Cr微合金化低碳钢热变形行为

采用Gleeble-3500热模拟机对一种含微量合金元素Cr、Mn、Ti的低碳钢在变形温度700～1050℃.应变速率0.01～0.1s~(-1)条件下的热变形行为进行研究.结果表明:单相奥氏体区和铁索体区,峰值应力随变形温度的降低而升高,在两相区,峰值应力随着变形温度的降低而降低;在775～850℃与950～1050℃的温度区间,峰值应力的大小基本相当.建立了热加工图,并通过组织观察对其热加工图进行了解释.根据流变应力曲线,确定了试验低碳钢铁素体区的热变形激活能和热变形方程.     

低碳钢的热变形行为

采用Gkeble-3500热模拟试验机研究了低碳钢在700～1050℃、0.01～10 s-1条件下的热变形行为.结果表明,低碳钢在奥氏体区、铁素体区和奥氏体-铁素体两相区的热变形行为不同:在奥氏体区和铁素体区变形时,随变形温度的降低流变应力增加;而在两相区变形时,随变形温度的降低流变应力显著降低.低碳钢奥氏体区和铁素体区的热变形激活能分别为322和219 kJ/mol;通过回归分析.确定了该低碳钢奥氏体区和铁索体区的热变形方程,为低碳钢热变形工艺优化提供了理论依据.     

微碳钢的热变形方程及热加工图

采用Gleeble-3500热模拟试验机研究了微碳钢在700～1100℃、0.01～10 s-1条件下的热变形行为。确定了其在铁素体区和奥氏体区的热变形方程。建立了微碳钢在不同应变量下的热加工图(Processing Map)。结果表明,在铁素体区和奥氏体区,试验钢的峰值应力大小基本相当;试验钢在铁素体区和奥氏体区的热变形激活能分别为302 kJ/mol和353 kJ/mol;不同真应变下的热加工图相似,当变形温度为875℃,应变速率为0.01 s-1时,能量消耗效率达到最大值为0.5。     

铁素体基球铁的热变形行为

采用Gleeble3500热/力模拟试验机对铁素体基球铁在700～1000℃温度区间,应变速率0.001～1 s-1之间进行了热压缩实验,研究了该材料的热变形行为.通过回归分析建立了流变应力与热变形参数相互关系的数学模型.结果表明:在应变速率一定的条件下,流变应力随温度的升高而降低;在变形温度一定的条件下,流变应力随应变速率的升高也增加.在低应变速率(0.001～0.01 s-1)的情况下,球铁的热变形行为与低碳钢的相似;但在高应变速率(0.1～1 s-1)的情况下,球铁的流变应力比低碳钢的明显偏高.铁素体基球铁热压缩变形受热激活过程控制.     

高氮无镍奥氏体不锈钢热变形行为的研究

利用Gleebe-1500型热模拟试验机研究一种"人体友好型"高氮无镍奥氏体不锈钢的热变形行为和动态再结晶规律,试验条件为变形温度900~1100℃、应变速率0.001~10s-1。结果表明,随变形温度升高,峰值应力和流变应力逐渐减小,动态再结晶速率增加;在变形温度不变的条件下,随变形速率的降低,峰值应力和流变应力降低;在变形速率为0.01、0.001s-1时,变形后期发生二次加工硬化;通过数值分析计算得出热变形激活能为280.09 k J/mol,并列出高氮无镍奥氏体不锈钢的热变形方程。     

40Cr钢的形变热处理组织

利用Gleeble 1500热/力学模拟实验机,对40Cr钢进行了变形温度为710～1 050℃,变形速率为0.1～1s-1,变形量为0.7的热模拟单向压缩试验.分析了钢热变形组织.结果表明,该钢在950～1 050℃变形温度下,奥氏体发生了动态再结晶;710℃变形温度下,应变奥氏体加速铁素体析出.     

低碳钢热变形过程中奥氏体动态再结晶问题分析

以Q235低碳钢为研究对象,研究其在不同温度和应变速率热变形过程中的膨胀曲线改变,揭示低碳钢在动态再结晶过程的临界条件和晶粒尺寸。结果表明,当变形温度大于850℃,应变速率在0.1~60.0 s-1之间,应力应变曲线上对应峰值为动态再结晶过程。奥氏体动态再结晶发生的前提条件是εc=3.628×10-4DA0.21Z0.17,且可以通过控制钢的冷却速度获得较小尺寸的铁素体晶粒。     

20MnSiV钢热压缩三区组织变形特征北大核心CSCD

采用Gleeble-3500热模拟试验机研究了20Mn Si V热轧钢筋在高应变速率下,三区(铁素体单向区、铁素体加奥氏体双相区及奥氏体单相区)压缩时的组织变化及变形特征。结果表明:铁素体单向区变形时,组织分布不均且晶粒粗大,应避免在该相区进行变形;铁素体加奥氏体双相区变形时奥氏体相转化成细小均匀的铁素体和珠光体,以760℃时的组织最佳,细晶强化和相变强化作用共同保证了材料在双相区变形比在奥氏体单相区变形具有更高的强韧性;结合变形抗力特征发现,随着变形温度的升高,变形抗力总体呈降低趋势,但存在3个低应力温度点,且在760℃最为显著;变形过程中铁素体与奥氏体合理的体积分数及相分布是760℃应力降低的主要原因。     

20MnSiV钢热压缩三区组织变形特征

采用Gleeble-3500热模拟试验机研究了20Mn Si V热轧钢筋在高应变速率下,三区(铁素体单向区、铁素体加奥氏体双相区及奥氏体单相区)压缩时的组织变化及变形特征。结果表明:铁素体单向区变形时,组织分布不均且晶粒粗大,应避免在该相区进行变形;铁素体加奥氏体双相区变形时奥氏体相转化成细小均匀的铁素体和珠光体,以760℃时的组织最佳,细晶强化和相变强化作用共同保证了材料在双相区变形比在奥氏体单相区变形具有更高的强韧性;结合变形抗力特征发现,随着变形温度的升高,变形抗力总体呈降低趋势,但存在3个低应力温度点,且在760℃最为显著;变形过程中铁素体与奥氏体合理的体积分数及相分布是760℃应力降低的主要原因。     

变形温度对高强IF钢应力-应变曲线及组织的影响

以高强IF钢为研究对象，在Gleeble3800热模拟机上，测定了在变形量为50％，变形速率为10s^-1时，变形温度分别为1000～700℃的应力-应变曲线。实验结果表明，在实验条件下，应力-应变曲线仅为动态回复型，不随温度的变化而改变类型；在铁素体区进行变形时，动态软化行为明显大于在奥氏体区变形，且在高温区域铁素体区变形的流变应力显著降低，同时随变形温度的升高，晶粒变的细小。     

Effects of Post-weld Heat Treatment on Microstructure,Mechanical Properties and the Role of Weld Reinforcement in 2219 Aluminum Alloy TIG-Welded Joints

In as-welded state, each region of 2219 aluminum alloy TIG-welded joint shows diff erent microstructure and microhardness due to the diff erent welding heat cycles and the resulting evolution of second phases. After the post-weld heat treatment, both the amount and the size of the eutectic structure or θ phases decreased. Correspondingly, both the Cu content in α-Al matrix and the microhardness increased to a similar level in each region of the joint, and the tensile strength of the entire joint was greatly improved. Post-weld heat treatment played the role of solid solution strengthening and aging strengthening. After the post-weld heat treatment, the weld performance became similar to other regions, but weld reinforcements lost their reinforcing eff ect on the weld and their existence was more of an adverse eff ect. The joint without weld reinforcements after the post-weld heat treatment had the optimal tensile properties, and the specimens randomly crack in the weld zone.     

The First Phase of the SRIF Industrialized Base in ＂West Area＂ Has Been Put into Operation

After nearly two years＇ tense construction, the first phase of industrialized base of Shenyang Research Institute of Foundry （SRIF）, located at the Tiexi Casting and Forging Industrial Park in the west of Tiexi District, has now been completed and formally put into operation.     

THERMODYNAMICS STUDY ON THE DECOMPOSITION OF CHROMITE WITH KOH

Institute of Process Engineering, Chinese Academy of Sciences, China, has proposed a method for oxidative leaching of chromite with potassium hydroxide. Understanding the mechanism of chromite decomposition, especially in the potassium hydroxide fusion, is important for the optimization of the operating parameters of the oxidative leaching process. A traditional thermodynamic method is proposed and the thermal decomposition and the reaction decomposition during the oxidative leaching of chromite with KOH and oxygen is discussed, which suggests that chromite is mainly destroyed by reactions with KOH and oxygen. Meanwhile, equilibrium of the main reactions of the above process was calculated at different temperatures and oxygen partial pressures. The stable zones of productions, namely, K2CrO4 and Fe2O3, increase with the decrease of temperature, which indicates that higher temperature is not beneficial to thermodynamic reactions. In addition, a comparison of the general alkali methods is carried out, and it is concluded that the KOH leaching process is thermodynamically superior to the conventional chromate production process.     

INFLUENCE OF HEAT TREATMENT ON DAMPING BEHAVIOUR OF THE MAGNESIUM WROUGHT ALLOY AZ61

The effect of isochronal heat treatments for 1h on variation of damping, hardness and microstructural change of the magnesium wrought alloy AZ61 was investigated. Damping and hardness behaviour could be attributed to the evolution of precipitation process. The influence of precipitation on damping behaviour was explained in the framework of the dislocation string model of Granato and Lücke.     

Theoretical Analysis for the Motion and Temperature of Melt Droplets in Spray Degassing Process

The motion of melt droplets in spray degassing process was analyzed theoretically. The height of the treatment tank in spray degassing process could be determined by the results of theoretical calculation of motion of melt droplets. To know whether the melt droplets would solidify during spraying process, the balance temperature of melt droplets was also theoretically analyzed. Then proof experiments for theoretical results about temperature of melt droplets were carried. In comparison, the experimental results were nearly similar to the calculation results.     

Growth Kinetics of Single Inclusion Particle in Molten Melts

On the basis of the single-particle framework, a new theory on inclusion growth in metallurgical melts is developed to study the kinetics of inclusion growth on account of reaction and collision. The studies show that the early growth of inclusion depends on reaction growth and Brawnian motion collision, and where the former is decisive, the late growth depends on turbulence collision and Stokes＇ collision, and where the former is dominant; collision growth is very quick during the smelting process, lessened in the refining process, but nearly negligible in the continuous casting process.     

An Easy Way to Quantify the Adhesion Energy of Nanostructured Cu/X(X=Cr,Ta,Mo,Nb,Zr) Multilayer Films Adherent to Polyimide Substrates

An approach based on film buckling under simple uniaxial tensile testing was utilized in this paper to quantitatively estimate the interfacial energy of the nanostructured multilayer films(NMFs) adherent to flexible substrates. The interfacial energies of polyimide-supported NMFs are determined to be *5.0 J/m2 for Cu/Cr, *4.1 J/m2 for Cu/Ta,*2.8 J/m2 for Cu/Mo, *1.1 J/m2 for Cu/Nb, and *1.2 J/m2 for Cu/Zr NMFs. Furthermore, a linear relationship between the adhesion energy and the interfacial shear strength is clearly demonstrated for the Cu-based NMFs, which is highly indicative of the applicability and reliability of the modified models.     

High-Speed Friction Stir Welding of SiC_p/Al–Mg–Si–Cu Composite

A 17 vol% SiCp/Al–Mg–Si–Cu composite plate with a thickness of 3 mm was successfully friction stir welded(FSWed) at a very high welding speed of 2000 mm/min for the first time. Microstructural observation indicated that the coarsening of the precipitates was greatly inhibited in the heat-affected zone of the FSW joint at high welding speed, due to the significantly reduced peak temperature and duration at high temperature. Therefore, prominent enhancement of the hardness was achieved at the lowest hardness zone of the FSW joint at this high welding speed, which was similar to that of the nugget zone. Furthermore, the ultimate tensile strength of the joint was as high as 369 MPa, which was much higher than that obtained at low welding speed of 100 mm/min(298 MPa). This study provides an effective method to weld aluminum matrix composite with superior quality and high welding efficiency.     

新型的治疗阿尔茨海默氏症药物(1-二甲基磷酰基-2,2,2-三氯)-乙基-1-醇烟酸醋对体外神经细胞的作用

目的: 观察本实验室合成的一种治疗阿尔茨海默氏症(AD)的药物(1-二甲基磷酰基-2, 2, 2 -三氯)-乙基^-1-醇烟酸醋(NMF),对体外培养的皮层神经细胞活性的影响以及对海人藻酸(KA)所致的神经损伤的保护作用。方法: 采用体外培养皮层神经元的方法,解剖分离 15 d胚胎小鼠皮层神经细胞, 接种于 96孔板,48 h 后加药并培养 72 h,以 MIT 法 观察 NMF 对小鼠皮层神经细胞活性的影响;同时将接种于 24 孔板的细胞预先给予 NMF,d 3 时加或不加KA处理后,以台盼蓝染色鉴别并计数死、活细胞,可得出细胞的存活率。结果: NMF 明显促进胎鼠皮层神经元活性,其中 NMF1、0. 1、10nmol·L^-1促进神经元活性增殖率分别高达 34.7%、37.4%、36. 7%, NMF 明显促进正常胎鼠皮层神经元存活卒,与对照组比较,10nmol·L^-1 NMF 对皮层神经元的存活率分别提高 39.3%、73.5%。 NMF能显著 对抗 KA 所致的神经元损伤,与 KA 损伤组相比, NMF0.1、10、10nmol·L^-1对损伤皮层神经元的保护率分别为 77.30%、80.10%、84.15%。结论: NMF 明 显促进胎鼠皮层神经元的洁性、提高正常皮层神经元,的存活卒,并能有效地保护KA所致的神经元损伤,提示 NMF 是一种很有潜力的治疗 AD 的药物。     

A STUDY OF TEMPERATURE-DEPENDENT VALENCE BOND STRUCTURE OF TITANIUM

On the basis of energy and shape method for the determination of the valence bond (VB) structures of crystal, the valence bond structure of titanium is redetermined at room temperature and calculated in the whole temperature range of 0-1943K. The outer shell electronic distribution of Ti is e_c~(2.9907) · (s_c~(0.4980) d_c~(2.4927)) ef1.0093 in crystal. The temperature dependences of the VB structures of hcp and bcc phases are the same. The VB structures of hcp and bcc phases monotonically increase or decrease with the increase in temperature, but show discontinuous changes at the phase-transformation temperature 1155K.