Nanorefrigerants: A comprehensive review on its past,present and future

Nanofluid as a heat transfer fluid has been gaining popularity ever since its inception. Consequently, the researchers and experimentalists from the refrigeration industry could not keep themselves away from the ever growing horizon of nanofluid applications. The research on the refrigerant based nanofluids or a nanorefrigerant is slowly but surely increasing. The boiling heat transfer coefficient data for nanofluids and nanorefrigerants have been inconsistent but, in general, researchers have observed a rise in the boiling heat transfer coefficient that encourages them to pursue their research further in this field. Numerous studies regarding nanorefrigerants have shown that the addition of nanoparticles lead to a better system performance and energy efficiency. This review paper is an attempt to summarise all the aspects of nanorefrigerants such as its preparation, thermophysical properties, pressure drop in nanorefrigerants, boiling heat transfer and performance of nanorefrigerants in various domestic refrigerators.     

Impact of selected parameters on refrigerant flow boiling heat transfer and pressure drop in minichannels

This paper presents results concerning flow boiling heat transfer in a rectangular minichannel 1 mm deep, 40 mm wide and 360 mm long. The refrigerant flowing in the minichannel, Fluorinert FC-72, was heated by a thin foil microstructured on the side in contact with the fluid. Two types of microstructured surfaces were used: one with evenly distributed microcavities and the other with non-uniformly distributed minicavities. Liquid crystal thermography was applied to determine the temperature of the smooth side of the foil. The paper analyses mainly the impact of the microstructured heating surface and orientation of the minichanel on the heat transfer coefficient and two phase pressure drop. This required calculating the local values of heat transfer coefficient and measuring the pressure drop for different positions of the minichannel with enhanced heating wall. Moreover, the effects of selected thermal and flow parameters (mass flux density and inlet pressure), the geometric parameters, and the type of cooling liquid on the nucleate boiling heat transfer is studied. From the measurement results it is evident that applying a microstructured surface caused an increase in the heat transfer coefficient, which was approximately twice as high as that reported for the smooth surface. The highest values of the coefficient were observed for position 90° (the vertical minichannel) and position 0° (the horizontal minichannel), whereas the lowest were reported for position 180° (the horizontal minichannel). The experimental data concerning the two-phase flow pressure drop was compared with the calculation results obtained by applying nine correlations known from the literature. It is reported that most of the correlations can be used to predict the two-phase flow pressure drop gradient within an acceptable error limit (±30%) only for positions 90° and 135° (the vertical and inclined minichannels, respectively). The lowest agreement between the experimental data and the theoretical predictions was reported for the horizontal positions of the minichannel.     

Experimental study of turbulent single-phase flow and heat transfer inside a micro-finned tube

Single-phase heat transfer and pressure drop characteristics of a commercially available internally micro-finned tube with a nominal outside diameter of 7.94 mm were studied. Experiments were conducted in a double pipe heat exchanger with water as the cooling as well as the heating fluid for six sets of runs. The pressure drop data were collected under isothermal conditions. Data were taken for turbulent flow with 3300 ≤ Re ≤ 22,500 and 2.9 ≤ Pr ≤ 4.7. The heat transfer data were correlated by a Dittus–Boelter type correlation, while the pressure drop data were correlated by a Blasius type correlation. The correlation predicted values for both the Nusselt number and the friction factors were compared with other studies. It was found that the Nusselt numbers obtained from the present correlation fall in the middle region between the Copetti et al. and the Gnielinski smooth tube correlation predicted Nusselt number values. For pressure drop results, the present correlation predicted friction factors values were nearly double that of the Blasius smooth tube correlation predicted friction factors. It was also found that the rough tube Gnielinski and Haaland correlations can be used as a good approximation to predict the finned tube Nusselt number and ffriction factor, respectively, in the tested Reynolds number range.     

Evaporation heat transfer and pressure drop of ammonia in a mixed configuration chevron plate heat exchanger

Ammonia is a naturally occurring environment friendly refrigerant with attractive thermo-physical properties. Experimental investigation of heat transfer and pressure drop during steady state evaporation of ammonia in a commercial plate heat exchanger has been carried out for an un-symmetric 30°/60° chevron plate configuration. Experiments were conducted for saturation temperatures ranging from −25 °C to −2 °C. The heat flux was varied between 21 kW m⁻² and 44 kW m⁻². Experimental results show significant effect of saturation temperature, heat flux and exit vapor quality on heat transfer coefficient and pressure drop. Current mixed plate configuration data are compared with previous studies on the same heat exchanger with symmetric plate configurations. This comparison highlighted importance of optimization in selection of the heat exchangers. Correlations for two phase Nusselt number and friction factor for each chevron plate configuration considered are developed. A Nusselt number correlation generalized for a range of chevron angles is also proposed.     

Heat transfer and pressure drop in a plate-type evaporator

A plate-type evaporator, working with natural refrigerant circulation, has been investigated both experimentally and theoretically. Motivated by the phase-out of ozone-depleting substances, HCFC22 was compared to HFC134a and two zeotropic refrigerant mixtures. The effect of different separator liquid levels, i.e. refrigerant flows, and its influence on heat transfer was also studied. The investigated plate-type evaporator consists of thirteen vertical flow channels and its size is 3.0 m × 0.5 m. The heat source for the evaporator is a falling water film on the outside of the plate. Experimental studies have been carried out using a test facility that enabled detailed measurements of heat transfer and pressure drop. Experiments were compared to results from a calculation method that simultaneously calculates heat transfer and pressure drop in a variable number of steps along the evaporator. The calculation method is based on a pressure drop correlation proposed by the VDI-Wärmeatlas and a heat transfer correlation for vertical tubes proposed by Steiner and Taborek. For different evaporator duties, heat transfer was over predicted by 12% for pure fluids by 15% for mixtures. Calculated pressure drops were well within ±5% of the measured values. Changes in heat transfer due to different flows were closely predicted by the proposed calculation method.     

Heat transfer enhancement by winglet-type vortex generator arrays in compact plain-fin-and-tube heat exchangers

The potential of winglet type vortex generator (VG) arrays for air-side heat transfer enhancement is experimentally evaluated by full-scale wind-tunnel testing of a compact plain-fin-and-tube heat exchanger. The effectiveness of a 3VG alternate-tube inline array of vortex generators is compared to a single-row vortex generator design and the baseline configuration. The winglets are placed in a common-flow-up orientation for improved tube wake management. The overall heat transfer and pressure drop performance are assessed under dry-surface conditions over a Reynolds number range based on hydraulic diameter of 220 ≤ Re ≤ 960. It is found that the air-side heat transfer coefficient increases from 16.5% to 44% for the single-row winglet arrangement with an increase in pressure drop of less than 12%. For the three-row vortex generator array, the enhancement in heat transfer coefficient increases with Reynolds number from 29.9% to 68.8% with a pressure drop penalty from 26% at Re = 960 to 87.5% at Re = 220. The results indicate that vortex generator arrays can significantly enhance the performance of fin-tube heat exchangers with flow depths and fin densities typical to those used in air-cooling and refrigeration applications.     

Measurement and prediction of heat transfer coefficient on ammonia flow boiling in a microfin plate evaporator

Thermal characteristics of ammonia flow boiling in a microfin plate evaporator are experimentally investigated. Titanium microfin heat transfer surface is manufactured to enhance boiling heat transfer. Longitudinally- and laterally-microfined surfaces are used and those performances are compared. Heat transfer coefficient of microfin plate evaporator is also compared with that of plain-surface plate evaporator. The effects of mass flux, heat flux, channel height, and saturation pressure on heat transfer coefficient are presented and discussed. The experiments are conducted for the range of mass flux (5 and 7.5 kg m⁻² s⁻¹), heat flux (10, 15, and 20 kW m⁻²), channel height (1, 2, and 5 mm), and saturation pressure (0.7 and 0.9 MPa). Heat transfer coefficient is compared with that predicted by available empirical correlations proposed by other researchers. Modified correlations using Lockhart-Martinelli parameter to predict heat transfer coefficient are developed and they cover more than 87% of the experimental data.     

Experimental study on thermal characteristics of ammonia flow boiling in a plate evaporator at low mass flux

Thermal characteristics of a plate evaporator using ammonia are experimentally investigated. The effects of mass flux, heat flux, channel height, and saturation pressure on heat transfer coefficient of the evaporator are discussed. The experiments are conducted for mass flux (5 and 7.5 kg m⁻² s⁻¹), heat flux (10, 15, and 20 kW m⁻²), channel height (1, 2, and 5 mm), and saturation pressure (0.7 and 0.9 MPa). Heat transfer coefficient is obtained as a function of quality for all experimental conditions. The characteristics of heat transfer coefficient are discussed and compared with those of earlier works. All experimental results are compiled by using Lockhart–Martinelli parameter. The developed empirical correlation predicts 85% of the experimental data within ±30% range.     

CO2 flow condensation heat transfer and pressure drop in multi-port microchannels at low temperatures

CO₂ flow condensation heat transfer coefficients and pressure drop are investigated for 0.89 mm microchannels at horizontal flow conditions. They were measured at saturation temperatures of −15 and −25 °C, mass fluxes from 200 to 800 kg m⁻² s⁻¹, and wall subcooling temperatures from 2 to 4 °C. Flow patterns for experimental conditions were predicted by two flow pattern maps, and it could be predicted that annular flow patterns could exist in most of flow conditions except low mass flux and low vapor quality conditions. Measured heat transfer coefficients increased with the increase of mass fluxes and vapor qualities, whereas they were almost independent of wall subcooling temperature changes. Several correlations could predict heat transfer coefficients within acceptable error range, and from this comparison, it could be inferred that the flow condensation mechanism in 0.89 mm channels should be similar to that in large tubes. CO₂ two-phase pressure drop, measured in adiabatic conditions, increased with the increase of mass flux and vapor quality, and it decreased with the increase of saturation temperature. By comparing measured pressure drop with calculated values, it was shown that several correlations could predict the measured values relatively well.     

NH3 in-tube condensation heat transfer and pressure drop in a smooth tube

This paper presents an overview of the issues and new results for in-tube condensation of ammonia in horizontal round tubes. A new empirical correlation is presented based on measured NH₃ in-tube condensation heat transfer and pressure drop by Komandiwirya et al. [Komandiwirya, H.B., Hrnjak, P.S., Newell, T.A., 2005. An experimental investigation of pressure drop and heat transfer in an in-tube condensation system of ammonia with and without miscible oil in smooth and enhanced tubes. ACRC CR-54, University of Illinois at Urbana-Champaign] in an 8.1 mm aluminum tube at a saturation temperature of 35 °C, and for a mass flux range of 20–270 kg m⁻² s⁻¹. Most correlations overpredict these measured NH₃ heat transfer coefficients, up to 300%. The reasons are attributed to difference in thermophysical properties of ammonia compared to other refrigerants used in generation and validation of the correlations. Based on the conventional correlations, thermophysical properties of ammonia, and measured heat transfer coefficients, a new correlation was developed which can predict most of the measured values within ±20%. Measured NH₃ pressure drop is shown and discussed. Two separated flow models are shown to predict the pressure drop relatively well at pressure drop higher than 1 kPa m⁻¹, while a homogeneous model yields acceptable values at pressure drop less than 1 kPa m⁻¹. The pressure drop mechanism and prediction accuracy are explained though the use of flow patterns.     

Refrigerant R134a vaporisation heat transfer and pressure drop inside a small brazed plate heat exchanger

This paper presents the experimental heat transfer coefficients and pressure drop measured during refrigerant R134a vaporisation inside a small brazed plate heat exchanger (BPHE): the effects of heat flux, refrigerant mass flux, saturation temperature and outlet conditions are investigated. The BPHE tested consists of 10 plates, 72 mm in width and 310 mm in length, which present a macro-scale herringbone corrugation with an inclination angle of 65° and corrugation amplitude of 2 mm.The experimental results are reported in terms of refrigerant side heat transfer coefficients and frictional pressure drop. The heat transfer coefficients show great sensitivity both to heat flux and outlet conditions and weak sensitivity to saturation temperature. The frictional pressure drop shows a linear dependence on the kinetic energy per unit volume of the refrigerant flow.The experimental heat transfer coefficients are also compared with two well-known correlations for nucleate pool boiling and a correlation for frictional pressure drop is proposed.     

Condensation heat transfer and pressure drop characteristics of CO2 in a microchannel

The condensation heat transfer coefficient and pressure drop of CO₂ in a multiport microchannel with a hydraulic diameter of 1.5 mm was investigated with variation of the mass flux from 400 to 1000 kgm⁻²s⁻¹ and of the condensation temperature from −5 to 5 °C. The heat transfer coefficient and pressure drop increased with the decrease of condensation temperature and the increase of mass flux. However, the rate of increase of the heat transfer coefficient was retarded by these changes. The gradient of the pressure drop with respect to vapor quality is significant with the increase of mass flux. The existing models for heat transfer coefficient overpredicted the experimental data, and the deviation increased at high vapor quality and at high heat transfer coefficient. The smallest mean deviation of ±51.8% was found by the Thome et al. model. For the pressure drop, the Mishima and Hibiki model showed mean deviation of 29.1%.     

Printed circuit heat exchanger thermal–hydraulic performance in supercritical CO2 experimental loop

Heat transfer and pressure drop characteristics of the Printed Circuit Heat Exchanger (PCHE) were investigated in an experimental supercritical CO₂ loop. The inlet temperature and pressure were varied from 280 to 300 °C/2.2 to 3.2 MPa in the hot side and from 90 to 108 °C/6.5 to 10.5 MPa in the cold side while the mass flow rate was varied from 40 to 80 kg h⁻¹. The overall heat transfer coefficient range is 300–650 W m⁻² K⁻¹ while the compactness with respect to the heat exchanger core is approximately 1050 m² m⁻³. The empirical correlations to predict the local heat transfer coefficient and pressure drop factor as a function of the Reynolds number have been proposed for the tested PCHE.     

Effect of lubricating oil on cooling heat transfer of supercritical carbon dioxide

In this research, the cooling heat transfer coefficient and pressure drop of supercritical CO₂ with PAG-type lubricating oil entrained were experimentally investigated. The inner diameter of the test tubes ranged from 1 to 6 mm. The experiments were conducted at lubricating oil concentrations from 0 to 5%, pressures from 8 to 10 MPa, mass fluxes from 200 to 1200 kg m⁻² s⁻¹, and heat fluxes from 12 to 24 kW m⁻².In comparison to the oil-free condition, when lubricating oil entrainment occurred, the heat transfer coefficient decreased and the pressure drop increased. The maximum reduction in the heat transfer coefficients—about 75%—occurred in the vicinity of the pseudocritical temperature. The influence of oil was significant for a small tube diameter and a large oil concentration. From visual observation, it was confirmed that this degradation in the heat transfer was due to the formation of an oil-rich layer along the inner wall of the test tube. However, when the oil concentration exceeded 3%, no further degradation in the heat transfer coefficient could be confirmed, which implies that the oil flowing along with CO₂ in the bulk region does not influence the heat transfer coefficient and the pressure drops significantly. For a large tube at a lower mass flux, no significant degradation in the heat transfer coefficient was observed until the oil concentration reached 1%. This is due to the transition of the flow pattern from an annular-dispersed flow to a wavy flow for a large tube, with CO₂ flowing on the upper side and the oil-rich layer on the lower side of the test section.     

Condensation heat transfer and two-phase frictional pressure drop in a single minichannel with R1234ze(E) and other refrigerants

R1234ze(E), trans-1, 3, 3, 3-tetrafluoropropene, is a fluorinated propene isomer which may be a substitute of R134a for refrigeration applications. R1234ze(E) has a much lower GWP_100-years than that of R134a. In this paper, the local heat transfer coefficient during condensation of R1234ze(E) is investigated in a single minichannel, horizontally arranged, with hydraulic diameter equal to 0.96 mm. Since the saturation temperature drop directly affects the heat transfer rate, the pressure drop during adiabatic two phase flow of R1234ze(E) is also measured. Predictive models are assessed both for condensation heat transfer and pressure drop. A comparative analysis is carried out among several fluids (R1234ze(E), R32, R134a and R1234yf) starting from experimental data collected at the same conditions and using the Performance Evaluation Criteria (PEC) named Penalty Factor (PF) and Total Temperature Penalization (TTP) to rank the tested refrigerants in forced convective condensation.     

Condensation heat transfer and pressure drop in flattened microfin tubes having different aspect ratios

In this study, condensation heat transfer coefficients and pressure drops of R-410A are obtained in flattened microfin tubes made from 7.0 mm O.D. round microfin tubes. The test range covers saturation temperature 45 °C, mass flux 100–400 kg m⁻² s⁻¹ and quality 0.2–0.8. Results show that the effect of aspect ratio on condensation heat transfer coefficient is dependent on the flow pattern. For annular flow, the heat transfer coefficient increases as aspect ratio increases. For stratified flow, however, the heat transfer coefficient decreases as aspect ratio increases. The pressure drop always increases as aspect ratio increases. Possible reasoning is provided based on the estimated flow pattern in flat microfin tubes. Comparison with existing round microfin tube correlations is made.     

Evaporative heat transfer and pressure drop of R410A in microchannels

Convective boiling heat transfer coefficients and two-phase pressure drops of R410A are investigated in rectangular microchannels whose hydraulic diameters are 1.36 and 1.44 mm. The mass flux was varied from 200 to 400 kg/m²s, heat flux from 10 to 20 kW/m², as the saturation temperatures were maintained at 0, 5 and 10 °C. A direct heating method was used to provide heat flux into the fluid. The boiling heat transfer coefficients of R410A in the microchannels were much different with those in single tubes, and the test conditions only slightly affected the heat transfer coefficients before dryout vapor quality. The present heat transfer correlation for microchannels, which was developed by introducing non-dimensional parameters of Bo, We_l, and Re_l used in the existing heat transfer correlations for large diameter tubes, yielded satisfactory predictions of the present data with a mean deviation of 18%. The pressure drops of R410A in the microchannels showed very similar trends with those in large diameter tubes. The existing two-phase pressure drop correlations for R410A in microchannels satisfactorily predicted the present data.     

Pressure drop reduction and heat transfer deterioration of slush nitrogen in triangular and circular pipe flows

Slush fluids such as slush hydrogen and slush nitrogen are characterized by superior properties as functional thermal fluids due to their density and heat of fusion. In addition to allowing efficient hydrogen transport and storage, slush hydrogen can serve as a refrigerant for high-temperature superconducting (HTS) equipment using MgB₂, with the potential for synergistic effects. In this study, pressure drop reduction and heat transfer deterioration experiments were performed on slush nitrogen flowing in a horizontal triangular pipe with sides of 20 mm under the conditions of three different cross-sectional orientations. Experimental conditions consisted of flow velocity (0.3–4.2 m/s), solid fraction (0–25 wt.%), and heat flux (0, 10, and 20 kW/m²). Pressure drop reduction became apparent at flow velocities exceeding about 1.3–1.8 m/s, representing a maximum amount of reduction of 16–19% in comparison with liquid nitrogen, regardless of heating. Heat transfer deterioration was seen at flow velocities of over 1.2–1.8 m/s, for a maximum amount of deterioration of 13–16%. The authors of the current study compared the results for pressure drop reduction and heat transfer deterioration in triangular pipe with those obtained previously for circular and square pipes, clarifying differences in flow and heat transfer properties. Also, a correlation equation was obtained between the slush Reynolds number and the pipe friction factor, which is important in the estimation of pressure drop in unheated triangular pipe. Furthermore, a second correlation equation was derived between the modified slush Reynolds number and the pipe friction factor, enabling the integrated prediction of pressure drop in both unheated triangular and circular pipes.     

The impact of fouling on the performance of filter–evaporator combinations

This paper presents results of experiments performed on different combinations of five types of filters of varying efficiencies (MERV4, 6, 8, 11, and 14) and four types of evaporator coils with depths and fin geometries under clean and fouled conditions. The fouled conditions were obtained after injection of 600 g (1612 g/m² of coil face area) of dust upstream of the filter–coil combination, which was meant to simulate a year of operation in the field. The air-side pressure drops of the coils and filters and air-side effective heat transfer coefficients of the coils were determined from the measurements under the clean and fouled conditions. Depending upon the filter and coil, the coil pressure drops increased in the range of 6–30% for an air velocity of 2.54 m/s. The impact was significantly greater for tests performed without an upstream filter (the coil pressure drops increased from 43% to 200%). The largest relative effect of fouling on pressure drop occurs for coils with fewer rows, primarily due to higher fin densities. The impact of fouling on air-side effective heat transfer coefficients was found to be relatively small, which ranged from −14% to 4%. In some cases, heat transfer was actually enhanced due to additional turbulence caused by the presence of dust. However, with large dust deposits, heat transfer is degraded because the dust also acts as insulation and creates an uneven air velocity.     

Experimental study on the evaporative heat transfer and pressure drop of CO2 flowing upward in vertical smooth and micro-fin tubes with the diameter of 5 mm

Because of the ozone layer depletion and global warming, new alternative refrigerants are being developed. In this study, evaporation heat transfer characteristic and pressure drop of carbon dioxide flowing upward in vertical smooth and micro-fin tubes were investigated by experiment with regard to evaporating temperature, mass flux and heat flux. The vertical smooth and micro-fin tubes with outer diameter (OD) of 5 mm and length of 1.44 m were selected as a test section to measure the evaporative heat transfer coefficient. The tests were conducted at mass fluxes from 212 to 530 kg/(m² s), saturation temperatures from −5 to 20 °C and heat fluxes from 15 to 45 kW/m², where the test section was heated by a direct heating method. The differences of heat transfer characteristics between the smooth and the micro-fin tubes were analyzed with respect to enhancement factor (EF) and penalty factor (PF). Average evaporation heat transfer coefficients for the micro-fin tube were approximately 111–207% higher than those for the smooth tube at the same test conditions, and PF was increased from 106 to 123%.