Commercial application scenario using patent analysis: Fermentative hydrogen production from biomass

The main purpose of this study is to use patent analysis to investigate scenarios for future commercial applications of dark fermentation or anaerobic fermentation using biomass or organic matter as feedstock materials. The first step in this study includes a patent search procedure and patent content interpretation, in which 29 technology patents were identified from the US patent database and divided into five groups in accordance with the scope of their technical applications. The following five scenarios of commercial applications of biomass fermentation for hydrogen production were established through a combination of group applications: screening and cultivation of hydrogen-producing bacteria, biomass waste sources, biomass energization application, value enhancement of waste or wastewater treatment systems, and the application of a multi-functional hydrogen production system integrated with other technologies.     

Hydrogen production technologies: Attractiveness and future perspective

Transition to more renewable energies to render current energy demand and set aside conventional resources for the next generation needs promising strategies. Frame the future energy plan to address the energy crisis requires to have insight and foresight about the hereafter of technologies and their markets. Among different renewable energy resources, hydrogen demonstrates an encouraging future. Therefore, understanding the flexibility and compatibility of hydrogen production technologies is important to pave the way for this transition. One strategy to achieve the mentioned targets is to evaluate different hydrogen technologies based on their life cycle and their acceptance at the commercial scale. For the very first time, various hydrogen production technologies are evaluated in terms of the technology life cycle. A novel approach is employed to find the current state of the hydrogen production technologies market. By applying simple and free tools such as search traffic and patent search, the technology adoption curve and technology life cycle of each hydrogen production technology is assessed. Two criteria are utilized for this matter, patents as a technical indicator and Google trend as a technology interest indicator. For this matter 35 088 patents have been extracted and analysed. Then the data are fitted by logistic function curve to foresight different technologies' life cycle. The technology attractiveness of each hydrogen production technologies is determined by obtaining the ratio of published patents to granted ones. The level of acceptance of each hydrogen technology is assessed by using an adaptation diagram. By the combination of these two diagrams, the current status and future of the technologies are achieved and validated. Findings show that most of the hydrogen production technologies are in the slope of enlightenment and plateau of productivity stages.     

Technical and economic evaluation of solar hydrogen production by supercritical water gasification of biomass in China

A novel thermochemical method for solar hydrogen production was proposed by state key laboratory of multiphase flow in power engineering (SKLMFPE) of Xi’an Jiaotong University. In this paper, a technical and economic evaluation of the new solar hydrogen production technology was conducted. Firstly, the advantages of this new solar hydrogen production process, compared with other processes, were assessed and thermodynamic analysis of the new process was carried out. The results show that biomass gasification in supercritical water driven by concentrating solar energy may be used to achieve high efficiency solar thermal decomposition of water and biomass for hydrogen production. Secondly, the hydrogen production cost was analyzed using the method of the total annual revenue requirement. The estimated hydrogen production cost was 38.46RMB/kg for the experimental demonstration system with a treatment capacity of 1 ton wet biomass per hour, and it would be decreased to 25.1 RMB/kg if the treatment capacity of wet biomass increased from 1 t/h to 10 t/h. A sensitivity analysis was also performed and influence of parameters on the hydrogen production cost was studied. The results from technical and economic evaluation show that supercritical water gasification of biomass driven by concentrated solar energy is a promising technology for hydrogen production and it is competitive compared to other solar hydrogen production technologies.     

Value analysis for commercialization of fermentative hydrogen production from biomass

In addition to producing hydrogen gas, biohydrogen production is also used to process wastewater. Therefore, this study specifically conducted value analyses of two different scenarios of fermentative hydrogen production from a biomass system: to increase the value of a wastewater treatment system and to specifically carry out hydrogen production. The analytical results showed that fermentative hydrogen production from a biomass system would increase the value of a wastewater treatment system and make its commercialization more feasible. In contrast, fermentative hydrogen production from a biomass system designed specifically for producing hydrogen gas would have a lower system value, which indicated that it is not yet ready for commercialization. The main obstacle to be overcome in promoting biohydrogen production technology and system application is the lack of sales channels for the system's products such as hydrogen gas and electricity. Thus, in order to realize its commercialization, this paper suggests that governments provide investment subsidies for the use of biohydrogen production technology and establish a buy-back tariff system for fuel cells.     

Recent advances in hydrogen production by thermo-catalytic conversion of biomass

Hydrogen production from biomass is a green, clean, and zero emissions technology that has attracted increasing attention. This technology has been considered to possess a long-term growth potential, and it is expected to gradually reduce environmental pollution and over-exploitation of resources. In this context, we holistically review this technology and focused on the conversion of biomass into hydrogen using chemical methods (i.e., those with potential for obtaining H₂-rich producer gas streams). Several reaction parameters were discussed and classified herein including biomass conversion methods and conditions, hydrogen production and carbon conversion ratios, the effect of different catalysts types, the catalytic properties of these materials, and their related mechanisms. The overall findings provide new insights for the selection of highly effective and suitable hydrogen production catalysts by biomass conversion applications.     

Analysis of Russia's biofuel knowledge base: A comparison with Germany and China

This study assesses the evolutionary trajectory of the knowledge base of Russian biofuel technology compared to that of Germany, one of the successful leaders in adopting renewable energy, and China, an aggressive latecomer at promoting renewable energy. A total of 1797 patents filed in Russia, 8282 in Germany and 20,549 in China were retrieved from the European Patent Office database through 2012. We identify four collectively representative measures of a knowledge base (size, growth, cumulativeness, and interdependence), which are observable from biofuel patent citations. Furthermore, we define the exploratory–exploitative index, which enables us to identify the nature of learning embedded in the knowledge base structure. Our citation network analysis of the biofuel knowledge base trajectory by country, in conjunction with policy milestones, shows that Russia's biofuel knowledge base lacks both the increasing technological specialization of that in Germany and the accelerated growth rate of that in China. The German biofuel citation network shows a well-established knowledge base with increasing connectivity, while China's has grown exceptionally fast but with a sparseness of citations reflecting limited connections to preceding, foundational technologies. We conclude by addressing policy implications as well as limitations of the study and potential topics to explore in future research.     

Industrial emergy evaluation for hydrogen production systems from biomass and natural gas

Fossil fuel resources are the main source for hydrogen production, and hydrogen production by renewable energy, such as biomass, is under development. To compare the performance in natural resource utilization for different hydrogen production systems, in this paper, two laboratorial hydrogen production systems from biomass and one industrial hydrogen production system from natural gas are analyzed by using industrial emergy evaluation indices. One of the laboratorial systems is a continuous supercritical water gasification system from glucose, and the other is a batch supercritical water gasification system from sawdust. The industrial system adopts American Brown technology. The evaluation results show that although the industrial emergy efficiency (IEE) of the industrial system from natural gas is higher than that of the laboratorial systems from biomass, the industrial emergy index of sustainability (IEIS) of the two laboratorial systems are higher than that of the industrial system. To make the laboratorial biomass system become an industrial system, the system should improve its yield, and reduce its capital investment.     

Assessment of the technological development and economic potential of photobioreactors

In this paper, we investigate the development and economic potential of the photobioreactor (PBR) technology for energy purposes, i.e. production of hydrogen or biofuels. The approach adopted is to consider the technology, its expected costs and revenues, and related risks from an investor perspective. To this end we develop an investment model that is used to calculate the economic feasibility of PBRs for different scenarios, including a best-case scenario, with plenty of sunlight and water, inexpensive nutrients, high prices for hydrogen and biomass, and low other costs. The best-case scenario is compared to a scenario with less favorable boundary conditions. We find that PBR efficiencies will likely be less than 10%, with typical values between 1.8% and 5.6%. We also find that hydrogen production costs would be lower than those for biodiesel or biogas from solid biomass produced in PBRs. Compared to biofuels from traditional agriculture there is a great advantage for the PBR technology if land is scarce, because land is used more efficiently. Since PBRs can be designed as a closed system they can be applied in very dry regions. In the long term this might enable this promising concept to penetrate the energy supply market.     

Production of hydrogen energy through biomass (waste wood) gasification

Biomass gasification, conversion of solid carbonaceous fuel into combustible gas by partial combustion, is a prominent technology for the production of hydrogen from biomass. The concentration of hydrogen in the gas generated from gasification depends mainly upon moisture content, type and composition of biomass, operating conditions and configuration of the biomass gasifier. The potential of production of hydrogen from wood waste by applying downdraft gasification technology is investigated. An experimental study is carried out using an Imbert downdraft biomass gasifier covering a wide range of operating parameters. The producer gas generated in the downdraft gasifier is analyzed using a gas chromatograph (NUCON 5765) with thermal conductivity detector (TCD). The effects of air flow rate and moisture content on the quality of producer gas are studied by performing experiments. The performance of the biomass gasifier is evaluated in terms of equivalence ratio, composition of producer gas, and rate of hydrogen production.     

环境低负荷制氢技术及集成制氢系统

讨论了各种环境低负荷的制氢技术。SPE电解水制氢技术成熟，将成为未来主要制氢方法之一。生物化学制氢和半导体光解水制氢仅以太阳能为能源，前景广阔。生物质制氢清洁、节能，值得推广。环境低负荷集成制氢系统综合多种技术，是制氢技术发展的一个趋势。     

几种生物质制氢方式的探讨

生物质资源丰富，是一种重要的可再生能源而且其自身是氢的载体；与矿物燃料相比，具有挥发分高，硫、氮含量低等优点，无论是从能源角度还是从环境角度，发展生物质制氢技术都具有重要的意义。文章论述了生物质制氢的各种方式，介绍了各自的优缺点及面临的困难，着重论述了生物质热化学转换方式制氢，并对其未来的应用前景做了一定的预测。     

生物质流化床气化技术应用研究现状

按所得产品不同,可将生物质气化技术分为制氢、发电和合成液体燃料3大类。文章介绍了生物质流化床水蒸气气化制氢、催化气化制氢和超临界水气化制氢的工艺特点;分析了生物质流化床气化发电的技术、经济可行性;简述了生物质流化床气化合成液体燃料的研究现状;指出气化产出气化学当量比调变、焦油去除问题和合成气净化是生物质流化床气化技术应用的主要瓶颈,认为定向气化是今后研究的主要方向。     

A patent analysis on advanced biohydrogen technology development and commercialisation: Scope and competitiveness

The need of developing renewable energy to reduce the impact on the global environment and climate change of the increasing industrial development has fostered the use of biological processes to produce biofuel from biohydrogen. The present work made a patent analysis of advanced hydrogen production techniques comparing it with similar prior art in China, Japan, the Republic of Korea, the European Union and the United States (U.S.) The aims were to find the scope, competitiveness of prior art, as well as the technology trend on biohydrogen production methods. The patents value was assessed its geographic scope and competitiveness indicators such as green image, low cost, energy efficiency and equipment design. It was found that most of the hydrogen production methods and associated technologies are developed by academic institutions, however their patents are reduced to a local level, and few are patented at international level, which reduces their competitiveness. The China (P.R.C.) is the biggest patent contributor worldwide in terms of hydrogen production methods by academic institutions. Japan is a huge patent contributor, in terms of methods aiming rear-end products application of hydrogen by private companies. The biggest amount of prior art found that the most popular methods of pre-treatment and dark fermentation produced coincide with the time of energetic crisis and the green movement to find alternative fuels. Finally, patent analysis of this study can help to discern the current technology trend and to develop the next generation of biohydrogen processes and associated technologies.     

生物质热化学转化制氢技术

生物质是一种重要的可再生能源，是氢的载体，与矿物燃料相比，具有挥发分高，硫、氮含量低等优点。无论是从能源角度还是从环境角度，发展生物质制氢技术都具有重要的意义。目前有关生物质制氢方面的研究主要集中在热化学转换法和生物法，文章从热化学转换的角度，进行了几种生物质制氢路线的技术经济分析预测。     

The role of biomass in California's hydrogen economy

This paper presents the results of a model of hydrogen production from waste biomass in California. We develop a profit-maximizing model of a biomass hydrogen industry from field to vehicle tank. This model is used to estimate the economic potential for hydrogen production from two waste biomass resources in Northern California—wheat straw and rice straw—taking into account the on the ground geographic dimensions of both biomass supply and hydrogen demand. The systems analysis approach allows for explicit consideration of the interactions between feedstock collection, hydrogen production, and hydrogen distribution in finding the optimal system design. This case study approach provides insight into both the real-world potential and the real-world cost of producing hydrogen from waste biomass. Additional context is provided through the estimation of California's total waste biomass hydrogen potential. We find that enough biomass is available from waste sources to provide up to 40% of the current California passenger car fuel demand as hydrogen. Optimized supply chains result in delivered hydrogen costing between $3/kg and $5.50/kg with one-tenth of the well-to-wheels greenhouse gas emissions of conventional gasoline-fueled vehicles.     

The evolution of hydrogen research: Is Germany heading for an early lock-in?

In this article we analyse and evaluate the German Research and Development (R&D) system related to the development of hydrogen technology for mobile applications. We analysed both research projects and patents in the period 1974–2002. The paper focuses on an analysis of the main technological trends, the role of governments in steering the transition and an evaluation of the speed and direction of the transition to hydrogen. Our findings show that the attention for hydrogen is strongly increasing and that overall the variety in research projects is increasing. This is positive. However, some technologies receive more attention than others. The number of projects and patents related to infrastructure and refuelling is very low while on board production of hydrogen is a clear winner. In terms of storage, liquid hydrogen receives most attention. We are concerned about these directions in R&D strategy since different well to wheel studies have shown the drawbacks of these options in terms of energy efficiency. Different governments play an active role in stimulating research and development, which broadens the variety of research topics, which is positive. However, the distance between government and industrial interests may be too large to lead to a significant influence of policy efforts. We therefore recommend stronger policy coordination to counteract the risks of premature lock-in in suboptimal hydrogen technologies.     

Modeling the effect of non-linear process parameters on the prediction of hydrogen production by steam reforming of bio-oil and glycerol using artificial neural network

Biomass-derived substrates such as bio-oil and glycerol are gaining wide acceptability as feedstocks to produce hydrogen using a steam reforming process. The wide acceptability can be attributed to a huge amount of glycerol and bio-oil obtained as by-products of biodiesel production and pyrolysis processes. Several parameters have been reported to affect the production of hydrogen by biomass steam reforming. This study investigates the effect of non-linear process parameters on the prediction of hydrogen production by biomass (bio-oil and glycerol) steam reforming using artificial neural network (ANN) modeling technique. Twenty different multilayer ANN model architectures were tested using datasets obtained from the bio-oil and glycerol steam reforming. Two algorithms namely Levenberg-Marquardt and Bayesian regularization were employed for the training of the ANNs. An optimized network configuration consisting of 3 input layer 14 hidden neurons, 1 output layer, and 3 input layer, 5 hidden neurons, and 1 output layer were obtained for the Levenberg-Marquardt and Bayesian regularization trained network, respectively for hydrogen production by bio-oil steam reforming. While an optimized network configuration consisting of 5 input nodes, 9 hidden neurons, 1 output node, and 5 input nodes, 8 hidden neurons, and 1 output node were obtained for Levenberg-Marquardt and Bayesian regularization trained network, respectively for hydrogen production by glycerol steam reforming. Based on the optimized network, the predicted hydrogen production from the bio-oil and glycerol steam agreed with the actual values with the coefficient of determination (R²) > 0.9. A low mean square error of 3.024 × 10⁻²⁴ and 6.22 × 10⁻¹⁵ for the optimized for Levenberg-Marquardt and Bayesian regularization-trained ANN, respectively. The neural network analyses of the two processes showed that reaction temperature and glycerol-to-water molar ratio were the most relevant factors that influenced the production of hydrogen by bio-oil and glycerol steam reforming, respectively. This study has demonstrated the robustness of the ANN as a technique for investigating the effect of non-linear process parameters on hydrogen production by bio-oil and glycerol steam reforming.     

A review on biomass‐based hydrogen production and potential applications

In this paper, a detailed review is presented to discuss biomass‐based hydrogen production systems and their applications. Some optimum hydrogen production and operating conditions are studied through a comprehensive sensitivity analysis on the hydrogen yield from steam biomass gasification. In addition, a hybrid system, which combines a biomass‐based hydrogen production system and a solid oxide fuel cell unit is considered for performance assessment. A comparative thermodynamic study also is undertaken to investigate various operational aspects through energy and exergy efficiencies. The results of this study show that there are various key parameters affecting the hydrogen production process and system performance. They also indicate that it is possible to increase the hydrogen yield from 70 to 107 g H₂ per kg of sawdust wood. By studying the energy and exergy efficiencies, the performance assessment shows the potential to produce hydrogen from steam biomass gasification. The study further reveals a strong potential of this system as it utilizes steam biomass gasification for hydrogen production. To evaluate the system performance, the efficiencies are calculated at particular pressures, temperatures, current densities, and fuel utilization factors. It is found that there is a strong potential in the gasification temperature range 1023–1423 K to increase energy efficiency with a hydrogen yield from 45 to 55% and the exergy efficiency with hydrogen yield from 22 to 32%, respectively, whereas the exergy efficiency of electricity production decreases from 56 to 49.4%. Hydrogen production by steam sawdust gasification appears to be an ultimate option for hydrogen production based on the parametric studies and performance assessments that were carried out through energy and exergy efficiencies. Finally, the system integration is an attractive option for better performance. Copyright © 2012 John Wiley & Sons, Ltd.     

Hydrogen-rich gas production from biomass air and oxygen/steam gasification in a downdraft gasifier

Biomass gasification is an important method to obtain renewable hydrogen. However, this technology still stagnates in a laboratory scale because of its high-energy consumption. In order to get maximum hydrogen yield and decrease energy consumption, this study applies a self-heated downdraft gasifier as the reactor and uses char as the catalyst to study the characteristics of hydrogen production from biomass gasification. Air and oxygen/steam are utilized as the gasifying agents. The experimental results indicate that compared to biomass air gasification, biomass oxygen/steam gasification improves hydrogen yield depending on the volume of downdraft gasifier, and also nearly doubles the heating value of fuel gas. The maximum lower heating value of fuel gas reaches 11.11 MJ/N m³ for biomass oxygen/steam gasification. Over the ranges of operating conditions examined, the maximum hydrogen yield reaches 45.16 g H₂/kg biomass. For biomass oxygen/steam gasification, the content of H₂ and CO reaches 63.27–72.56%, while the content of H₂ and CO gets to 52.19–63.31% for biomass air gasification. The ratio of H₂/CO for biomass oxygen/steam gasification reaches 0.70–0.90, which is lower than that of biomass air gasification, 1.06–1.27. The experimental and comparison results prove that biomass oxygen/steam gasification in a downdraft gasifier is an effective, relatively low energy consumption technology for hydrogen-rich gas production.     

Technology exploration and forecasting of biofuels and biohydrogen energy from patent analysis

The status and activity of technological development in the field of biofuel and biohydrogen energy from the year 2000–2011 were investigated utilizing patent bibliometric analysis. Based on the reports, the current status indicates that the key technologies for biofuel energy have reached technological maturity in the United States. However, the principal or predominant technologies for biohydrogen energy need a great deal of work to accelerate the development of biohydrogen technology. In addition, three important subjects were found from citation techniques, which are related to biodiesel fuel, biological fuel cell, and the biohydrogen. These patents described that the focus of key techniques of energy production should be established towards low energy demand technologies, and biohydrogen was found to be a potential candidate of the future. Finally, this proposed model can be applied to all high-technology cases, and particularly to green energy field.