船舶余热固体吸附式制冷可行性分析和模拟实验系统设计

目前利用船舶余热的吸附式制冷的研究主要集中在渔船上,对在远洋船舶上应用的研究还仅仅是初步设想.本文探讨了利用远洋船舶柴油机余热进行固体吸附制冷的可行性,并提出了摸拟船舶余热的固体吸附式制冷实验系统的设计方案.     

降低吸附式制冷系统驱动热源温度的研究进展

吸附式制冷是一种环境友好的制冷方式,可以利用低品位热能提供冷量,因此具有重要的节能意义。目前,吸附式制冷技术在太阳能热利用、工业余热利用等中低温余热领域已有应用,但对低于60℃热源的利用实例较少。降低吸附式制冷系统所需的驱动热源温度是扩大吸附式制冷系统使用范围的重要手段。吸附式制冷系统所需驱动热源温度与系统循环方式、吸附剂性能等因素密切相关。从二级/多级吸附式制冷循环、表面酸性强度与孔结构等影响吸附剂再生温度方面阐述了降低吸附式制冷系统驱动热源温度技术的国内外研究现状。分析结果显示,多级循环吸附式制冷系统可以降低装置的驱动热源温度,但装置结构较为复杂;低再生温度吸附剂能够拓宽吸附式制冷装置的驱动热源温度范围,吸附剂的脱附温度与表面极性、酸性、孔结构等参数有关,对吸附剂进行改性,吸附剂极性弱、酸性低的表面特性有利于降低脱附温度。另外,还介绍了数据中心余热驱动的吸附式制冷技术。开展降低吸附式制冷系统驱动热源温度的研究为低温余热高效利用提供了技术参考。     

远洋渔船吸收式制冷应用可行性分析

氨-水吸收式制冷作为一种成熟的陆用技术,如果能在拥有丰富余热资源的渔船上应用,将在节能环保领域产生明显成效。通过实船调查,本文分析了具体条件下氨-水吸收式制冷机应用于实船的可行性,对吸收制冷系统进行了初步的设计,并对技术经济性进行了量化分析,最后分析了系统控制的关键点。     

A review of thermodynamics and heat transfer in solar refrigeration system

Solar energy is one of the most efficient, clean and affordable energy alternatives available today. With the current concerns about global warming and ever increasing energy rates, countries are seriously looking for domestic and industrial usage of solar energy. In the present study, a detail review of the application of solar energy for refrigeration systems has been carried out. The utilization of solar energy for refrigeration systems would help in improvement of energy economics, energy consumption and energy efficiency. The review focuses especially on solar panel, desiccant fluid for icemaker and its components. The study also includes thermodynamic equation and material for making component of refrigeration to improve the coefficient of performance. Study around the economic evaluation and solar performance coefficient in the type of refrigerator, modeling and simulation, mathematical equation of heat transfer and type of absorption used are other topics that could be considered.     

余热制冷用氯化钙_硅胶复合吸附剂的制备及性能研究

为了开发出利用余热进行吸附制冷的高性能吸附剂,采用浸渍法在真空下将氯化钙担载于粗孔硅胶上,制备了硅胶/氯化钙复合吸附剂,测试了复合吸附剂的吸附等温线和吸附速率,测试结果表明:浸渍法得到的复合吸附剂对水具有更大的吸附能力,在20%的湿度下,复合吸附剂在2h的吸附量为15.64 g/100 g吸附剂,是单一硅胶在相同条件下吸附量的8.06倍。用制备的复合吸附剂制作了一台小型吸附制冷机并进行了测试,当热源温度为90℃,冷却水温度为35℃时,在整个循环周期内(15 min),制冷功率为0.705kW,单位质量吸附剂的制冷功率(SCP)为70.51 W/kg,COP为0.25。     

固体吸附式制冷强化传热研究进展

吸附床的传热强化是影响固体吸附式制冷的主要因素。简述了吸附制冷的强化传热研究进展,介绍了几种常用的吸附床强化传热方法,提出了固体吸附式制冷强化传热的研究方向。     

吸附剂固化的发展与固化活性炭块的试验研究

吸附剂的固化成型被认为是增大吸附式制冷系统的制冷量一个可行的方法。本文一方面综述了吸附系统中吸附剂固化的发展现状，讨论各种固化技术和方法。另一方面总结了在我们实验室所涉及的活性炭固化研究工作，给出了以块状活性炭一甲醇为吸附工质对时比较合适的固化工艺参数。     

SrCl_2-NH_3化学吸附式制冷工质对吸附特性的研究

对以SrCl2 为吸附剂、NH3 为致冷剂所组成的化学吸附式制冷工质对的吸附性能进行了研究 ,得到了吸附等温线、回归出吸附等温方程并对化学吸附过程机理进行了探讨。研究结果表明 ,SrCl2 NH3 工质对的吸附制冷量大 ,适宜太阳能或低品位余热驱动 ,是性能优良的工质对。     

A review on adsorption refrigeration technology and adsorption deterioration in physical adsorption systems

As one kind of environmentally friendly refrigeration, the adsorption refrigeration has attracted many attentions in resent decades. This paper introduces the researches of adsorption refrigeration systems with the commonly used working pairs, advanced adsorption cycles, heat and mass transfer enhancement and attempts of adsorption refrigeration applications. Poor heat and mass transfer problem is a bottleneck to prevent the improvements of the adsorption refrigeration technique. Two ways to enhance the heat and mass transfer are discussed in this paper. The adsorption deterioration of adsorbent, another obstacle to physical adsorption refrigeration applications, is also pointed out. And the possible reasons and the possible methods are analyzed.     

Research and development of consolidated adsorbent for adsorption systems

Adsorption heat pump and refrigeration systems are noiseless, non-corrosive and environment friendly. For these reasons the research activities in this sector are still increasing to solve the crucial points that make these systems not yet ready to compete with the well-known vapor compression system. There is an increasing interest in the development and use of adsorption chillers due to their various economic and impressive environmental benefits, enabling solar energy or waste heat to be used for applications such as district networks and cogeneration plants. In order to increase the cooling power, much effort has been devoted to enhance materials heat transfer properties. Consolidated adsorbent could be the solution. This paper provides a literature review on current progress of consolidated adsorbent for adsorption systems. A number of consolidated technologies of adsorbent are discussed. The related work at our laboratory is also discussed.     

Thermodynamic analysis and performance study for adsorption refrigeration cycle driven by a fuel cell electric vehicle waste heat

Three kinds of adsorption refrigeration cycles are analyzed in this paper, a two‐bed continuous cycle, an adiabatic mass recovery cycle, and an isothermal mass recovery cycle. Operating parameters (including desorption temperature, adsorption temperature, cycle adsorption rate, COP, and period refrigerating capacity) with the change of the evaporating temperature, condensing temperature, heat capacity ratio, and heat resource temperature are discussed. The analysis indicates that performance differences between the mass recovery cycle and the two‐bed continuous cycle are reduced with an increasing of evaporating temperature and heat source temperature. By increasing the heat capacity ratio, COP values for the three kinds of cycle decrease. When the heat source temperature is between 70 and 90°C, the performance of the isothermal mass recovery cycle is best. Through study, this paper puts forward that the isothermal mass recovery cycle is the best cycle for adsorption refrigeration systems driven by fuel cell electrical vehicle waste heat. © 2010 Wiley Periodicals, Inc. Heat Trans Asian Res, 39(7): 523–538, 2010; Published online 16 July 2010 in Wiley Online Library ( wileyonlinelibrary.com ). DOI 10.1002/htj.20315     

吸附式空调技术探讨

在能源供应日益紧张和对环境保护要求越发苛刻的今天,寻找一种低碳环保的制冷方式是暖通制冷研究人员的期望。吸附式制冷技术因为对环境零影响,适应于在低温热源下驱动,近些年在余热废热利用、太阳能制冷方面吸引了众多研究者的目光,对此方面的研究也取得了长足的进步。从制冷原理、应用领域以及目前发展的等几个方面,简单介绍了吸附式制冷领域的基本概况,并提出了自己的一些看法。     

Experimental study on an adsorption icemaker driven by parabolic trough solar collector

An adsorption icemaker with energy storage system is proposed for the utilization of medium temperature solar energy. In this system, the solar energy collected by parabolic trough collector (PTC) was used to provide the heat source for the adsorption icemaker. The performance of the icemaker is tested and the experimental results showed that the highest COP reached 0.15 while the COP_sr could be 0.08 and the ice making capacity was 50 kg per day with 20 m² PTC and 30 kg compound adsorbent (calcium chloride + activated carbon) when the desorption temperature, condensing temperature and the direct normal solar radiation were 105 °C, 30 °C and 3 kWh/day·m², respectively.     

Simulation and Experimental Study of Metal Organic Frameworks Used in Adsorption Cooling

ABSTRACT

Metal-organic frameworks (MOFs) have recently attracted enormous interest over the past few years in energy storage and gas separation, yet there have been few reports for adsorption cooling applications. Adsorption cooling technology is an established alternative to mechanical vapor compression refrigeration systems and is an excellent alternative in industrial environments where waste heat is available. We explored the use of MOFs that have very high mass loading and relatively low heats of adsorption, with certain combinations of refrigerants to demonstrate a new type of highly efficient adsorption chiller. Computational fluid dynamics combined with a system level lumped-parameter model have been used to project size and performance for chillers with a cooling capacity ranging from a few kW to several thousand kW. These systems rely on stacked micro/mini-scale architectures to enhance heat and mass transfer. Recent computational studies of an adsorption chiller based on MOFs suggests that a thermally-driven coefficient of performance greater than one may be possible, which would represent a fundamental breakthrough in performance of adsorption chiller technology. Presented herein are computational and experimental results for hydrophyilic and fluorophilic MOFs.     

Simulation of an intermittent adsorptive solar cooling system

An analytical model of the adsorption solar cooling cycle is presented. This model accounts for heat and mass transfers in a porous bed in a two-dimensional transient process. After an experimental validation based on a solar icemaker using the activated carbon---methanol pair, a parametric study is presented. The influence of the choice of the activated carbon and condensing temperature is studied.     

Operational aspects of adsorption air‐conditioner used in diesel locomotive

A locomotive cabin adsorption air‐conditioner has been equipped in #DF4B‐2369 locomotive; and has been successfully run for 2 years. It is powered by waste heat from the exhaust of the diesel engine. The influence on heat transfer is described by the equivalent heat transfer coefficient or thermal resistance of components inside the adsorber. The variation of adsorption capacity is expressed by a non‐equilibrium adsorption function. The dynamic heat transfer process of adsorption air‐conditioning system is treated with the lumped parameter method. Some typical running experimental results are present. The diesel engine rotating speed and locomotive speed influenced on the refrigeration system are discussed. The maximum mean refrigeration power is regarded as an objective function. Based on experiments and theoretical analysis, the running characteristics of the air‐conditioning system are optimized. Some techniques of performance improvement are suggested as well. Copyright © 2006 John Wiley & Sons, Ltd.     

A comparison of the performances of adsorption and resorption refrigeration systems powered by the low grade heat

In order to study the refrigeration performances of the resorption refrigeration technology, the resorption working pair of BaCl₂–MnCl₂–NH₃, which has the similar working requirements for the heat source and cooling source, and also could satisfy the similar refrigeration requirements with the adsorption working pair of CaCl₂–NH₃, is studied by simulation and experiments. In the simulation the mass transfer resistance is not considered for the systems, and the refrigeration performances related with heat transfer performances are studied, results show that the resorption refrigeration system has a higher refrigeration power and COP (coefficient of the refrigeration performance) because the refrigeration effect is generated by the reaction heat compared to the latent heat of evaporation. After the simulation the experimental test unit is constructed, and the experimental data are analyzed. Results show that the resorption rate is influenced by the critical mass transfer performance very much, and the refrigeration performance is lower than that of adsorption system. The resorption system also has the problem of the larger refrigeration power loss for the reason of the sensible heat requirement of low temperature adsorber. How to improve the mass transfer performance of resorption system and decrease the influence on the refrigeration power by the sensible heat requirement of low temperature adsorber will be the key research directions for the application of resorption refrigeration systems.     

吸收式制冷循环利用低品位热能的研究现状和发展趋势

介绍吸收式制冷循环利用低品位热能的研究现状和发展趋势。阐述吸收式制冷系统对太阳能、工业余热、生物质能和地热能四种能源的利用情况,并主要从低品位热能的选择、吸收式制冷循环系统的优化和吸收器的优化三方面分析该系统存在的问题和发展趋势。     

Solar-Powered Adsorption Icemaker With Double-Stage Mass Recovery Cycle

The performance of an adsorption icemaker prototype operating in a double-stage mass recovery cycle was experimentally investigated under the generation temperature of 75°C. The prototype was heated in the regeneration phase by an electric heater, and an analytical model was employed to assess the daily number of cycles and the ice production, if evacuated tube solar collectors were used to supply the regeneration heat. It was found that the parasitic heat consumed by the metallic part of the reactor greatly reduced the coefficient of performance (COP) and ice production per unit area of solar collector. A reduction of the parasitic heat by 60% would increase the COP in 54%, and the daily ice production per unit area of solar collector in 50 to 54%, depending on the insolation. The performance of the studied prototype was inferior to the performance of some prototypes presented in the literature, which were directly heated by solar energy and used methanol as refrigerant, but this type of prototype could be an alternative to avoid subatmospheric working pressures and to provide ice on rainy and low insolation days, if waste heat or another heat source is available.     

一种有潜力的吸附式制冷工作对——活性炭纤维—甲醇

吸附式制冷具有无ＣＦＣｓ问题、可利用低品位热能驱动、价格效用比高等一系列优点。由于一般吸附剂吸附／解吸时间长和单位质量制冷功率小使吸附式制冷的产品化受阻。活性炭纤维是一般吸附剂活性炭的较好替代物，其对甲醇的吸附容量为活性炭的２－３倍，而吸附／解吸时间仅为活性炭的１／１０左右。对紧凑式吸附式冰箱，活性炭纤维－甲醇是一种好的工作对。