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1.
Shizhen Zhao Xun Song Xiuming Bu Chong Zhu Gang Wang Fang Liao Siwei Yang Miao Wang 《应用聚合物科学杂志》2017,134(18)
Because of the great demand for fluorescent materials, fluorescent dyes, semiconductor quantum dots, and carbon‐based quantum dots have been studied extensively. However, the poor photostability and potential biological toxicity need to be resolved. In this study, we demonstrated the synthesis of a new biomass quantum dot, the polydopamine dot (PDADs), via a simple hydrothermal method under an acidic environment. This new biomass quantum dot showed not only remarkable photoluminescence properties (quantum yield = 0.93) but also a high stability and low toxicity. Moreover, these PDADs could be used as a fluorescent probe for the rapid detection of Cr(VI) (response time = 0.01 s). The detection limit (1 × 10?11 M ) is the lowest detection limit reported for Cr(VI) fluorescent probes. The mechanism efficient quenching progress could have been due to the fast redox progress between the PDADs and Cr(VI). Moreover, we also showed a practical application of PDADs for Cr(VI) detection in vitro . © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134 , 44784. 相似文献
2.
Trisita Ghosh Rajkumar Sahoo Suman Kumar Ghosh Pallab Banerji Narayan Ch. Das 《Frontiers of Chemical Science and Engineering》2023,17(5):536
The past decade has witnessed a variety of members of the carbon family along with exposure of carbon dots due to their magnificent properties in sensing, bioimaging, catalytic applications, biomedical fields, and so on. Herein, we report the simple hydrothermal method to fabricate photoluminescent doped carbon quantum dots for the detection of noxious lead(II) ions. Lead(II) ion is very venomous for both the environment and human health for which its detection is demanded area in the research field. The as-prepared carbon dots show excellent photostability, low toxicity and significant photoluminescence properties along with good water solubility. Along with these properties, carbon dots have a quantum yield of approximately 15%. In the practical field of application, these carbon dots have been used as sensing probes for the detection of lead(II) ions with a detection limit of 60 nmol·L–1. The fluorescence intensity of carbon dots was remarkably quenched in the presence of the lead(II) ion selectively among all the tested metal ions. Furthermore, we have studied the Stern–Volmer relationship for lead(II) quenching along with the explanation of the probable quenching mechanism. Ability of the doped carbon dots in heavy metal ions sensing in an environmental sample was demonstrated. 相似文献
3.
Gabriele Rainò Giuseppe Visimberga Abdelmajid Salhi Maria T. Todaro Massimo De Vittorio Adriana Passaseo Roberto Cingolani Milena De Giorgi 《Nanoscale research letters》2007,2(10):509-511
We have investigated the ultra-fast carrier dynamics in Molecular Beam Epitaxy (MBE)-grown InAs/InGaAs/GaAs quantum dots (QDs)
emitting at 1.3 μm by time resolved photoluminescence (TRPL) upconversion measurements with a time resolution of about 200 fs.
Changing the detection energies in the spectral region from the energy of the quantum dots excitonic transition up to the
barrier layer absorption edge, we have found that, under high excitation intensity, the intrinsic electronic states are populated
mainly by carriers directly captured from the barrier. 相似文献
4.
Chuanxin Zhai Hui Zhang Ning Du Bingdi Chen Hai Huang Yulian Wu Deren Yang 《Nanoscale research letters》2011,6(1):31
We developed a novel one-pot polyol approach for the synthesis of biocompatible CdSe quantum dots (QDs) using poly(acrylic
acid) (PAA) as a capping ligand at 240°C. The morphological and structural characterization confirmed the formation of biocompatible
and monodisperse CdSe QDs with several nanometers in size. The encapsulation of CdS thin layers on the surface of CdSe QDs
(CdSe/CdS core–shell QDs) was used for passivating the defect emission (650 nm) and enhancing the fluorescent quantum yields
up to 30% of band-to-band emission (530–600 nm). Moreover, the PL emission peak of CdSe/CdS core–shell QDs could be tuned
from 530 to 600 nm by the size of CdSe core. The as-prepared CdSe/CdS core–shell QDs with small size, well water solubility,
good monodispersity, and bright PL emission showed high performance as fluorescent cell labels in vitro. The viability of
QDs-labeled 293T cells was evaluated using a 3-(4,5-dimethylthiazol)-2-diphenyltertrazolium bromide (MTT) assay. The results
showed the satisfactory (>80%) biocompatibility of as-synthesized PAA-capped QDs at the Cd concentration of 15 μg/ml. 相似文献
5.
Vilius Poderys Marija Matulionyte Algirdas Selskis Ricardas Rotomskis 《Nanoscale research letters》2011,6(1):9-6
Semiconductor nanoparticles (quantum dots) are promising fluorescent markers, but it is very little known about interaction
of quantum dots with biological molecules. In this study, interaction of CdTe quantum dots coated with thioglycolic acid (TGA)
with bovine serum albumin was investigated. Steady state spectroscopy, atomic force microscopy, electron microscopy and dynamic
light scattering methods were used. It was explored how bovine serum albumin affects stability and spectral properties of
quantum dots in aqueous media. CdTe–TGA quantum dots in aqueous solution appeared to be not stable and precipitated. Interaction
with bovine serum albumin significantly enhanced stability and photoluminescence quantum yield of quantum dots and prevented
quantum dots from aggregating. 相似文献
6.
V. G. Melekhin E. V. Kolobkova A. A. Lipovskii V. D. Petrikov A. M. Malyarevich V. G. Savitsky 《Glass Physics and Chemistry》2008,34(4):351-355
A new fluorophosphate glass matrix containing PbSe quantum dots characterized by a narrow size distribution (ΔR/R ∼ 5–7%, where R is the size of a quantum dot) is prepared under heat treatment. It is demonstrated that fluorophosphate glasses can be doped
by introducing (ZnSe + PbO) or PbSe into the composition of the glass. The optical absorption spectra of the quantum dots
corresponding to the strong quantum confinement regime are studied over a wide range of quantum-dot sizes (4–18 nm). The nonlinear
optical absorption is investigated at a wavelength of 1.54 μm. It is revealed that the introduction of (ZnSe + PbO) rather
than of PbSe into the composition of the glass improves the bleaching contrast owing to a more uniform distribution of the
quantum dots over the volume of the glass sample. 相似文献
7.
In order to couple high cellular uptake and target specificity of dendrimer molecule with excellent optical properties of
semiconductor nanoparticles, the interaction of cysteine-capped CdTe quantum dots with dendrimer was investigated through
spectroscopic techniques. NH2-terminated dendrimer molecule quenched the photoluminescence of CdTe quantum dots. The binding constants and binding capacity
were calculated, and the nature of binding was found to be noncovalent. Significant decrease in luminescence intensity of
CdTe quantum dots owing to noncovalent binding with dendrimer limits further utilization of these nanoassemblies. Hence, an
attempt is made, for the first time, to synthesize stable, highly luminescent, covalently linked CdTe–Dendrimer conjugate
in aqueous medium using glutaric dialdehyde (G) linker. Conjugate has been characterized through Fourier transform infrared
spectroscopy and transmission electron microscopy. In this strategy, photoluminescence quantum efficiency of CdTe quantum
dots with narrow emission bandwidths remained unaffected after formation of the conjugate. 相似文献
8.
Chuanmiao Yan Fangqiong Tang Linlin Li Hongbo Li Xinglu Huang Dong Chen Xianwei Meng Jun Ren 《Nanoscale research letters》2010,5(1):189-194
This work described a continuous method to synthesize CdTe/CdS/ZnS core/shell/shell quantum dots. In an integrated system
by flawlessly combining the chemical aerosol flow system working at high temperature (200–300°C) to generate CdTe/CdS intermediate
products and an additional heat-up setup at relatively low temperature to overcoat the ZnS shells, the CdTe/CdS/ZnS multishell
structures were realized. The as-synthesized CdTe/CdS/ZnS core/shell/shell quantum dots are characterized by photoluminescence
spectra, X-ray diffraction (XRD), energy-dispersive X-ray spectra (EDS), transmission electron microscopy (TEM), and high-resolution
transmission electron microscopy (HRTEM). Fluorescence and XRD results confirm that the obtained quantum dots have a core/shell/shell
structure. It shows the highest quantum yield above 45% when compared to the rhodamine 6G. The core/shell/shell QDs were more
stable via the oxidation experiment by H2O2. 相似文献
9.
The fluorescence labeling of viruses is a useful technology for virus detection and imaging. By combining the excellent fluorescence properties of quantum dots (QDs) with the high affinity and specificity of aptamers, we constructed a QD-aptamer probe. The aptamer A22, against the hemagglutinin of influenza A virus, was linked to QDs, producing the QD-A22 probe. Fluorescence imaging and transmission electron microscopy showed that the QD-A22 probe could specifically recognize and label influenza A virus particles. This QD labeling technique provides a new strategy for labeling virus particles for virus detection and imaging. 相似文献
10.
Site-controlled InAs nano dots were successfully fabricated by a STMBE system (in situ scanning tunneling microscopy during
molecular beam epitaxy growth) at substrate temperatures from 50 to 430°C. After 1.5 ML of the InAs wetting layer (WL) growth
by ordinal Stranski–Krastanov dot fabrication procedures, we applied voltage at particular sites on the InAs WL, creating
the site where In atoms, which were migrating on the WL, favored to congregate. At 240°C, InAs nano dots (width: 20–40 nm,
height: 1.5–2.0 nm) were fabricated. At 430°C, InAs nano dots (width: 16–20 nm, height: 0.75–1.5 nm) were also fabricated.
However, these dots were remained at least 40 s and collapsed less than 1000 s. Then, we fabricated InAs nano dots (width:
24–150 nm, height: 2.8–28 nm) at 300°C under In and As4 irradiations. These were not collapsed and considered to high crystalline dots. 相似文献
11.
Heyn C Klingbeil M Strelow C Stemmann A Mendach S Hansen W 《Nanoscale research letters》2010,5(10):1633-1636
We study the optical emission of single GaAs quantum dots (QDs). The QDs are fabricated by filling of nanoholes in AlGaAs
and AlAs which are generated in a self-assembled fashion by local droplet etching with Al droplets. Using suitable process
parameters, we create either uniform QDs in partially filled deep holes or QDs with very broad size distribution in completely
filled shallow holes. Micro photoluminescence measurements of single QDs of both types establish sharp excitonic peaks. We
measure a fine-structure splitting in the range of 22–40μeV and no dependence on QD size. Furthermore, we find a decrease
in exciton–biexciton splitting with increasing QD size. 相似文献
12.
Di D Perez-Wurfl I Gentle A Kim DH Hao X Shi L Conibeer G Green MA 《Nanoscale research letters》2010,5(11):1762-1767
As an important step towards the realisation of silicon-based tandem solar cells using silicon quantum dots embedded in a
silicon dioxide (SiO2) matrix, single-junction silicon quantum dot (Si QD) solar cells on quartz substrates have been fabricated. The total thickness
of the solar cell material is 420 nm. The cells contain 4 nm diameter Si quantum dots. The impacts of post-metallisation treatments
such as phosphoric acid (H3PO4) etching, nitrogen (N2) gas anneal and forming gas (Ar: H2) anneal on the cells’ electrical and photovoltaic properties are investigated. The Si QD solar cells studied in this work
have achieved an open circuit voltage of 410 mV after various processes. Parameters extracted from dark I–V, light I–V and circular transfer length measurement (CTLM) suggest limiting mechanism in the Si QD solar cell operation and possible
approaches for further improvement. 相似文献
13.
DNA microarrays are powerful tools for the high throughput analysis of nucleic acids due to their parallel detection capabilities. To realize the apparent power of DNA microarray, an efficient assay format is essential and a variety of assay formats have been developed for nucleic acid detection on microarrays. Many of them employ fluorescence-based methods because fluorescence detection is straightforward and easy to implement. Herein we broadly review fluorescence-based assay formats with a focus on PCR-associated target preparation. For the heterogeneous assay of nucleic acid on DNA microarrays, sensitivity is one of the most important factors and special emphasis has been given to recently developed signal amplification strategies aimed at achieving high sensitivity. 相似文献
14.
We report the observation of coupling of single InGaAs quantum dots with the surface plasmon resonance of a metal nanocrystal,
which leads to clear enhancement of the photoluminescence in the spectral region of the surface plasmon resonance of the metal
structures. Sharp emission lines, typical for single quantum dot emission, are observed, whereas for reference samples, only
weak continuous background emission is visible. The composite metal–semiconductor structure is prepared by molecular beam
epitaxy utilizing the principle of strain-driven adatom migration for the positioning of the metal nanocrystals with respect
to the quantum dots without use of any additional processing steps. 相似文献
15.
Within the framework of adiabatic approximation, the energy levels and direct interband light absorption in a strongly prolated
ellipsoidal quantum dot are studied. Analytical expressions for the particle energy spectrum and absorption threshold frequencies
in three regimes of quantization are obtained. Selection rules for quantum transitions are revealed. Absorption edge and absorption
coefficient for three regimes of size quantization (SQ) are also considered. To facilitate the comparison of obtained results
with the probable experimental data, size dispersion distribution of growing quantum dots by the small semiaxe in the regimes
of strong and weak SQ by two experimentally realizing distribution functions have been taken into account. Distribution functions
of Lifshits–Slezov and Gaussian have been considered. 相似文献
16.
17.
Background
The recent advance in nanomaterial research field prompts the development of diagnostics of infectious diseases greatly. Many nanomaterials have been developed and applied to molecular diagnostics in labs. At present, the diagnostic test of human papillomavirus (HPV) relies exclusively on molecular test. Hereon, we report a rapid and facile quantum dots (QDs) and superparamagnetic nanoparticle-based hybridization assay for the detection of (HPV) 16 infections which combines the merits of superparamagnetic nanoparticles and QDs and wholly differs from a conventional hybridization assay at that the reaction occurs at homogeneous solution, and total time for detection is no more than 1 h.Methods
The probes were labeled with superparamagnetic nanoparticles and QDs. Sixty cervical swab samples were used to perform a hybridization assay with these probes, and the results were compared with type-specific polymerase chain reaction (PCR) method.Results
The statistic analysis suggests that there is no significant difference between these two methods. Furthermore, this method is much quicker and easier than the type-specific PCR method.Conclusion
This study has successfully validated the clinical performance of our hybridization assay. The advantages in the time of detection and ease of process endow this method with great potential in clinical usage, especially mass epidemiological screening. 相似文献18.
Qun Wang Futian Liu Qinghui Jiang Xuejiao Sun Dongzhi Wang 《Journal of Inorganic and Organometallic Polymers and Materials》2012,22(1):27-31
Fe3O4@SiO2@ZnSe composite nanoparticles with superparamagnetism and luminescence have been prepared by a facile chemical method. Nontoxic
fluorescent ZnSe quantum dots were assembled around the Fe3O4-silica core–shell nanocomposite via chemical bonds formed between –COOH and –NH2. Transmission electron microscopy images show that the nanocomposites are approximately spherical and between 50 nm and 80 nm
in size. The bifunctional nanocomposites exhibit superparamagnetic behavior and good fluorescence intensity. Magnetic attraction
test, vibrating sample magnetometer at 300 K, UV–visible absorption and fluorescence emission spectroscopy were applied to
characterize the magnetic/fluorescent properties of the nanocomposites. 相似文献
19.
使用微流控技术连续合成CdSe@ZnS核壳型量子点,并使用巯基丙酸对其进行表面改性,制备出可以被铜离子淬灭的水溶性CdSe@ZnS核壳型量子点。随后以聚乙烯醇(PVA)水凝胶为骨架,将改性后的量子点通过氢键作用力负载于骨架上,得到制备工艺简单、热稳定性高的复合荧光传感器件。该传感器的荧光强度随水溶液中铜离子浓度呈线性负相关关系,检测灵敏度可达20 μmol/L。其简便的操作和敏感的响应使之与原子吸收分光光度法形成优势互补,适用于水体铜离子污染的原位检测。该负载方法具有一定普适性,提供了将任意量子点制成器件应用于某种金属离子检测的新方式,实现了可回收的、环境友好的重金属离子快速检测目的。 相似文献