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一、前言酒瓶瓶口密封衬垫纸(下称衬垫纸)的研制任务系四川省轻工厅八二年轻工业科学研究计划下达的。八三年接转重庆市科委。主要目的是研制用复合纸代替目前螺纹口类酒瓶广泛采用的瓶口密封材料——内塞及胶套。这种复合纸具有良好的密封性能。使用方便,价格便宜等优点。国外,酒类的包装有桶装、罐装、坛装、瓶装及盒装等多种形式,封口材料也各异。但市场销售仍以瓶装为主,就瓶装而言,仍以螺纹口玻璃瓶为主。封口材料一般都使用密封衬垫。其特点是密封性能好,使用方便,重复开闭仍能保持密封。 相似文献
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目前塑料饮料瓶的封口结构,并不能保护瓶口螺纹部分的卫生,因为瓶口螺纹部分是非密封保护的。所有的瓶装饮料,只需轻轻拧开瓶盖即可畅饮。可是,你是否想过,有时候很可能就"祸从口入"。2010年6月,家住合肥的王女士在百盛超市内购买了康师傅茉莉清茶的瓶装饮料,打开后却发现瓶盖内壁 相似文献
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该研究探究聚对苯二甲酸乙二醇酯(polyethylene terephthalate, PET)饮料瓶和再生食品级再生聚对苯二甲酸乙二醇酯(regenerated polyethylene terephthalate, rPET)切片中锑迁移情况,及食品模拟液、温度对PET饮料瓶和rPET切片中锑迁移行为的影响。将PET饮料瓶和rPET切片样品在4%(体积分数)乙酸、10%(体积分数)和20%(体积分数)乙醇食品模拟液中完全浸泡,利用电感耦合等离子体质谱仪(inductively coupled plasma-mass spectrometry, ICP-MS)对PET饮料瓶和rPET切片中的锑进行定量分析。通过实验迁移量与迁移模型预测曲线拟合,分析不同食品模拟液和温度对迁移扩散系数的影响。结果表明,在60℃且达到迁移平衡时,rPET切片较PET饮料瓶中锑向不同食品模拟液中的迁移量均增加;对比3种食品模拟液,PET饮料瓶和rPET切片中锑向4%乙酸食品模拟液中扩散系数更高;在不同温度下,PET饮料瓶中锑向4%乙酸中迁移的实验测定值与迁移模型预测曲线拟合效果良好(拟合度达0.9以上),温... 相似文献
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<正>PET(聚脂)饮料瓶在中国发展仅有十多年的时间,而热灌装PET饮料瓶在中国的历史更短,仅为6年左右的时间,但发展势头之猛,超过大多数其他包装容器。众所周知,茶饮料、果汁饮料等是饮料发展的重点,其中大部分包装容器均是选用PET热灌装瓶,而且比例有不断增长的趋势。PET饮料瓶的一般生产过程为:注塑成瓶胚→ 相似文献
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The barrier effect of a silicon oxide (SiOx) coating on the inner surface of PET bottles, in terms of the ability to reduce the migration of post-consumer compounds from the PET bottle wall into food simulants (3% acetic acid and 10% ethanol), was investigated. The barrier effect was examined by artificially introducing model substances (surrogates) into the PET bottle wall to represent a worst-case scenario. Test bottles with three different spiking levels up to approximately 1000 mg kg(-1) per surrogate were blown and coated on the inner surface. The SiOx-coated bottles and the non-coated reference bottles were filled with food simulants. From the specific migration of the surrogates with different bottles wall concentrations, the maximum surrogate concentrations in the bottle wall corresponding to migration of 10 microg l(-1) were determined. It was shown that the SiOx coating layer is an efficient barrier to post-consumer compounds. The maximum bottle wall concentrations of the surrogates corresponding to migration of 10 microg l(-1) were in the range of 200 mg kg(-1) for toluene and approximately 900 mg kg(-1) for benzophenone. Consequently, the SiOx coating allows use of conventionally recycled post-consumer PET flakes (without a super-clean recycling process) for packaging aqueous and low alcoholic foodstuffs (under cold-fill conditions) and protects food from migration of unwanted contaminants from post-consumer PET. 相似文献
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《Food Reviews International》2013,29(4):271-283
To assess the role of the container material on the quality of olive oil, literature results concerning the analytical definition of the quality of oils stored in PET or glass bottles were critically reviewed. The performance of active and passive barrier PET containers may move towards that of glass bottles. The influence of storage conditions was also considered: the main factors affecting the sensory quality loss upon storage are light and the initial oil oxygen concentration, aside from the bottle material. Further research needs are anticipated since new active and passive barrier bottles indeed deserve further attention. 相似文献
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The ability of liquids to reduce oxygen permeation through low density polyethylene (LDPE), oriented polypropylene (OPP), polyethylene terepthalate (PET), and polyvinylidene chloride (PVTDC) films was mathematically modeled using a water/xanthan solution as a model medium. For low barrier films (LDPE and OPP), the medium substantially reduced oxygen permeation. In PET, an intermediate barrier, the medium produced a recognizable, but minor reductions in permeation. For the highest barrier (PVDC), the medium's influence on permeation was almost unidentifiable. The effect of the medium's oxygen solubility constant and diffusion coefficient on permeation was also examined. For all films, reduction in permeation became significant only after solubility and diffusion values fell below 40% of water values. 相似文献
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<正> 几年前,一系列玻璃啤酒瓶爆炸伤人事件发生后,啤酒行业一直在寻求更加安全的包装替代品,PET 包装随之走人人们的视线。现在,尽管 PET 瓶已经被几乎所有的饮料所接受,而啤酒界在采用PET 作为啤酒包装方面却是显得有些踌躇不前。其实,PET 包装在对啤酒品质、口 相似文献
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The permeation parameters of conventional PET films, films coated with SiOx and SiOx-coated films laminated to LDPE were determined for ethyl acetate using the permeation cell/gas chromatography method. Permeation to O2 and water vapour was also determined to monitor overall changes in the barrier properties of the experimental films. Coating of the PET film was achieved by a 'directed evaporation' method that increased the yield of the coating process from 30-35 to > 70%. It was shown that the SiOx coating increased the film barrier to ethyl acetate by approximately 20-30 times. Permeation values showed low reproducibility, indicating the need for further development and standardization of the 'directed evaporation' web-coating process. The barrier to oxygen and water vapour increased by 20-25 and 12-14 times respectively after coating. The web-coating speed did not seem to influence the barrier properties of the films. Permeation coefficients, diffusion coefficients and solubility coefficients were calculated for all samples. 相似文献
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PET表面镀氧化硅薄膜具有优良的阻隔性能,但没有热封性能。为了更好地将PET表面镀氧化硅薄膜应用到包装领域,需要将表面沉积氧化硅的PET薄膜与其他热封性能较好的薄膜进行复合,复合膜将具有更好的热封性能。采用实验和理论分析相结合的方法,分析了包装用表面镀氧化硅PET薄膜的热封强度影响因素。结果表明,薄膜间的复合强度和热封温度对热封强度影响最大。 相似文献
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Frank Welle Roland Franz 《Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment》2013,30(6):788-794
The barrier effect of a silicon oxide (SiO x ) coating on the inner surface of PET bottles, in terms of the ability to reduce the migration of post-consumer compounds from the PET bottle wall into food simulants (3% acetic acid and 10% ethanol), was investigated. The barrier effect was examined by artificially introducing model substances (surrogates) into the PET bottle wall to represent a worst-case scenario. Test bottles with three different spiking levels up to ~1000 mg kg?1 per surrogate were blown and coated on the inner surface. The SiO x -coated bottles and the non-coated reference bottles were filled with food simulants. From the specific migration of the surrogates with different bottles wall concentrations, the maximum surrogate concentrations in the bottle wall corresponding to migration of 10 µg l?1 were determined. It was shown that the SiO x coating layer is an efficient barrier to post-consumer compounds. The maximum bottle wall concentrations of the surrogates corresponding to migration of 10 µg l?1 were in the range of 200 mg kg?1 for toluene and ~900 mg kg?1 for benzophenone. Consequently, the SiO x coating allows use of conventionally recycled post-consumer PET flakes (without a super-clean recycling process) for packaging aqueous and low alcoholic foodstuffs (under cold-fill conditions) and protects food from migration of unwanted contaminants from post-consumer PET. 相似文献
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Many studies have been carried out in order to make bottle-to-bottle recycling feasible. The problem is that residual contaminants in recycled plastic intended for food packaging could be a risk to public health. One option is to use a layer of virgin material, named functional barrier, which prevents the contaminants migration process. This paper shows the feasibility of using polyethylene terephthalate (PET) recycled for food packaging employing a functional barrier made from hydrogen amorphous carbon film deposited by Plasma Enhanced Chemical Vapour Deposition (PECVD) process. PET samples were deliberately contaminated with a series of surrogates using a FDA protocol. After that, PET samples were coated with approximately 600 and 1200 Angstrons thickness of amorphous carbon film. Then, the migration tests using as food simulants: water, 10% ethanol, 3% acetic acid, and isooctane were applied to the sample in order to check the chemical resistance of the new coated material. After the tests, the liquid extracts were analysed using a solid-phase microextraction device (SPME) coupled to GC-MS. 相似文献