Interaction of bentonite colloids with Cs, Eu, Th and U in presence of humic acid: A flow field-flow fractionation study

The interaction of Cs(I), Eu(III), Th(IV) and U(VI) with montmorillonite colloids was investigated in natural Grimsel Test Site groundwater over a 3 years period. The asymmetric flow field-flow fractionation combined with various detectors was applied to study size variations of colloids and to monitor colloid association of trace metals. The colloids suspended directly in the low ionic strength (I), slightly alkaline granitic groundwater (I = 10⁻³ mol/L, pH 9.6) showed a gradual agglomeration with a size distribution shift from initially 10-200 nm to 50-400 nm within over 3 years. The Ca²⁺ concentration of 2.1 × 10⁻⁴ mol/L in the ground water is believed to be responsible for the slow agglomeration due to Ca²⁺ ion exchange against Li⁺ and Na⁺ at the permanently charged basal clay planes. Furthermore, the Ca²⁺ concentration lies close to the critical coagulation concentration (CCC) of 10⁻³ mol L⁻¹ for clay colloids. Slow destabilization may delimit clay colloid migration in this specific groundwater over long time scales. Eu(III) and Th(IV) are found predominantly bound to clay colloids, while U(VI) prevails as the UO₂(OH)₃⁻ complex and Cs(I) remains mainly as aquo ion under our experimental conditions. Speciation calculations qualitatively represent the experimental data. A focus was set on the reversibility of metal ion-colloid binding. Addition of humic acid as a competing ligand induces rapid metal ion dissociation from clay colloids in the case of Eu(III) even after previous aging for about 3 years. Interestingly only partial dissociation occurs in the case of Th(IV). Experiments and calculations prove that the humate complexes dominate the speciation of all metal ions under given conditions. The partial irreversibility of clay bound Th(IV) is presently not understood but might play an important role for the colloid-mediated transport of polyvalent actinides over wide distances in natural groundwater.     

Astronomical Site Testing in Northwest of Argentina

We present the preliminary results of the astronomical site testing, which the group IATE of the OAC is developing in northwest of Argentine in collaboration with ESO and the Department of Astronomy of Cornell University. We show the results, which we have obtained from the analysis of GOES 8 satellite images in the 10.7 μm band, which allowed us to configurate a map of clear sky regions in an area between 23° and 28° S, and 66° 30′ and 69° W. We also comment logistical and tectonic aspects, and discuss next steps to follow in the research.     

Evaluation of hydrogeochemical processes and groundwater quality for suitability of drinking and irrigation purposes: a case study in the Aosta Valley region,Italy

The present study aims to discuss the hydrogeochemical processes in the Aosta Valley region and assess the quality of its groundwater for suitability of drinking and irrigation purposes. One hundred twenty-two samples were collected from the Aosta Valley region in the years 2007 and 2008 (61 per year), and analysed for pH, electrical conductivity, total dissolved solids (TDS), total hardness, major cations and anions. The pH of the samples in both years indicated a near-neutral to alkaline nature of the groundwater. The cation and anion chemistry showed the general ionic abundance as: Ca²⁺ > Mg²⁺ > Na⁺ > K⁺ and HCO₃ ^?>SO₄ ^2?>Cl^?>NO₃ ^?>F^? in both years. Ca²⁺-Mg²⁺-HCO₃ ^? and Ca²⁺-Mg²⁺-Cl^?-SO₄ ^2? were the dominant hydrogeochemical facies. The computed saturation indices demonstrated that the groundwater was supersaturated with respect to dolomite and calcite in both years. The groundwater chemistry of the study area was mainly controlled by the dissolution of carbonate, sulphate and silicate minerals, as well as ion exchange processes. A comparison of the groundwater quality in relation to drinking water standards showed that most of the water samples were suitable for drinking and domestic uses. The computed water quality index (WQI) values of the study area groundwater ranged from 24 to 84 in the year 2007 and from 22 to 82 in the year 2008, and all the location fell under the Excellent to Good category. Quality assessment for irrigation uses revealed that the groundwater was good to permissible quality for irrigation; however, locally higher salinity, residual sodium carbonate (RSC) and magnesium hazard (MH) restricted its suitability for irrigation at a few sites. These results will be useful in implementing future measures in groundwater resource management at regional and national level.     

Multi-technique monitoring of ocean tide loading in northern France

We have organised afield study of ocean tide loading in the northwestern part of France, where tidal amplitudes are known to be among the highest in the world. GPS and gravimetric techniques have already proved their capability to measure such weak and high-frequency signals. In this study, these classical observations are complemented with less usual techniques, such as tiltmeter and Satellite Laser Ranging (SLR) measurements. We present here the preliminary results for a common period of observations spanning from 12–19 May 2004. Additional measurements from the French Transportable Laser Ranging Station (FTLRS) were available during September and October 2004. Observation residuals are computed as the difference between the observed and the predicted time signals. We obtain small RMS residuals for GPS measurements (2.5/3.1/4.5 mm for the eastward, northward and upward components), for absolute and relative gravimetry (9 nm/s² and 13 nm/s²) and for tiltmeters (0.05 μrad for EW component). We also fit the amplitude of the main M2 tidal constituent to FTLRS observations and we find a value of 3.731 cm, which is comparable to the theoretical value.     

6. Environmental Context

On Earth, the Archaean aeon lasted from 4.0 to 2.5 Ga; it corresponds to a relatively stable period. Compared with today, internal Earth heat production was several times greater resulting in high geothermal flux that induced the genesis of rocks such as komatiites and TTG suites, which are no more generated on Earth since 2.5 Ga. Similarly, the details of plate tectonic modalities (plate size, plate motion rate, plate thickness, tectonic style, irregular crustal growth, etc...) were different of modern plate tectonics. Both atmosphere and ocean compositions have been progressively modified and the greater heat production favoured the development of hydrothermalism and therefore created niches potentially favourable for the development of some forms of life. Catastrophic events such as giant meteorite falls or world-sized glaciations drastically and suddenly changed the environment of Earth surface, thus being able to strongly affect development of life. Even if specialists still debate about the age of the oldest indubitable fossil trace of life, Archaean can be considered as having been extremely favourable for life development and diversification.