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通过对短程硝化反硝化工艺的研究,开发了好氧/厌氧/好氧/缺氧(O1/A1/O2/A2)生物脱氮新工艺并用于焦化废水的处理。考察了NH4+-N、COD、TN对反应器运行效果影响。结果表明,当进水COD平均为3 012.9 mg/L,NH4+-N、TN、挥发酚、总氰平均质量浓度分别为590.5、608.4、361.8、34.5 mg/L;出水COD平均为81.7 mg/L,出水NH4+-N、TN、挥发酚、总氰的平均质量浓度分别为0.1、9.9、0.1、0.1 mg/L,出水指标达到国家污水综合排放一级标准,A/O工艺处理这种焦化废水TN偏高,而用O1/A1/O2/A2工艺可以解决这一问题,实现了TN脱除。考察了温度、DO、pH对短程硝化影响。结果表明,在DO质量浓度为1.0~1.5 mg/L、温度在30~35℃、pH 7.5~8.0,系统能够进行稳定短程硝化反硝化。 相似文献
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考察了厌氧/好氧/缺氧(A/O/A)工艺处理焦化废水对COD和NH3-N的去除效果。连续试验表明,焦化废水进水CODCr、NH3-N平均浓度分别为2 450 mg/L、121 mg/L,在经过系统稳定运行处理后出水浓度分别为115 mg/L、10.6 mg/L,去除率分别为95.3%、91.2%,达到了《污水综合排放标准》的二级标准。将厌氧池和缺氧池内的出气作为气源放回曝气池中,在缺氧环境下形成气升循环。好氧池为气提升三相循环流化床结构,不设沉淀池,MLSS高达10~12 g/L。 相似文献
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废报纸粉填充聚丙烯材料的研究 总被引:7,自引:3,他引:7
本文介绍废报纸粉填充聚丙烯(PP)的研制。通过在体系中加入高分子偶联剂马来酸酐(MAH)接枝PP(MAPP)来改善纸粉与PP基体的相容性,并针对纸粉填充后材料变脆的问题,用乙丙橡胶(EPDM)和乙烯醋酸乙烯共聚物(EVA)对材料进行增韧,均取得显著的效果。所制材料的纸粉填充量(质量分数)可高达50%~60%,价廉、质轻、其主要性能好于桑塔纳轿车用木粉填充PP板,可望有较好的应用前景。当纸粉填充量(质量分数)为40%~50%时,主要性能:弯曲强度69.01~74.83MPa,杨氏弯曲模量2640~2996MPa,冲击强度13.25~13.50kJ/m2。 相似文献
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A new NOx storage-reduction electrochemical catalyst has been prepared from a polycrystalline Pt film deposited on 8 mol% Y2O3-stabilized ZrO2 (YSZ) solid electrolyte. BaO has been added onto the Pt film by impregnation method. The NOx storage capacity of Pt-BaO/YSZ system was investigated at 350 °C and 400 °C under lean conditions. Results have shown that the electrochemical catalyst was effective for NOx storage. When nitric oxides are fully stored, the catalyst potential is high and reaches its maximum. On the other hand, when a part of NO and also NO2 desorb to the gas phase, the catalyst potential remarkably drops and finally stabilizes when no more NOx storage occurs but only the reaction of NO oxidation into NO2. Furthermore, the investigation has clearly demonstrated that the catalyst potential variation versus temperature or chemical composition is an effective indicator for in situ following the NOx storage-reduction process, i.e. the storage as well as the regeneration phase. The catalyst potential variations during NOx storage process was explained in terms of oxygen coverage modifications on the Pt. 相似文献
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KAMRAN AYKAN 《Journal of the American Ceramic Society》1968,51(10):577-581
The TiO2 -rich side of the system PbO-TiO2 was investigated by X-ray diffraction techniques, and a new compound PbTi3 O7 was found. It has a bimolecular monoclinic unit Cell with a = 10.732 A, b = 3.812 A, c = 6.578 A, and β= 98° 05'. The PbTi3 O7 decomposes into PbTiOs and rutile at temperatures above 850°C. The overall decomposition proceeds according to first-order kinetics with an apparent activation energy of about 170 kcal mole-1 . 相似文献
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针对焦化废水处理工程设计过程中极少涉及基于氰化物浓度变化与考察分析的实际问题,通过对已经运行的广东韶钢集团焦化废水处理工程统计数据的辨析,提出实现总氰化物高效去除的技术与运行强化方法。分析数据发现,在降解的过程中,氰化物滞后于酚类代表的有机物,络合氰的降解比游离氰慢,生物处理过程中由水力停留时间控制的碳源利用与金属离子的存在影响氰化物的降解,而A/O1/H/O2工艺在有效分配除碳过程与脱氮过程中实现了氰化物的高效降解。进一步工程实践证明,焦化废水处理全部指标达标的高效性可以通过充分考虑复杂组分降解动力学的协同与优化操作条件加以实现。 相似文献
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Liang Fang Heping Su Qian Yu Hui Zhang Bolin Wu 《Journal of the American Ceramic Society》2008,91(8):2769-2771
A high dielectric constant and low-loss ceramic with composition Sr4 LaTiNb3 O15 has been prepared by the conventional solid-state ceramic route. This compound adopts an A5 B4 O15 cation-deficient hexagonal perovskite structure and crystallizes in the trigonal system with unit cell parameters a =5.6307(2), c =11.3692(3) Å, V =312.16(2) Å3 , and Z =1. The dielectric properties of dense ceramics sintered in air at 1460°C have been characterized at microwave frequencies. The results show that the material affords a relatively high dielectric constant ɛr ∼43, a high quality factor Q × f ∼44 718 GHz, and a low temperature coefficient of resonant frequency TCf ∼13 ppm/°C. 相似文献
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A New Ternary Nanolaminate Carbide: Ti3 SnC2 总被引:1,自引:0,他引:1
Sylvain Dubois Thierry Cabioc'h Patrick Chartier Véronique Gauthier Michel Jaouen 《Journal of the American Ceramic Society》2007,90(8):2642-2644
We report on the synthesis of Ti n +1 SnC n (MAX phases) by hot isostatic pressing starting with titanium, tin, and carbon powders. In addition to the already known Ti2 SnC compound (211 MAX phase), a new 312 MAX phase, Ti3 SnC2 , is formed. Its lattice parameters, deduced from Rietveld analysis of X-ray diffraction patterns, are found to be a =0.31366 nm and c =1.8650 nm. 相似文献
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Fully dense aluminas, prepared by hot-pressing, were found to swell during annealing at 1600°C in air, but not during annealing in a reducing atmosphere (po2 = 10-7 Pa). The reaction followed the relation p - po = -K log t, where po and p are the initial and final densities, respectively, t is the time, and AT is a constant. The rate of swelling was enhanced by MgO solute. The reduction in density resulted from the nucleation and growth of grain-boundary pores. Pore formation was attributed to the reaction of carbon and sulfur impurities at the boundaries with oxygen, which had diffused down the grain boundaries from the ambient, to form CO/CO2 and SO2 gas at high pressures. Preliminary results indicate that this reaction can be avoided by preannealing powders in flowing oxygen prior to hot-pressing. The consequences of internal gas-forming reactions to other processes such as high-temperature creep and sintering are also discussed. 相似文献
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The hexagonal perovskite, Ba8 ZnTa6 O24 , was prepared in single-phase form and was found to be a stable secondary phase, formed as a result of the loss of ZnO from Ba(Zn1/3 Ta2/3 )O3 microwave dielectrics. The experimental and calculated X-ray patterns of Ba8 ZnTa6 O24 indicate it is isostructural with Ba8 Ta6 NiO24 with an 8H (cchc)2 close-packed BaO3 stacking sequence and the lattice parameters, a =10.0825(14), c =19.0587(38)Å. High-density ceramics of Ba8 ZnTa6 O24 could be prepared at temperatures considerably lower (1400°C) than those used to sinter pure Ba(Zn1/3 Ta2/3 )O3 , and exhibit very good microwave dielectric properties with ɛ=30.5, Q f =62 300, and τf =+36 ppm/°C at 8.9 GHz. 相似文献
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Oleg A. Shlyakhtin Young-Jei Oh 《International Journal of Applied Ceramic Technology》2009,6(2):312-323
The liquid phase sintering of fine BiNbO4 powders allows to obtain dense ceramics with excellent microwave dielectric properties (ɛ=44–46; Q × f =16,500–21,600 GHz) at T ≥700°C. The thermal decomposition of freeze-dried precursors results in the crystallization of a metastable β'-BiNbO4 polymorph that transforms into a stable orthorhombic α-modification at T ≥700°C. The dependence of sinterability on the powder synthesis temperature shows the maximum at 600°C, corresponding to the formation of crystalline BiNbO4 powders with a grain size 80–100 nm. Sintering temperature reduction to 700°C prevents the deterioration of silver contacts during co-firing with BiNbO4 ceramics. In situ scanning electron microscopy observation of the morphological evolution during sintering shows that the intense shrinkage soon after the appearance of a CuO–V2 O5 eutectics-based liquid phase is accompanied by complete transformation of the ensemble of primary BiNbO4 particles. 相似文献
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本文研究了AS/EVA/NBR共混体系性能与组成比,形态结构的关系;并研究了NBR组成对共混体系性能的影响。结果表明EVA可作为AS与NBR的相容剂;适量EVA可以大幅度提高共混物的冲击韧性,且可改善制品外观;共混物具有优良的常,低温冲击韧性。较好的其它力学性能性。TEM观察结果揭示EVA的加入可使NBR颗粒分布均匀,粒径变小;部分EVA处于NBR颗粒与AS基本相界面上,起着相容的作用。 相似文献
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Ahmed G. Solomah Reinhard Odoj Christoph Freiburg 《Journal of the American Ceramic Society》1983,66(10):c182-c183
A new identification and indexing for the phase BaAl2 Ti5 O14 were accomplished using an X-ray diffraction technique. The new lattice parameters for the tetragonal lattice structure are: a0 =9.990 × 10-10 m and c0 =12.264 × 10-10 m, with a corresponding volume 1.224 × 10-27 m3 . The data provided by the Joint Committee on Powder Diffraction Standards are inconsistent both in lattice parameter values and Miller indices. The X-ray powder diffraction pattern of BaAl2 Ti5 O14 was indexed using the LSUCR (least-squares unit cell refinement) computer program. 相似文献
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《国际聚合物材料杂志》2012,61(2):86-91
A novel strategy was developed for one-step synthesis of PANI/gold nanoconjugates to develop new resistant penicillin G molecules. Spherical monodispersed PANI/gold colloids were prepared by a photochemical reaction between aqueous gold chloride solution and acidic polyaniline solution. Functionalized PANI/gold colloids were then grafted to the C3 carboxyl group of the β lactam ring of penicillin in the presence of N-(3-dimethylaminopropyl)-N′-ethylcarbodiimide hydrochloride (EDAC) with a conjugation yield of 175 µg mg?1. These novel gold penicillin G nanoconjugates showed a very good growth inhibition against β lactam resistant Staphylococcus aureus (gram positive). This work thus describes a novel strategy for one step synthesis of PANI/gold colloids to develop resistant antibiotic nanoconjugates as novel bactericidal materials. 相似文献
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The creep rate in MgO-fluxed hot-pressed Si3 N4 is calculated by means of a model which assumes a solution-precipitation mechanism, and by using the kinetic data for the dissolution rate of β-Si3 N4 in an Mg-Si-O-N glass (which was obtained in independent experiments). Despite simplifying assumptions, the predictions match quite favorably with experimental measurements of creep in hot-pressed Si3 N4 . 相似文献
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Pure cubic perovskites Ba(Na2/5 W3/5 )O3 , Sr(Na2/5 W3/5 )l5)O3 , and Sr(Li2/5 W3/5 )O3 were prepared by solid-state reaction at 600° to 650°C in air, by starting with oxides or carbonates of the various elements. The cubic forms have an ordered arrangement of the B cations in the ABO3 structure, and the lattice constants are a =0.8324 nm [Ba(Na2/5 W3/5 )O3 ], 0.8136 nm Sr(Na2/5 W3/5 )O3 ], and 0.7958 nm [Sr(Li2/5 W3/5 )O3 ] 相似文献
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Fred J. Parker 《Journal of the American Ceramic Society》1990,73(4):929-932
The characterization and properties of ceramic composites containing the phases Al2 TiO5 , ZrTiO4 , and ZrO2 are described. The range of compositions investigated gives very low average thermal expansions (α24–1000°C as low as −2.0 × 10−6 °C−1 ) and excellent high-temperature stability. The low thermal expansions are apparently due to a combination of microcracking by the titanate phases and a contractive phase transformation by the ZrO2 . The crystal chemistry and microstructure of the product are processing dependent. Although the composites represent a complex microcracking system, the low thermal expansions and high-temperature stability make them potential candidates for commercial applications requiring thermal shock resistance. 相似文献