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通过原位溶液聚合制备了聚苯胺/碳纳米管(PANI/CNT)复合材料。采用透射电子显微镜(TEM)、紫外-可见光光谱(UV-VIS)、傅立叶变换红外光谱(FTIR)、热失重分析(TGA)及差示扫描量热法(DSC)研究了PANI/CNT复合材料的结构与性能。研究表明,苯胺(ANI)的聚合倾向于在碳纳米管(CNT)表面进行,形成PANI包覆的CNT。CNT表面PANI层的厚度随溶液中ANI含量的增加而增加;当溶液中ANI含量较低时,CNT表面PANI层厚度均匀;当ANI含量过高时,CNT表面PANI层厚度不均匀,形成一些颗粒状附着物。PANI与CNT之间主要是物理吸附;PANI/CNT复合材料的电导率远高于PANI本身。同时,PANI/CNT复合材料的耐热性远高于PANI,并受PANI含量影响。 相似文献
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在室温下,采用化学原位聚合法制备得到超级电容器用导电聚苯胺(PANI),并采用扫描电子显微镜(SEM)和X-射线衍射(XRD)对其形貌和结构进行了表征.以制备的PANI为活性物质作为电极材料,1 mol/L Na2SO4水溶液为电解液组装成扣式超级电容器,通过循环伏安和恒电流充放电测试研究其电化学性能.结果表明,制备的... 相似文献
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用原位聚合和乳液聚合两种方法制备聚苯胺(PANI)包覆螺旋碳纤维(CMCs)复合材料,使用红外光谱(FTIR),扫描电子显微镜(SEM),X射线衍射(XRD)等手段对其形貌和结构进行了表征。结果表明,用硝酸处理CMCs(表示为H-CMCs)为纤维表面提供含有羧基等含氧官能团。这为苯胺在H-CMCs表面的聚合提供基础,有助于PANI附着在H-CMCs的表面。用循环伏安、恒流充放电、交流阻抗等电化学方法测试了复合材料的电化学特性,结果表明:PANI包覆H-CMCs,其比电容值明显高于H-CMCs自身,表现出良好的大电容性能。原位聚合法更有益于PANI与H-CMCs的协同作用,使复合体的电容性能提高。 相似文献
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为了研究聚苯胺(PANI)/银复合薄膜对不锈钢的防腐蚀性能,采用循环伏安法在不锈钢表面沉积一层Ag后,再通过对苯胺的电化学聚合制备了PANI膜。利用阳极极化法和交流阻抗法研究了PANI/Ag复合膜的耐蚀性及其影响因素。结果表明:在0.1 mol/L NaC l溶液中,不锈钢覆盖复合膜后的自腐蚀电位比无膜时有所提高,其耐蚀性能得到增强;电化学聚合溶液浓度、扫描速率及扫描上限等因素对复合膜耐蚀性的影响情况为:电解液中苯胺和硫酸浓度过高或过低都会影响膜的致密度,从而影响复合膜的耐蚀性;电化学参数的变化会影响复合膜的聚合速率,使复合膜的抗腐蚀能力不同;当苯胺单体浓度为0.2 mol/L、硫酸浓度为1 mol/L、扫描电位上限为1 V、扫描次数为50次、扫描速率为50 mV/s时,采用循环伏安法聚合苯胺,可形成沉积致密度高、耐蚀性好的复合膜。 相似文献
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利用静电纺丝技术制备聚氨酯(PU)纳米纤维,采用原位聚合法在纤维表面聚合导电聚合物聚苯胺(PANI),得到具有优良导电性能的柔性PU/PANI复合纳米导电纤维。通过扫描电镜观察到表面均匀包覆聚苯胺的复合纳米纤维;红外光谱结果证明在聚氨酯纳米纤维表面成功合成了聚苯胺。通过实验可知,聚苯胺最佳聚合工艺为苯胺单体浓度为1.3 mol/L、聚合时间为120 min。导电性能测试发现,PU/PANI复合纳米纤维导电性能优良,电导率可达7.6×10-1S/cm,经聚合后力学性能较为稳定。将PU/PANI导电纳米纤维制成简易柔性传感器件,探究发现PU/PANI导电纳米纤维具有柔性应变电学性质,且反应灵敏。 相似文献
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为合成树脂/聚苯胺(PANI)/多壁碳纳米管(MWCNTs)三元纳米复合电磁屏蔽材料的制备提供理论依据,在苯胺的盐酸溶液中,以过硫酸铵为氧化剂,采用原位聚合法制备PANI/MWCNTs纳米复合材料,并对PANI/MWCNTs纳米复合材料的结构、形貌以及热稳定性能进行研究。结果表明:PANI成功包覆在MWCNTs表面,且PANI和MWCNTs存在一定的相互作用;PANI在MWCNTs表面不均一性的有序生长,有效地改善了MWCNTs的分散性;PANI/MWCNTs纳米复合材料的热分解起始温度达到280℃,当温度为364℃时,热失重率为20%,说明PANI/MWCNTs纳米复合材料具有良好的热稳定性。 相似文献
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Production planning and scheduling are becoming the core of production management, which support the decision of a petrochemical company. The optimization of production planning and scheduling is attempted by every refinery because it gains additional profit and stabilizes the daily production. The optimization problem considered in industry and academic research is of different levels of realism and complexity, thus increasing the gap. Operation research with mathematical programming is a conventional approach used to address the planning and scheduling problem. Additionally, modeling the processes, objectives, and constraints and developing the optimization algorithms are significant for industry and research. This paper introduces the perspective of production planning and scheduling from the development viewpoint. 相似文献
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目的 探索江门世遗文化的传承、发展和转化的新思路,践行国家在《粤港澳大湾区发展规划》纲要中要求江门承担与港澳地区文化创意合作与开发任务的分工。方法 与澳门高校紧密合作,开展专业培训课程,以开平碉楼为例,从人文视角开展设计研究,梳理开平碉楼的文化脉络,把世遗文化的元素和其背后的文化融入文创产品中,提升文创产品的附加值,推动当地文创产业结构的变革。结果 两地高校构建了稳定的科研团队,开设长期有效的设计培训课程,与景区建立了研究协作关系,帮助景区构建了一套产销研的商业模式。结论 以跨区域高校合作为平台,以文创产品为抓手,依托江澳两地的资源优势,可以构建江门世遗文化全新的品牌形象,最终推动开平世遗文化的活化。 相似文献
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Masao Doyama 《Bulletin of Materials Science》1999,22(3):723-728
By making a step on one surface (
) of a rectangular small paralellepiped copper crystal, dislocations could be created by the molecular dynamic method. The
dislocation created was not a complete edge dislocation but a pair of Heidenreich-Shockley partial dislocations. Each time
a dislocation was created, the stress on the surface was released. Small copper crystals having a notch were pulled (until
fracture), compressed and buckled by use of the molecular dynamic method. An embedded atom potential was used to represent
the interaction between atoms. Dislocations were created near the tip of the notch. A very sharp yield stress was observed.
The results of high speed deformations of pure silicon small crystals using the molecular dynamics are presented. The results
suggest that plastic deformation may be possible for the silicon with a high speed deformation even at room temperature. Another
small size single crystal, the same size and the same surfaces, was compressed using molecular dynamic method. The surfaces
are {110}, {112} and {111}. The compressed direction was [111]. It was found that silicon crystals are possible to be compressed
with a high speed deformation. This may suggest that silicon may be plastically deformed with high speed deformation. 相似文献
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Albert C. Parr 《Journal of research of the National Institute of Standards and Technology》2001,106(1):151-186
The national measurement system for photometric and radiometric quantities is presently based upon techniques that make these quantities traceable to a high-accuracy cryogenic radiometer. The redefinition of the candela in 1979 provided the opportunity for national measurement laboratories to base their photometric measurements on optical detector technology rather than on the emission from high-temperature blackbody optical sources. The ensuing technical developments of the past 20 years, including the significant improvements in cryogenic radiometer performance, have provided the opportunity to place the fundamental maintenance of photometric quantities upon absolute detector based technology as was allowed by the 1979 redefinition. Additionally, the development of improved photodetectors has had a significant impact on the methodology in most of the radiometric measurement areas. This paper will review the status of the NIST implementation of the technical changes mandated by the 1979 redefinition of the candela and its effect upon the maintenance and dissemination of optical radiation measurements. 相似文献
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New measurements are reported for the density and viscosity of tetralin and trans-decalin. The density was determined from room temperature to 60°C for tetralin and to 95°C for trans-decalin. The kinematic viscosity was measured up to temperatures slightly above 100°C. Our results improve upon the values recommended by the American Petroleum Institute for these liquids. 相似文献
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Miniature and MEMS-type vacuum sensors and pumps 总被引:1,自引:0,他引:1
Anna Grecka-Drzazga 《Vacuum》2009,83(12):1419-1426
In the paper, the observable trends of the actual research and development of selected types of miniature and MEMS-type vacuum sensors are presented. Some information about the new types of active vacuum gauges, which are offered by the leading manufacturers of the vacuum measurement instruments, is given. Next, the list of MEMS devices that need vacuum for proper operation is presented. Some aspects of vacuum-encapsulation of MEMS devices, on wafer level and package level are shown. The new conceptions of obtaining and maintenance of high and ultra-high vacuum in MEMS devices are described. They concern the conception of integration of a miniature orbitron pump on-chip with MEMS-type device or with vacuum part of the portable advanced instruments such as electron microscope, ion mass spectrometer, and free electron laser. 相似文献