激光和等离子体处理对复合材料表面涂层附着力的影响研究

为了提高环氧涂料在纤维增强聚丙烯复合材料上的附着力,采用激光和等离子体表面前处理方法,应用超景深显微镜、粗糙度测定仪、接触角测试仪以及附着力测试仪,研究了激光和等离子体表面处理对纤维增强聚丙烯复合材料表面形貌、表面粗糙度和表面水接触角的影响,并且探究了这2种表面处理方式对环氧涂层在复合材料上附着力的影响。结果表明:2种处理方式均可明显提高环氧涂层在基材上的附着力,附着力均可由不到1 MPa提高至8 MPa以上。     

激光处理对玻璃纤维增强复合材料与涂层间附着力的影响研究

为了提高民机玻璃纤维增强复合材料（ GFRP）与表面涂层之间的附着力,采用波长为 1 064 nm的红外脉冲激光对 GFRP基体进行表面处理。通过不同激光功率与传统 240目砂纸手工打磨工艺的对比,采用扫描电镜、 3D光学表面轮廓仪、接触角测量仪等,研究了不同处理方式对 GFRP基体微观形貌、粗糙度、水接触角的影响。结果表明：激光功率达到最大功率的 40%、60%、80%时,能获得较粗糙的微观表面、较低的水接触角和高的表面浸润性,而且激光表面处理比手工打磨 GFRP基体的附着力提升效果更显著。从效果和能耗考虑,选取最大功率（ 120 W）的 40%进行激光表面处理时, GFRP基体与涂层之间附着性能最佳。     

低温等离子体对ＰＢＯ纤维表面改性的研究

 为提高ＰＢＯ纤维／环氧树脂复合材料的剪切强度,采用低温等离子体结合涂层技术对聚对苯撑苯并双唑（ＰＢＯ）纤维进行表面改性,分别用ＳＥＭ、ＩＲ对等离子体处理前后纤维表面形态、化学结构进行了表征,通过复合材料层间剪切强度测试,研究不同处理方式对复合材料层间剪切强度的影响。结果表明,等离子体处理后纤维表面粗糙度增加,极性增强。经低温等离子体结合涂层技术处理后,ＰＢＯ纤维／环氧树脂复合材料的层间剪切强度得到显著提高,较未处理样品提高了３９％。     

等离子体表面处理对木塑复合材料涂饰性能的影响

为改善聚丙烯基木塑复合材料表面与涂料之间的附着效果,利用等离子体处理技术,对其表面进行处理。采用接触角测试、傅立叶变换红外光谱分析(FTIR)以及X射线光电子能谱分析(XPS)对处理前后复合材料表面的性能变化进行了分析,同时采用自动附着力测试仪对等离子体处理后复合材料表面与丙烯酸聚氨酯水性漆的附着效果进行了测试。研究结果表明,经等离子体处理后,聚丙烯基木塑复合材料的表面接触角减小,表面润湿性得到改善,表面有-OH、-C=O和-O-C=O等新官能团生成;XPS分析表明,经等离子体处理后,材料表面氧含量增加。漆膜附着力测试表明,等离子体处理后材料表面与丙烯酸聚氨酯水性漆的漆膜附着力有显著提高。     

钢材表面处理工艺对环氧涂层附着力的影响

海洋工程涂层保护性能的强弱与涂装作业前钢材表面处理质量的好坏有直接关系。基于此,寻找那些可以使钢材表面获得高附着力的表面处理工艺是相当有必要的。环氧涂层为本文的实验对象,通过试验数据分析钢材表面采用的不同喷砂工艺和粗糙度的关系,继而进一步分析粗糙度的变化对环氧涂层附着力变化的影响。     

民机铝合金蒙皮的激光织构化处理

采用波长为1064 nm的激光表面处理设备在2024-T3铝合金表面刻蚀出平行线、正方形和菱形这3种织构表面。采用扫描电子显微镜与激光共聚焦显微镜观察了不同织构表面的微观形貌。通过测量对水和甘油的接触角来评价它们的浸润性。用拉脱法测试了其表面环氧涂层的附着力。结果表明,在单位面积能量密度相同的情况下,表面织构为正方形和菱形的试样表面粗糙度由处理前的1.9μm分别提升至7.6μm和7.9μm,表现出更好的浸润性,环氧涂层的附着力比未处理试样提高了70%左右,而平行线织构表面的涂层附着力只提高了24%。通过金相观察、强度失效分析及硬度测试发现,织构化处理对飞机蒙皮的力学性能基本没有影响。     

环氧粉末涂层对金属基材附着力的影响因素

环氧粉末涂料具有附着力好、耐腐蚀性强、耐温性能好等优点，在金属防腐特别是重防腐领域应用非常广泛。在环氧粉末涂层的诸多性能中，涂层对基材的附着力是非常重要的一项技术指标，也是满足其他性能的基础，附着力的好坏直接影响着涂层对基材的保护寿命。本文主要从喷涂温度、基材表面处理的表面粗糙度以及粉末涂料原材料等方面讨论了环氧涂层对金属基材表面附着力的影响因素。研究表明：喷涂温度提高有利于涂层附着力的提高，表面粗糙度提高且锚纹深度相对均匀有利于涂层附着力的提高，填料以及助剂的种类对附着力具有一定的影响。     

激光扫描间距对民机铝合金蒙皮涂层附着力的影响

通过提高飞机铝合金蒙皮表面的粗糙度和浸润性，从而提升蒙皮表面涂层的附着力，采用 1 064 nm波长激光设备对 2024-T3铝合金试样进行表面处理，通过扫描电子显微镜表征及力学性能分析确定最佳的激光功率参数。通过单因素法改变激光扫描间距处理试样表面，对试样进行金相与强度失效分析以及硬度测试，并测试试样表面的粗糙度和接触角，以及喷涂后涂层的附着力。结果表明：随扫描间距的减小，接触角逐渐减小，粗糙度逐渐增大，铝合金蒙皮表现出更好的浸润性。扫描间距为 0. 05 mm时涂层附着力提升最大，相较于原始表面，提升了 80%。说明适当参数的激光表面处理可以在不影响试样力学性能的情况下有效提升涂层附着力。     

氨气等离子体接枝环氧涂层改性芳纶Ⅲ表面

采用氨气等离子体接枝环氧涂层工艺对芳纶Ⅲ进行表面改性,采用红外光谱、扫描电镜、原子力显微镜等对改性前后纤维表面的化学组成、形貌、粗糙度、浸润性能进行了研究。结果表明:经氨气等离子体接枝环氧涂层处理后,环氧树脂涂层能够以化学键形式接枝到芳纶Ⅲ表面,同时纤维表面的粗糙度有了明显的增加,浸润性得到显著的改善。     

空气介质阻挡放电等离子体对国产芳纶ⅢA表面改性的研究

采用空气介质阻挡放电等离子体对国产芳纶ⅢA进行表面处理,优化了其处理工艺。用SEM、XPS等方法研究了处理前后纤维表面形态和化学状态的变化,通过短梁剪切试验评价了芳纶ⅢA/环氧复合材料的抗层间剪切强度。结果表明:经空气等离子体处理后芳纶ⅢA表面粗糙度增加,极性增强,纤维力学性能无明显变化,芳纶ⅢA/环氧复合材料的抗层间剪切强度提高了18%。     

Investigation of accumulated laser fluence and bondline thickness effects on adhesive joint performance of CFRP composites

In the present study, both the effects of accumulated laser fluence as surface treatment and bondline thickness on adhesive bonding of carbon fiber reinforced polymer (CFRP) composite materials were investigated. Proper CFRP composite surfaces for adhesive bonding were obtained by a laser treatment process using pulsed CO₂ laser. Laser treatments were obtained with different accumulated laser fluences and then surfaces were analyzed with roughness and contact angle measurements. Adhesive bonding was performed with various bondline thicknesses ranged between 30–500 µm using two component structural epoxy based paste adhesive (Loctite Hysol ® EA 9396^TM). Adhesive bonding strength of bonded samples was determined with single lap shear tests. It is worthy to note that if the accumulated laser fluence which has significant effect on shear strength does not optimize, it causes ineffective adhesion.     

Influence of plasma treatment on properties of ramie fiber and the reinforced composites

In this research, 9 series of ramie fibers were treated under low-temperature plasma with diverse output powers and treatment times. By analysis of the surface energy and adhesion power with epoxy resin, 3 groups as well as control group were chosen as reinforced fibers of composites. The influences of these parameters on the ramie fiber and its composites such as topography and mechanical properties were tested by scanning electron microscopy (SEM), atomic force microscopy (AFM), tensile property and fragmentation test of single-fiber composites. Contact angle and surface free energy results indicated that with the increased treatment times and output powers, surface energy and adhesion work with epoxy resin improved. Compared with the untreated fibers, surface energy and adhesion work with epoxy resin grew 124.5 and 59.1% after 3 min-200 w treatment. SEM and AFM showed low temperature plasma treatment etched the surface of ramie fiber to enhance the coherence between fiber and resin, consequently fiber was not easy to pull-out. After 3 min-200 w treatment, tensile strength of ramie fiber was 253.8 MPa, it had about 30.5% more than that of untreated fiber reinforced composite. Interface shear stress was complicated which was affected by properties of fiber, resin and interface. Fragmentation test showed biggest interface shear stress achieved 17.2 MPa, which represented a 54.0% increase over untreated fiber reinforced composites.     

Surface modification of armos fibers with oxygen plasma treatment for improving interfacial adhesion with poly(phthalazinone ether sulfone ketone) resin

We introduce in this article oxygen plasma treatment as a convenient and effective method for the surface modification of Armos fibers. The effects of oxygen‐plasma‐treatment power on both the Armos fiber surface properties and Armos‐fiber‐reinforced poly(phthalazinone ether sulfone ketone) composite interfacial adhesion were investigated. The Armos fiber surface chemical composition, surface morphology and roughness, and surface wettability as a function of oxygen‐plasma‐treatment power were measured by X‐ray photoelectron spectroscopy, scanning electronic microscopy, atomic force microscopy, and dynamic contact angle analysis. The results show that oxygen plasma treatment introduced a lot of reactive functional groups onto the fiber surface, changed the surface morphology, increased the surface roughness, and enhanced the surface wettability. Additionally, the effect of the oxygen‐plasma‐treatment power on the composite interfacial adhesion was measured by interlaminar shear strength with a short‐beam bending test. Oxygen plasma treatment was an effective method for improving the composite interfacial properties by both chemical bonding and physical effects. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

硅烷偶联剂处理木塑复合材胶接接头的耐水性

利用硅烷偶联剂KH560对木粉/聚乙烯复合材料进行表面处理以改善其胶接性能。利用接触角、吸水量、表面形貌以及胶接强度测试等分析方法,研究了硅烷偶联剂处理聚乙烯木塑复合材料胶接接头在水环境中的胶接耐久性能。试验结果表明,机械打磨并偶联剂处理后,聚乙烯木塑复合材表面接触角增加,表面粗糙度增大,胶接强度和耐水性明显提高。偶联剂分子链上环氧基团的"架桥"作用以及甲氧基的憎水作用,是粘接强度和耐水性能提高的主要原因。浸水环境下,聚乙烯木塑复合材料表面粗糙度略有降低;随着浸水时间的延长,表面接触角下降,胶接接头的吸水量增加,胶接强度下降。水环境下聚乙烯木塑复合材料中木质纤维成分的吸水膨胀,是造成胶接强度下降的主要原因。     

界面结合对GF/PDCPD复合材料性能的影响

界面结合性能对制备性能优异的复合材料具有重要意义。通过对双环戊二烯（DCPD）与玻璃纤维（GF）的浸润性进行研究，将其与等效环氧树脂比较，开发了一种与玻璃纤维具有较好结合性的DCPD树脂，用其制备出一种综合性能优异的玻璃纤维增强PDCPD基复合材料。通过动态接触角、90?拉伸强度和层间剪切强度实验，测定了不同树脂与玻璃纤维之间的粘附力，提供了玻璃纤维与不同树脂界面性能差异。结果表明，SCB-600 DCPD树脂与玻璃纤维的结合性较优，动态接触角为60.35??0.3?，90?拉伸强度为(42.3?1.6) MPa，层间剪切强度为(61.3?3.2) MPa，与1564环氧树脂相当。进一步优化了DCPD树脂质量分数，当树脂质量分数为30%?2%时，SCB-600 DCPD复合材料具有相对最优的力学性能，材料拉伸强度为(1180.1?4.1) MPa，弯曲强度为(1060.4?4.6) MPa，缺口冲击强度为(145.3?4.8) KJ/m2。其弯曲和拉伸强度与玻璃纤维增强环氧树脂基复合材料的性能基本相当，但缺口冲击强度优于1564环氧树脂。     

Influence of oxygen plasma treatment on interfacial properties of poly(p‐phenylene benzobisoxazole) fiber‐reinforced poly(phthalazinone ether sulfone ketone) composite

The influence of oxygen plasma treatment on both surface properties of poly(p‐phenylene benzobisoxazole) (PBO) fibers and interfacial properties of PBO fiber reinforced poly(phthalazinone ether sulfone ketone) (PPESK) composite were investigated. Surface chemical composition, surface roughness, and surface morphologies of PBO fibers were analyzed by X‐ray photoelectron spectroscopy (XPS), Atomic force microscopy (AFM), and scanning electron microscopy (SEM), respectively. Surface free energy of the fibers was characterized by dynamic contact angle analysis (DCAA). The interlaminar shear strength (ILSS) and water absorption of PBO fiber‐reinforced PPESK composite were measured. Fracture mechanisms of the composite were examined by SEM. The results indicated that oxygen plasma treatment significantly improved the interfacial adhesion of PBO fiber‐reinforced PPESK composite by introducing some polar or oxygen‐containing groups to PBO fiber surfaces and by fiber surface roughening. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009     

Long-term hydrophobicity and ice adhesion strength of latex paints containing silicone oil microcapsules

Waterborne anti-icing coatings were prepared by embedding silicone oil microcapsules in latex paints. The long-term hydrophobicity and ice adhesion strength of the coatings were examined with a QUV accelerated weathering tester and a pull-off adhesion tester. The effects of silicone oil content and pigment/binder (PB) ratio on the long-term hydrophobicity and the ice adhesion strength of the coatings were investigated. A higher silicone oil content and a PB ratio close to the critical pigment volume concentration favor long-term hydrophobicity of the coatings. An obvious decrease in ice adhesion strength was achieved for coatings with a PB ratio of 5.0 and a silicone oil content of 4.2%. For coatings with the same surface roughness, a higher water contact angle (WCA) led to lower ice adhesion strength. However, for coatings with different surface roughnesses, the ice adhesion strength was found to be dependent on surface roughness rather than on WCA.     

Polyurethane paint adhesion improvement on aluminium alloy treated by plasma jet and dielectric barrier discharge

The effect of atmospheric pressure plasma treatment on the adhesion between a protective coating and AA1100 alloy was investigated. Two plasma sources were used for surface modifications: atmospheric pressure plasma jet and dielectric barrier discharge. The surface roughness and water contact angle measurements were conducted in order to evaluate the changes on the aluminium surface after plasma processing. The paint coating was tested using the adhesion tape test (ASTM D3359). A significant improvement of surface wettability and adhesion was obtained after plasma treatments.     

Effect of plasma pretreatment on durability of sol-gel superhydrophobic coatings on laser modified stainless steel substrates

Superhydrophobic surfaces were generated on stainless steel SS 304 substrates, using a combination of physical as well as chemical modification of the surface and tested for use in biomedical applications. Nanosecond pulsed laser was used for physical modification, i.e. creating nanoscaled roughness on the substrates. An additional chemical modification was performed using fluorosilane-based sol-gel nanocomposite coatings to further improve the hydrophobicity. Presently, the key challenge that such surfaces face, is to possess a substantial durability. In this study, a surface activation technique such as plasma pre-treatment was adopted to improve the adhesion of coatings on the laser treated substrates. The coatings deposited using dip coating technique were cured at 150 °C. The surface morphology and the roughness of the processed substrates and the coated samples were characterized using Atomic Force Microscope and Scanning Electron Microscope. The wettability of the surface was monitored and evaluated throughout the study using water contact angle measurements. Weathering tests and scratch resistance measurements using a crockmeter were carried out to evaluate the durability, which revealed that the adhesion could be improved with plasma treatment of the laser textured substrates, prior to coating deposition. Maximum anti-bacterial activity of up to 90% towards the bacterial species Escherichia coli was found on the substrates coated with the fluorosilane-based superhydrophobic coatings for an exposure time of 30 min, without any addition of external anti-bacterial agents. Thus, the preliminary results obtained from the present investigation were found to be promising and were indicative of use of these surfaces for biomedical applications.     

芳纶纤维增强树脂基复合材料的界面粘结性能研究

为了改善芳纶纤维增强树脂基复合材料的界面粘结性能,从树脂基体入手,依据相似相容原理和芳纶的结构特点,合成出新型热固性树脂(AFR–T)用作芳纶复合材料的基体,以未经表面处理的芳纶作增强材料,采用热压成型法制备了AFR–T/芳纶纤维复合材料,并通过测定溶度参数、接触角、线膨胀系数、层间剪切强度(ILSS)和横向拉伸强度等方法研究了复合材料的界面粘结性能。结果表明,AFR–T树脂浇注体与芳纶的溶度参数相近,AFR–T树脂溶液在芳纶纸表面的接触角为36.9°,小于环氧树脂(EP)溶液与芳纶纸的接触角(53.2°),说明AFR–T树脂对芳纶的浸润性优于EP;AFR–T/芳纶纤维复合材料的ILSS和横向拉伸强度为73.0 MPa和25.3 MPa,分别比EP/芳纶纤维复合材料提高了25.9%和32.5%,这表明AFR–T树脂与芳纶纤维之间的浸润性和界面粘结性能较好。