Al膜的微孔阵列湿法腐蚀技术研究

微通道板(Microchannel Plate,MCP)是像增强器中实现电子倍增的关键器件。以硅为基体制备的微通道板相对于传统的微通道板在性能方面有很大的提高。在对硅进行反应离子深刻蚀(DRIE)前,需要对充当掩蔽层的金属铝膜进行湿法腐蚀。对于掩模图形为孔径10 m、孔间距5 m的大面阵的微孔阵列,在腐蚀过程中,微孔孔径较小导致溶液对流困难且反应生成物H2极易吸附在反应界面上,影响反应物质的输送和化学反应的进行。如果腐蚀参数不合适,阵列式微孔图形会出现随机腐蚀、不完全腐蚀、过腐蚀等现象。通过加入表面活性剂,减小溶液中表面应力,可以促使反应物H2排出。同时通过逐一控制变量,研究了腐蚀液浓度、腐蚀液温度和腐蚀时间对腐蚀结果的影响。结果表明,腐蚀速率与腐蚀液浓度、腐蚀液温度成正比。通过参数优化,得到了最佳的腐蚀参数。此时图形完整,尺寸准确,解决了微孔阵列的图形化问题。     

表面处理对液晶显示阵列基板中黑矩阵残留的影响

主要分析了黑矩阵残留程度与SiNx、SiON、SiOx等基底表面亲水特性的关系,研究了等离子体处理对基底表面亲水特性以及黑矩阵残留的影响。首先,通过原子力显微镜和扫描电子显微镜对黑矩阵在不同基底表面的残留颗粒大小、表面粗糙度进行了测试。然后,使用接触角测试仪对不同基底表面的亲水特性进行了表征,分析了表面亲水特性和黑矩阵残留程度的关系。最后,研究了等离子体处理条件对基底表面亲水特性的影响,提出了采用O2/He等离子体对基底表面进行改性来解决黑矩阵的残留问题。实验结果表明:基底表面的水接触角越小、亲水性越强,黑矩阵在基底表面的残留越少;O2/He等离子体表面处理使基底表面的水接触角从17°降低到3°,增强了基底表面的亲水特性,并且黑矩阵工艺之后基底表面的粗糙度从3.06nm降低到0.69nm,消除了黑矩阵的残留。     

铝基板表面氧化铝层分子自组装活化法镀铜

采用分子自组装活化法在铝基板表面氧化铝上实施化学镀铜,镀层有很好的剥离强度,通过SEM、EDS和离子色谱对其进行了表征。研究了硅烷化时间与基体表面硅烷修饰量的关系,浸钯时间对基体表面钯含量的影响,硅烷化时间对镀层剥离强度的影响。通过正交试验得到最佳工艺条件:硅烷化处理用3-氨基丙基三乙氧基硅烷,质量分数为0.4%,硅烷化时间12h、温度50℃、浸钯溶液活化时间30min、30℃;得到的镀铜层剥离强度为1.00。     

微通道板腐蚀工艺研究

根据微通道板芯皮料玻璃的性质,选择了腐蚀工艺的腐蚀液,即HCl和NaOH溶液.利用真空压差法和显微镜形貌分析法,检测和分析了微通道板腐蚀工艺中通道的腐蚀进程.在腐蚀过程中,利用测量微通道板质量损失法衡量了腐蚀的程度,并检查了腐蚀效果.依据实验结果分析,提出了有效的微通道板酸-碱-酸交替腐蚀工艺以及具体的工艺参数.采用此工艺,可使芯料和芯皮料扩散层被完全腐蚀,同时避免了皮料被腐蚀,得到了光滑的通道壁,形成稳定的二次电子发射层.     

化学腐蚀硅表面结构反射率影响因素的研究

单晶硅片在碱溶液中的腐蚀会引起表面结构的变化,利用紫外可见分光光度计测量硅片表面反射率,发现碱溶液的浓度、腐蚀时间、添加剂的选择（无水乙醇或异丙醇）以及添加剂的浓度均对硅片表面反射率有影响。比较几个因素发现碱溶液的浓度和腐蚀时间对硅片表面反射率影响最大。当腐蚀温度为80℃,NaOH固体浓度为15g/L,添加剂无水乙醇体积分数10%时,腐蚀30min得到硅片反射率最低,达到11.15%。     

三代微通道板记忆效应研究

针对三代微通道板在制作像增强器中出现的电子记忆效应现象进行分析,指出记忆效应的产生机理是通道内壁表面的多孔介质膜(PbO-Al2O3-SiO2系铅铝硅酸盐玻璃)引起的自激发射.分析了多孔介质膜的结构和形成原因,提出了采用调整玻璃材料中SiO2含量、优化金属氧化物的引入种类及数量改进通道内壁结构.工艺上采用减少皮料被酸碱腐蚀的时间和降低还原温度以减少多孔介质膜的形成.实验结果表明,采用新的材料配方,优化的三次酸碱腐蚀和520～560 ℃氢还原工艺消除了微通道板的记忆效应,提高了像增强器的信噪比.     

硅微通道板像增强器的研究

微通道板作为电子倍增器件可以对电子、离子、紫外和软X射线进行探测和成像.传统微通道板制备是采用玻璃纤维拉制和氢还原等技术,提出分别采用半导体体微加工和电化学腐蚀制备硅微通道板的新技术.在干法刻蚀中采用 ICP 技术制备了孔径为 6～20 μm、间隔4～8 μm、长径比 15～30 的硅微通道板,初步试验结果为对于长径比为 16 的样品,电子增益为 102 数量级.同时,开展了湿法电化学腐蚀技术制作硅微通道板的研究,分析讨论了电化学腐蚀微通道板的机理.结果表明,干法和湿法刻蚀技术可以制备高长径比硅微通道板,与 ICP 技术型比,电化学腐蚀具有较低的成本.     

硅抛光片表面疏水改性工艺研究

采用稀释HF溶液对亲水性的硅抛光片表面进行了疏水改性,并对HF腐蚀硅片表面氧化层、钝化表面的机理进行了分析。研究了HF溶液浓度和反应时间对硅抛光片表面颗粒度和接触角的影响,通过对比分析,得到了HF溶液疏水改性的最佳浓度和最佳反应时间,HF体积比为3%,反应时间为120 s时,HF能够与样品表面充分反应,并且二次吸附颗粒数量最少。采用兆声溢流方式可以大大减少样品表面吸附颗粒数量,而不影响疏水性能。     

纳秒激光诱导氧化钛片及涂层的润湿性研究

采用纳秒激光在纯钛片表面制备微织构,并辅助化学处理的方法,获得了类似"荷叶效应"且润湿稳定的超疏水表面。通过调整激光加工工艺参数,获得了具有不同润湿性的微纳米结构;在此基础上,采用全氟癸基三甲氧基硅烷和乙醇溶液的混合溶液在微结构表面制备涂层。采用扫描电子显微镜和能谱分析后可知钛板在激光作用下产生了多尺度的氧化钛多孔微结构;通过接触角测量表征进一步分析了钛片表面的亲水性与微纳米结构表面变化规律的关系,以及涂层对表面润湿性的影响,为生物医学药物输送方面的研究提供了参考。     

热处理对脉冲激光沉积羟基磷灰石薄膜组织和性能的影响

利用脉冲激光沉积技术在Ti6Al4V(TC4)合金表面制备了羟基磷灰石(HA)薄膜,研究了退火温度对薄膜组织和性能的影响。采用扫描电子显微镜(SEM)、能谱仪(EDS)、X射线衍射(XRD)和傅里叶红外光谱(FTIR)等分析手段对热处理前后薄膜的表面形貌、成分和组织结构进行了分析;采用轮廓仪、接触角测量仪分别对热处理前后薄膜的表面粗糙度和润湿性进行了测量。实验结果表明,利用脉冲激光沉积技术制备的HA薄膜致密、无缺陷,主要由非晶相组成。热处理后的薄膜结晶度提高、表面粗糙度增大,Ca/P比更接近于HA,具有更好的表面亲水性。但是过高的热处理温度(700℃)会导致薄膜中微裂纹的出现。     

Preparation and Characterization of TaN ALD Precursors

High purity organic-tantalum precursors for thin film ALD TaN were synthesized and characterized.Vapor pressure and thermal stability of these precursors were studied.From the vapor pressure analysis,it was found that TBTEMT has a higher vapor pressure than any other published liquid TaN precursor,including TBTDET,TAITMATA,and IPTDET.Thermal stability of the alkyl groups on the precursors was investigated using a 1H NMR technique.The results indicated that the tertbutylimino group is the most stable group on TBTDET and TBTEMT as compared to the dialkylamido groups.Thermal stability of TaN precursors decreased in the following order:TBTDET ＞ PDMAT ＞ TBTEMT.In conclusion,precursor vapor pressure and thermal stability were tuned by making slight variations in the ligand sphere around the metal center.     

Curved crystal spectrometer for the measurement of X-ray lines from laser-produced plasmas

In order to diagnose the laser-produced plasmas, a focusing curved crystal spectrometer has been developed for measuring the X-ray lines radiated from a laser-produced plasmas. The design is based on the fact that the ray emitted from a source located at one focus of an ellipse will converge on the other focus by the reflection of the elliptical surface. The focal length and the eccentricity of the ellipse are 1350 mm and 0.9586, respectively. The spectrometer can be used to measure the X- ray lines in the wavelength range of 0.2-0.37 nm, and a LiF crystal （200） （2d = 0.4027 nm） is used as dispersive element covering Bragg angle from 30° to 67.5°. The spectrometer was tested on Shengnang- Ⅱ which can deliver laser energy of 60-80 J/pulse and the laser wavelength is 0.35 μm. Photographs of spectra including the 1 s2p ^1P1-1s^2 ^1S0 resonance line（w）, the 1s2p ^3P2-1s^2 1S0 magnetic quadrupole line（x）, the 1s2p ^3P1-1 s^2 ^1S0 intercombination lines（y）, the 1 s2p ^3S~1-1 s^2 ^1S0 forbidden line（z） in helium-like Ti Ⅹ Ⅺ and the 1 s2s2p ^2P3/2-1 s622s ^2S1/2 line（q） in lithium-like Ti Ⅹ Ⅹhave been recorded with a X-ray CCD camera. The experimental result shows that the wavelength resolution（λ/△ 2） is above 1000 and the elliptical crystal spectrometer is suitable for X-ray spectroscopy.     

Electronic Structure of Semiconductor Nanocrystals

This paper reviews our recent development of the use of the large-scale pseudopotential method to calculate the electronic structure of semiconductor nanocrystals, such as quantum dots and wires, which often contain tens of thousands of atoms. The calculated size-dependent exciton energies and absorption spectra of quantum dots and wires are in good agreement with experiments. We show that the electronic structure of a nanocrystal can be tuned not only by its size,but also by its shape. Finally,we show that defect properties in quantum dots can be significantly different from those in bulk semiconductors.     

Critical Stage Rule-Based Real Time Dispatch（RTD）System in Highly-Mixed-Products （HMP） FAB

An improving utilization and efficiency of critical equipments in semiconductor wafer fabrication facilities are concerned. Semiconductor manufacturing FAB is one of the most complicated and cost sensitive environments. A good dispatching tool will make big difference in equipment utilization and FAB output as a whole. The equipment in this paper is In-Line DUV Scanner. There are many factors impacting utilization and output on this equipment group. In HMP environment one of the issues is changing of reticule in this area and idle counts due to load unbalance between equipments. Here we'll introduce a rule-based RTD system which aiming at decreasing the number of recipe change and idle counts among a group of scanner equipment in a high-mixed-products FAB.     

GaAsSb/InAlAs PA DHBTs Grown by Production MBE

The epi material growth of GaAsSb based DHBTs with InAlAs emitters are investigated using a 4 × 100mm multi-wafer production Riber 49 MBE reactor fully equipped with real-time in-situ sensors including an absorption band edge spectroscope and an optical-based flux monitor. The state-of-the-art hole mobilities are obtained from 100nm thick carbon-doped GaAsSb. A Sb composition variation of less than ± 0.1 atomic percent across a 4 × 100mm platen configuration has been achieved. The large area InAlAs/GaAsSb/InP DHBT device demonstrates excellent DC characteristics,such as BVCEO＞6V and a DC current gain of 45 at 1kA/cm2 for an emitter size of 50μm × 50μm. The devices have a 40nm thick GaAsSb base with p-doping of 4. 5 × 1019cm-3 . Devices with an emitter size of 4μm × 30μm have a current gain variation less than 2% across the fully processed 100mm wafer. ft and fmax are over 50GHz,with a power efficiency of 50% ,which are comparable to standard power GaAs HBT results. These results demonstrate the potential application of GaAsSb/InP DHBT for power amplifiers and the feasibility of multi-wafer MBE for mass production of GaAsSb-based HBTs.     

Noise character analysis and the restraint of self-pulsation laser diodes

We calculate the Langevin noise sources of self-pulsation laser diodes, analyze the effects of active region noise and saturable-absorption region noise on the power fluctuation as well as period fluctuation, and propose a novel method to restrain the noise effects. A visible SIMULINK model is established to simulate the system, The results indicate that the effects of noise in absorption region can be ignored; that with the increase of DC injecting current, the noise effects enhance power jitter, and nevertheless, the period jitter is decreased; and that with external sinusoidal current modulating the self-pulsation laser diode, the noise-induced power jitter and period jitter can be suppressed greatly. This work is valuable for clock recovery in all-optical network.     

High-quality single-crystal CdSe nanoribbons and their optical properties

Large-scale synthesis of single-crystal CdSe nanoribbons is achieved by a modified thermal evaporation method, in which two-step-thermal-evaporation is used to control CdSe sources＇ evaporation. The synthesized CdSe nanoribbons are usually several micrometers in width, 50 nm in thickness, and tens to several hundred micrometers in length. Studies have shown that high-quality CdSe nanoribbons with regular shapes can be obtained by this method. Room-temperature photolumines-cence indicates that the lasing emission at 710 nm has been observed under optical pumping （266 nm） at power densities of 25-153 kW/cm^2. The full width half maximum （FWHM） of the lasing mode is 0.67 nm     

Propagation of hermite-cosh-gaussian beams passing through ABCD optical system with an annular aperture

By using the expansion of the aperture function into a finte sum of complex Gaussian functions, the corresponding analytical expressions of Hermite-cosh-Gaussian beams passing through annular apertured paraxially and symmetrically optical systems written in terms of ABCD matrix were derived, and they could reduce to the cases with squared aperture. In a similar way, the corresponding analytical expressions of cosh-Gaussian beams through annular apertured ABCD matrix were also given. The method could save more calculation time than that by using the diffraction integral formula directly.     

Influence of polarization extinction ratio on distributed polarization coupling detection

Distributed polarization coupling in polarization-maintaining fibers can be detected by using a white light Michelson interferometer. This technique usually requires that only one polarization mode is excited. However, in practical measurement, the injection polarization direction could not be exactly aligned to one of the principal axes of the PMF, so the influence of the polarization extinction ratio should be considered. Based on the polarization coupling theory, the influence of the incident polarization extinction on the measurement result is evaluated and analyzed, and a method for distributed polarization coupling detection is developed when both two orthogonal eigenmodes are excited.     

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正Communications—VLSI Researches and industries of telecommunications have been growing rapidly in the last 20 years and will keep their high growing pace in the next decade.The involved researches and developments cover mobile communications,highway and last-mile broadband communication,domain specific communications,and emerging D2D M2M communications.Radio communication steps into its