A theoretical study of molten carbonate fuel cell combined with a solar power plant and Cu–Cl thermochemical cycle based on techno-economic analysis

A novel power and hydrogen coproduction system is designed and analyzed from energetic and economic point of view. Power is simultaneously produced from parabolic trough collector power plant and molten carbonate fuel cell whereas hydrogen is generated in a three-steps Cu–Cl thermochemical cycle. The key component of the system is the molten carbonate fuel cell that provides heat to others (Cu–Cl thermochemical cycle and steam accumulator). A mathematic model is developed for energetic and economic analyses. A parametric study is performed to assess the impact of some parameters on the system performance. From calculations, it is deduced that electric energy from fuel cell, solar plant and output hydrogen mass are respectively 578 GWh, 25 GWh and 306 tons. The overall energy efficiency of the proposed plants is 46.80 % and its LCOE is 7.64 c€/kWh. The use of MCFC waste heat allows increasing the solar power plant efficiency by 2.15 % and reducing the annual hydrogen consumption by 3 %. Parametric analysis shows that the amount of heat recovery impacts the energy efficiency of fuel cell and Cu–Cl cycle. Also, current density is a key parameter that influences the system efficiency.     

Performance assessment of a direct steam solar power plant with hydrogen energy storage: An exergoeconomic study

Power generation and its storage using solar energy and hydrogen energy systems is a promising approach to overcome serious challenges associated with fossil fuel-based power plants. In this study, an exergoeconomic model is developed to analyze a direct steam solar tower-hydrogen gas turbine power plant under different operating conditions. An on-grid solar power plant integrated with a hydrogen storage system composed of an electrolyser, hydrogen gas turbine and fuel cell is considered. When solar energy is not available, electrical power is generated by the gas turbine and the fuel cell utilizing the hydrogen produced by the electrolyser. The effects of different working parameters on the cycle performance during charging and discharging processes are investigated using thermodynamic analysis. The results indicate that increasing the solar irradiation by 36%, leads to 13% increase in the exergy efficiency of the cycle. Moreover, the mass flow rate of the heat transfer fluid in solar system has a considerable effect on the exergy cost of output power. Solar tower has the highest exergy destruction and capital investment cost. The highest exergoeconomic factor for the integrated cycle is 60.94%. The steam turbine and PEM electrolyser have the highest share of exergoeconomic factor i.e., 80.4% and 50%, respectively.     

Hydrogen production by coupling pressurized high temperature electrolyser with solar tower technology

Solar hydrogen production by coupling of pressurized high temperature electrolyser with concentrated solar tower technology is studied. As the high temperature electrolyser requires constant temperature conditions, the focus is made on a molten salt solar tower due to its high storage capacity. A flowsheet was developed and simulations were carried out with Aspen Plus 8.4 software for MW-scale hydrogen production plants. The solar part was laid out with HFLCAL software. Two different scenarios were considered: the first concerns the production of 400 kg/d hydrogen corresponding to mobility use (fuel station). The second scenario deals with the production of 4000 kg/d hydrogen for industrial use. The process was analyzed from a thermodynamic point of view by calculating the overall process efficiency and determining the annual production. It was assumed that a fixed hydrogen demand exists in the two cases and it was assessed to which extent this can be supplied by the solar high temperature electrolysis process including thermal storage as well as hydrogen storage. For time periods with a potential over supply of hydrogen, it was considered that the excess energy is sold as electricity to the grid. For time periods where the hydrogen demand cannot be fully supplied, electricity consumption from the grid was considered. It was assessed which solar multiple is appropriate to achieve low consumption of grid electricity and low excess energy. It is shown that the consumption of grid electricity is reduced for increasing solar multiple but the efficiency is also reduced. At a solar multiple of 3.0 an annual solar-to-H₂ efficiency greater than 14% is achieved at grid electricity production below 5% for the industrial case (4000 kg/d). In a sensitivity study the paramount importance of electrolyser performance, i.e. efficiency and conversion, is shown.     

Green hydrogen as feedstock: Financial analysis of a photovoltaic-powered electrolysis plant

The weather-dependent electricity generation from Renewable Energy Sources (RES), such as solar and wind power, entails that systems for energy storage are becoming progressively more important. Among the different solutions that are being explored, hydrogen is currently considered as a key technology allowing future long-term and large-scale storage of renewable power.Today, hydrogen is mainly produced from fossil fuels, and steam methane reforming (SMR) is the most common route for producing it from natural gas. None of the conventional methods used is GHG-free. The Power-to-Gas concept, based on water electrolysis using electricity coming from renewable sources is the most environmentally clean approach. Given its multiple uses, hydrogen is sold both as a fuel, which can produce electricity through fuel cells, and as a feedstock in several industrial processes. Just the feedstock could be, in the short term, the main market of RES-based hydrogen.In this paper, we present the results obtained from a techno-economic-financial evaluation of a system to produce green hydrogen to be sold as a feedstock for industries and research centres. A system which includes a 200 kW photovoltaic plant and a 180 kW electrolyser, to be located in Messina (Italy), is proposed as a case study. According to the analyses carried out, and taking into account the current development of technologies, it has been found that investment to realise a small-scale PV-based hydrogen production plant can be remunerative.     

Hybrid systems to address seasonal mismatches between electricity production and demand in nuclear renewable electrical grids

A strategy to enable zero-carbon variable electricity production with full utilization of renewable and nuclear energy sources has been developed. Wind and solar systems send electricity to the grid. Nuclear plants operate at full capacity with variable steam to turbines to match electricity demand with production (renewables and nuclear). Excess steam at times of low electricity prices and electricity demand go to hybrid fuel production and storage systems. The characteristic of these hybrid technologies is that the economic penalties for variable nuclear steam inputs are small. Three hybrid systems were identified that could be deployed at the required scale. The first option is the gigawatt-year hourly-to-seasonal heat storage system where excess steam from the nuclear plant is used to heat rock a kilometer underground to create an artificial geothermal heat source. The heat source produces electricity on demand using geothermal technology. The second option uses steam from the nuclear plant and electricity from the grid with high-temperature electrolysis (HTR) cells to produce hydrogen and oxygen. Hydrogen is primarily for industrial applications; however, the HTE can be operated in reverse using hydrogen for peak electricity production. The third option uses variable steam and electricity for shale oil production.     

Constructing an innovative Bio-Hydrogen Integrated Renewable Energy System

Hybrid Renewable Energy Systems (HRES) offer alternative energy options that deliver distributed power generation for isolated loads. However, the production of energy from both wind turbines and solar PV systems is weather-dependent. In this study, we developed an innovative Bio-Hydrogen Integrated Renewable Energy System (BHIRES) based on the integration of hydrogen generation from biomass fermentation, renewable energy power generation, hydrogen generation from water electrolysis, a hydrogen storage device, and a fuel cell providing combined heat and power. BHIRES can provide electric power, thermal energy, and hydrogen, with the additional function of processing biomass waste and wastewater. As indicated by results of the economic analysis conducted in this study, the cost of electricity and the average energy cost of using BHIRES are both lower than those for wind/PV/hydrogen HRES. Therefore, this system is ideal for users in remote areas such as islands, and farms in mountainous areas.     

A hybrid power generation system: solar‐driven Rankine engine–hydrogen storage

This paper reports on the feasibility of a hybrid power generation system consisting of a solar energy‐driven Rankine engine and a hydrogen storage unit. Solar energy, the power for the hybrid system, is converted into electrical power through a combination of a solar collector, a tracking device to maintain proper orientation with the sun and a Rankine cycle engine driving an electrical power generator. Excess electricity is utilized to produce hydrogen for storage through electrolysis of water. At the solar down time, the stored hydrogen can be used to produce high‐quality steam in an aphodid burner to operate a turbine and with a field modulated generator to supplement electric power. Case studies are carried out on the optimum configuration of the hybrid system satisfying the energy demand. A numerical example based on the actual measured solar input is also included to demonstrate the design potential. Copyright © 2001 John Wiley & Sons, Ltd.     

Hydrogen production through solar energy water electrolysis

Various methods of making hydrogen from water have been proposed, but at the present time the only practical way to make hydrogen from water without fossil fuel is electrolysis. The development of a new, advanced, water electrolyser has become necessary for use in hydrogen energy systems and in electricity storage systems. All the new possible electrolysis processes, suitable for large-scale plants, are being analysed, in view of their combination with solar electricity source. A study of system interactions between large-scale photovoltaic plants, for electrical energy supply, and water electrolysis, is carried out. The subsystems examined include power conditioning, control and loads, as they are going to operate. Water electrolysis systems have no doubt been improved considerably and are expected to become the principal means to produce a large amount of hydrogen in the coming hydrogen economy age. Thus, the present paper treats the subject of hydrogen energy production from direct solar energy conversion facilities located on the earth's oceans and lakes. Electrolysis interface is shown to be conveniently adapted to direct solar energy conversion, depending on technical and economical feasibility aspects as they emerge from the research phases. The intrinsic requirement for relatively immense solar collection areas for large-scale central conversion facilities, with widely variable electricity charges, is given. The operation of electrolysis and photovoltaic array combination is verified at different insolation levels. Solar cell arrays and electrolysers are giving the expected results during continuously variable solar energy inputs. Future markets will turn more and more towards larger scale systems powering significantly bigger loads, ranging from hundreds of kW to several MW in size. Detailed design and close attention to subsystem engineering in the development of high performance, high efficiency photovoltaic power plants, are carried out. An overall design of a 50 MWp photovoltaic central station for electricity and hydrogen co-generation is finally discussed.     

Innovative configuration of a hybrid nuclear-parabolic trough solar power plant

This paper proposes a combination of a nuclear and a concentrated solar power (CSP) plant. Most of today’s operating nuclear reactor systems are producing saturated steam at relatively low pressure. This, in turn, limits their thermodynamic efficiency. Superheating of nuclear steam with solar thermal energy has the potential to overcome this drawback. An innovative configuration of a hybrid nuclear-CSP plant is assembled and simulated. It brings together a small pressurised water reactor and a parabolic trough solar field. The solar heat is transferred to nuclear steam to raise its temperature. Continuous superheating is provided through molten salts-based thermal energy storage (TES). The results from design point calculations show that solar superheating has the potential to increase nuclear plant electric efficiency significantly. Solar heat to electricity conversion efficiency defined as the ratio of extra generated power to collected solar energy reaches unprecedented rates of 52%. An off-design model was used to simulate 24-h operation for one year by simulating 8760 cases. Due to TES non-stop operation is manageable.     

Solar enriched methane production by steam reforming process: Reactor design

A novel hybrid plant for a mixture of methane and hydrogen (enriched methane) production from a steam reforming reactor whose heat duty is supplied by a molten salt stream heated up by a concentrating solar power (CSP) plant developed by ENEA is here presented. By this way, a hydrogen stream, mixed with natural gas, is produced from solar energy by a consolidated production method as the steam reforming process and by a pre-commercial technology as molten salts parabolic mirrors solar plant. After the hydrogen production plant, the residual heat stored in molten salt stream is used to produce electricity and the plant is co-generative (hydrogen + electricity).The heat-exchanger-shaped reactor is dimensioned by a design tool developed in MatLab environment. A reactor 3.5 m long and with a diameter of 2″ is the most efficient in terms of methane conversion (14.8%) and catalyst efficiency (4.7 Nm³/h of hydrogen produced per kg_cat).     

Ethanol steam reforming heated up by molten salt CSP: Reactor assessment

In this paper hydrogen production via reforming of ethanol has been studied in a novel hybrid plant consisting in a ethanol reformer and a concentrating solar power (CSP) plant using molten salt as heat carrier fluid. The heat needed for the reforming of ethanol has been supplied to the system by molten salts heated up by solar energy. The molten salt stream temperature drop for supplying hydrogen production process heat duty is less than 20 K, making the molten salt stream still suitable for steam and electricity production in a co-generative plant (clean hydrogen and electricity).     

A techno-economic appraisal of hydrogen generation and the case for solid oxide electrolyser cells

There is significant interest in alternatives to fossil fuels in order to reduce carbon dioxide emissions. One option is the use of hydrogen in applications such as fuel cells. There are various routes to the production of hydrogen, one being via the electrolysis of water. Water electrolysers are already operational within industry on a small-scale, accounting for 4% of world hydrogen production. These electrolysers operate at low temperatures and require electrical power input that has been shown to be costly due to the limited efficiency of the electrolysis process. However, the use of high temperature solid oxide electrolyser cells (SOECs) has the potential to generate hydrogen with a higher electrical efficiency which may allow electrolysis to become cost competitive with steam methane reforming (SMR), depending on where the heat and electrical power to service the SOEC comes from.This paper examines the various routes to hydrogen production and, in particular electrolysis technologies. The cost of hydrogen production is examined in the context of the source of the electricity and the efficiency of the electrolysis process compared to SMR generation. It is found that to become cost competitive with SMR, the lowest cost electricity is required, sourced either from nuclear or combined cycle gas turbine plants with electrolysis efficiency as high as possible, meaning that SOEC technology is particularly attractive.     

Solar thermodynamic plants for cogenerative industrial applications in southern Europe

The paper deals with the preliminary design and optimization of cogenerative solar thermodynamic plants for industrial users. The considered plants are all based on proven parabolic trough technology, but different schemes have been analyzed: from a conventional configuration with indirect steam cycle and a heat transfer fluid such as synthetic oil or molten salts, to a more innovative arrangement with direct steam generation in the solar field. Thermodynamic parameters of the steam cycle have been optimized considering some constraints due to the heat requirements of the user, leading to a preliminary design of the main components of the system and an estimation of costs. Resulting net electric efficiency is about 10% for conventional synthetic oil plant, while 13% for innovative molten salts and DSG.A comparison with conventional solar thermodynamic systems for electricity production and photovoltaic power plants shows the economic and energetic benefits of the cogenerative solution. Cost of electricity for solar plant is cheaper of about 20 €/MWh than conventional solar power application. Moreover, heat recovery allows to achieve a further 50% of CO₂ emission savings compared to reference solar plants for only electricity production.     

Studies on the energy demand of two-stage fermentative hydrogen production from biomass in a factory equipped with fuel-cell based power plant

A conceptual factory to produce hydrogen from starchy biomass is considered. The production plant comprises a pretreatment unit for starchy raw material, a bioreactor for dark fermentation, a photobioreactor for photofermentation and gas upgrading & compression units, and is supplied with the necessary heat and power from the power plant. In the power plant, a part of the stream of raw gas produced in bioreactors is burned in a steam boiler and in addition some product gas from the upgrading unit is directed to fuel cells from which waste gas flows to a catalytic oxidizer. The demand for process heat is covered by steam generation in the boiler and oxidizer, and the power demand is covered by electricity generation in the fuel cells.     

Nanoparticle gasifier fuel cell for sustainable energy future

A new concept for production of electricity from biomass or coal using molten carbonate fuel cells is proposed. It involves feeding fine coal particles or biomass, for sustainable energy future, with steam into the anode compartment of the fuel cell in which the waste heat from the fuel cell is used to produce synthesis gas which reacts electrochemically. This concept is illustrated using carbon nanoparticles as the fuel.     

A comprehensive review on power-to-gas with hydrogen options for cleaner applications

This review presents the power-to-gas concept, particularly with hydrogen, from renewable energy sources to end-use applications in various sectors, ranging from transportation to natural gas distribution networks. The paper includes an overview of the leading related studies for comparative evaluation. Due to the intermittent/fluctuating phenomena of most renewables, power-to-hydrogen appears to be a promising option to offset any mismatch between demand and supply. It is a novel concept to increase the renewability of fuels and reach a sustainable energy system for future transportation, power and thermal process sectors. Comparisons of different hydrogen production methods fed by several energy sources are made regarding environmental impact, cost and efficiency. The present results show that hydrogen production (with power-to-hydrogen concept) via polymer electrolyte membrane electrolyser has lower environmental effects than other traditional methods, such as coal gasification and reforming and steam methane reforming. The geothermal energy-based system has the lowest levelized cost of electricity during hydrogen production, while natural gas has the highest value. The best option for the plant efficiency is found for high-temperature steam electrolysis fed from biogas, while the lowest efficiency value belongs to polymer electrolyte membrane electrolyser driven by solar photovoltaics, respectively.     

Cogeneration of power and substitute of natural gas using biomass and electrolytic hydrogen

Storing renewable energy sources is becoming a very important issue to allow a further reduction of greenhouse gas emissions. Most of such energy sources generate electric power which not always can be conveniently transferred to the grid and also its conversion to hydrogen presents some critical aspects connected mainly to hydrogen distribution and storage.Electrolysis generates not only hydrogen, but also oxygen which could be used to burn biomass or waste products (oxycombustion) in power plants with the result to obtain an exhaust gas containing mainly water and CO₂. This last can be converted into a mixture of methane and hydrogen by reacting with electrolytic hydrogen, so that the power used for electrolysis is stored into a fuel which can be distributed and stored just like natural gas.In this paper, an innovative biomass fuelled plant has been designed and simulated for different layouts with an internal combustion engine as a main power system. Utilizing hydrogen and oxygen produced through electrolysis and applying a hydrogasification process, the plant produces electricity and a substitute of natural gas. The result of such simulations is that the electricity can be stored in a useful and versatile fuel with a marginal efficiency up to 60%.     

Role of hydrogen in future North European power system in 2060

The Balmorel model has been used to calculate the economic optimal energy system configuration for the Scandinavian countries and Germany in 2060 assuming a nearly 100% coverage of the energy demands in the power, heat and transport sector with renewable energy sources. Different assumptions about the future success of fuel cell technologies have been investigated as well as different electricity and heat demand assumptions. The variability of wind power production was handled by varying the hydropower production and the production on CHP plants using biomass, by power transmission, by varying the heat production in heat pumps and electric heat boilers, and by varying the production of hydrogen in electrolysis plants in combination with hydrogen storage. Investment in hydrogen storage capacity corresponded to 1.2% of annual wind power production in the scenarios without a hydrogen demand from the transport sector, and approximately 4% in the scenarios with a hydrogen demand from the transport sector. Even the scenarios without a demand for hydrogen from the transport sector saw investments in hydrogen storage due to the need for flexibility provided by the ability to store hydrogen. The storage capacities of the electricity storages provided by plug-in hybrid electric vehicles were too small to make hydrogen storage superfluous.     

Wind energy–hydrogen storage hybrid power generation

In this theoretical investigation, a hybrid power generation system utilizing wind energy and hydrogen storage is presented. Firstly, the available wind energy is determined, which is followed by evaluating the efficiency of the wind energy conversion system. A revised model of windmill is proposed from which wind power density and electric power output are determined. When the load demand is less than the output of the generation, the excess electric power is relayed to the electrolytic cell where it is used to electrolyze the de‐ionized water. Hydrogen thus produced can be stored as hydrogen compressed gas or liquid. Once the hydrogen is stored in an appropriate high‐pressure vessel, it can be used in a combustion engine, fuel cell, or burned in a water‐cooled burner to produce a very high‐quality steam for space heating, or to drive a turbine to generate electric power. It can also be combined with organic materials to produce synthetic fuels. The conclusion is that the system produces no harmful waste and depletes no resources. Note that this system also works well with a solar collector instead of a windmill. Copyright © 2001 John Wiley & Sons, Ltd.     

Performance of a direct steam generation solar thermal power plant for electricity production as a function of the solar multiple

This paper describes the influence of the solar multiple on the annual performance of parabolic trough solar thermal power plants with direct steam generation (DSG). The reference system selected is a 50 MW_e DSG power plant, with thermal storage and auxiliary natural gas-fired boiler. It is considered that both systems are necessary for an optimum coupling to the electricity grid. Although thermal storage is an opening issue for DSG technology, it gives an additional degree of freedom for plant performance optimization. Fossil hybridization is also a key element if a reliable electricity production must be guaranteed for a defined time span. Once the yearly parameters of the solar power plant are calculated, the economic analysis is performed, assessing the effect of the solar multiple in the levelized cost of electricity, as well as in the annual natural gas consumption.