿和远端脉状铅锌银矿床组合,而当围岩为震旦系碎屑岩时,沿构造通道(断裂带)发育一套脉状钨锡多金属矿和远端脉状铅锌银矿床组合。     

湖南瑶岗仙钨矿成岩成矿作用年代学研究

湖南瑶岗仙钨矿床位于南岭东西构造带中部,加里东隆起带与印支-燕山凹陷带的交汇部位。区内出露地层有寒武系、泥盆系、石炭系和侏罗系,其中寒武系和泥盆系为含矿的主要层位。矿体赋存于燕山早期花岗岩体内外接触带。笔者在前人对矿床的地质构造、岩石地球化学以及同位素年代学等方面研究的基础上,采用SHRIMP铀-铅、铷-锶等时线和铼-锇等时线定年方法,对瑶岗仙花岗岩体及赋存于岩体内外接触带的黑钨矿-石英脉进行精确定年,获得岩体锆石SHRIMP铀-铅年龄为(170.7±2.2)Ma(置信度95%,n=12,MSWD=1.7),产于岩体外接触带寒武系地层中的黑钨矿-石英脉年龄为(175.8±4.1)Ma(置信度95%,MSWD=0.88),产于岩体内接触带的黑钨矿-石英脉年龄为(156±3)Ma(置信度95%,MSWD=0.20),产于外接触带石英脉中的辉钼矿年龄为(170±5)Ma。测定结果表明,瑶岗仙钨矿床的形成至少经历了两个成矿期,分别对应于J1/J2过渡期与J2/J3过渡期。今后的深部找矿工作尤其是杨梅岭矿段深部应该注意寻找两个时期分别形成的石英脉型和矽卡岩型矿体。     

粤北两类钨矿的成矿时代——以棉土窝和禾尚田为例

粤北地区广泛分布着石英脉型钨锡多金属矿床,根据围岩的差异可分为两类:一类以南雄县棉土窝钨矿床为代表,该矿床以寒武系砂岩地层、中粗粒花岗岩为成矿岩体围岩,以细粒花岗岩为成矿岩体,锆石U-Pb法测得细粒花岗岩的成岩年龄为153.82±0.96 Ma和146.95±0.84 Ma,辉钼矿Re-Os等时线法测得矿床的成矿年龄为150.5±1.4 Ma,黑云母Ar-Ar等时线法测得成矿年龄为151.0±1.2 Ma,从而得出棉土窝钨矿床的成矿时代为晚侏罗世,同时由于前人测得中粗粒花岗岩的年龄为230±2.3 Ma,属印支期,证明了印支期花岗岩也可作为石英脉型钨矿的围岩;另一类石英脉型钨矿床以乐昌禾尚田为代表。该矿床以泥盆系灰岩为围岩,Ar-Ar法测得其成矿年龄为161.1±1.1 Ma,证明其成矿时代也为晚侏罗世。这两类实例证明了粤北地区钨矿床与晚侏罗世侵入岩关系密切,印支期花岗岩与泥盆系灰岩中也可赋矿,这对该地区寻找类似钨矿床有重要的指导意义。     

Genesis of the Maka Pb-Zn-W deposit in southeastern Yunnan" Constraints from sphalerite Rb-Sr dating,cassiterite U-Pb dating and in -situ S,Pb isotopes of sulfideSCIEI北大核心CSCD

马卡铅锌钨矿床地处云南省马关县与麻栗坡县的南温河交界处,位于燕山晚期老君山复式花岗岩体北缘。野外地质调查发现,该矿床主要发育矽卡岩型、石英脉型铅锌矿化和萤石石英脉型白钨矿化,但它们的形成机制仍缺乏系统研究。本文通过闪锌矿Rb-Sr、锡石原位U-Pb同位素定年和硫化物原位S、Pb同位素分析,厘定了马卡矿床不同类型铅锌矿化年龄,并探讨了其成矿物质来源及成因机制。矽卡岩型和石英脉型铅锌矿石中闪锌矿分别获得了88.9±1.9Ma(MSWD=4.5)和85.18±0.72Ma(MSWD=1.2)的Rb-Sr等时线年龄,同时获得石英脉型铅锌矿石中锡石LA-ICP-MS U-Pb年龄为84.3±4.7Ma(MSWD=0.66)。结果指示锌、锡矿化时代为晚白垩世,矽卡岩型和石英脉型铅锌矿化分别与该区广泛出露的老君山花岗岩(-90Ma)和花岗斑岩年龄(80-86Ma)一致。矿石硫化物原位硫同位素测试结果显示,δ34S值范围为2.53‰-9.65‰,均值为4.7‰,与老君山花岗岩中硫化物硫同位素组成(4.07‰)相似,表明硫主要来源于老君山花岗岩,少部分源自沉积地层;原位铅同位素组成特征也表明矿石铅主要源自老君山花岗岩。综合研究认为,老君山花岗岩体南北缘地区具有相似的成矿地质条件。马卡矿床的形成主要与燕山晚期老君山复式花岗岩体有关,可能经历了与花岗岩有关的矽卡岩型矿化和与花岗斑岩有关的热液充填、交代成矿过程。     

新疆伊吾琼河坝地区铜、金矿成矿时代及其找矿前景

文章采用高分辨率、高灵敏度离子探针(SHRIMP)和Rb-Sr等时线定年技术,对新疆伊吾琼河坝地区的云英山斑岩铜矿和淖毛湖北山金矿床的岩体和矿体进行了年代学研究,获得云英山斑岩铜矿区内斜长花岗斑岩体SHRIMP锆石U-Pb年龄为(411.7±7.1)Ma(95%置信度,MSWD=3.0),该矿床的含矿石英脉石英矿物Rb-Sr等时线年龄为(357±15)Ma(95%置信度,MSWD=0.16);淖毛湖北山金矿含矿石英脉中石英矿物Rb-Sr等时线年龄为(346±10)Ma(95%置信度,MSWD=0.19).测定结果显示,该区斑岩型铜矿和破碎带蚀变岩型金矿的形成时间为晚泥盆世-早石炭世,表明云英山式斑岩型铜金矿和淖毛湖式金矿成矿作用与泥盆纪-石炭纪汇聚阶段的火山-次火山岩浆活动有关,也意味着在琼河坝地区具有寻找与火山作用有关的铜、金多金属矿的潜力.     

Définition d'une limite multicritère ; stratigraphie du passage Campanien–Maastrichtien du site géologique de Tercis (Landes,SW France)Definition of a multi-criteria boundary; stratigraphy of the Campanian–Maastrichtian interval of the geological site at Tercis (Landes,SW France)

Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.     

Quaternary stresses revealed by calcite twinning inversion: insights from observations in the Savonnières underground quarry (eastern France)

Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ₁ roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003).     

HYDROGEOLOGY

正20141756 Chen Ruige(Mathematical College,China University of Geosciences,Beijing100083,China);Zhou Xun Numerical Simulation of Groundwater Level Fluctuation in a Coastal Confined Aquifer with Sloping Initial Groundwater Level Induced by the Tide(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(7),2013,p.1099-1104,6 illus.,16 refs.) Key words:confined water,groundwater level     

METAMORPHIC PETROLOGY

正20141408 Cai Jia(Institute of Geology,Chinese Academy of Geological Sciences,Beijing100037,China);Liu Fulai Petrogenesis and Metamorphic P-T Conditions of Garnet-Spinel-Biotitebearing Paragneiss in Danangou Area,Daqingshan-Wulashan Metamorphic Complex Belt(Acta Petrologica Sinica,ISSN1000-0569,CN11-1922/P,29(7),     

SERIALS

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GEOPHYSICAL EXPLORATION

正20142386An Guoying(China Aero Geophysical Survey and Remote Sensing Center for Land and Resources,Beijing 100083,China)Application of Satellite Remote Sensing in Regional Hydrogeological Investigation:Taking Cenozoic Strata in Wenquan Sheet(1∶250 000)of Karakoram Range as an Example(Geosci-     

QUATERNARY GEOLOGY & GEOMORPHOLOGY

正20141016An Chengbang(Key Laboratory of Western China’s Environmental Systems,Ministry of Education,Lanzhou University,Lanzhou 730000,China);Zhao Yongtao Lake Records during the Last Glacial Maximum from Xinjiang,NW China and Their Climatic Impli-     

PETROLEUM GEOLOGY

正20141538 Cao Qing(School of Earth Sciences and Engineering,Xi’an Petroleum University,Xi’an 710065,China);Zhao Jingzhou Characteristics and Significance of Fluid Inclusions from Majiagou Formation,Yichuan Huangling Area,Ordos Basin(Advances in Earth Science,ISSN1001-8166,CN62-1091/P,28(7),2013,p.819-828,7 illus.,3 tables,43 refs.)     

GEOCHEMISTRY

正20142002 Wei Hualing(Institute of Geophysical and Geochemical Exploration,Chinese Academy of Geological Sciences,Langfang065000,China);Zhou Guohua Element Content and Mineral Compositions in Different Sizes of Soil in Tongling Area,Anhui Province(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(11),2013,p.1861     

ENGINEERING GEOLOGY

正20141768 An Shaopeng(Institute of Rock and Soil Mechannics,Chinese Academy of Sciences,Wuhan 430071,China);Wei Lide Experimental Study on Mechanical Behavior of Xigeda Formation Siltstone and Structure Interface(Journal of Engineering Geology,ISSN1004-9665,CN11-3249/P,21(5),2013,p.702-708,9illus.,1 table,16 refs.)