Adsorption Characteristics of Congo Red from Aqueous Solution onto Tea Waste

The feasibility of using tea waste (TW) as a low-cost adsorbent for the adsorption of an anionic dye (Congo red) from aqueous solution has been investigated. Adsorption in a batch process was conducted to study the effect of adsorbent dosage, initial dye concentration, contact time, pH, and temperature. The experimental data were analyzed by the Langmuir, Freundlich, and Temkin models. The adsorption system was best described by the Langmuir isotherm (R ² > 0.99). Adsorption kinetics followed a pseudo-second-order model (R ² > 0.99). The effect of mechanical treatment (vibratory mill) was also studied. The experimental results showed that using this physical treatment leads to an increase in the adsorption capacity of TW from 32.26 to 43.48 mg/g. Thermodynamic analyses revealed that the adsorption of Congo red on TW was endothermic and spontaneous in nature. The results indicated that TW can be employed as a potential low-cost adsorbent for the removal of Congo red from aqueous solution.     

Highly Efficient Adsorption of Anionic Dyes from Aqueous Solutions Using Sawdust Modified by Cationic Surfactant of Cetyltrimethylammonium Bromide

In the present study, the adsorption behavior of Congo Red (CR) dye from aqueous systems onto sawdust modified by cetyltrimethylammonium bromide, CH₃(CH₂)₁₅N(CH₃)₃Br (CTAB) was attempted. Adsorption experiments were carried out using both batch and column modes under various operating conditions. The effects of some important parameters such as solution pH, adsorbent dosage, initial dye concentration and contact time were investigated. Treatment of the equilibrium data obtained in batch experiments was carried out using Langmuir and Freundlich isotherm equations. Based on the isotherm analysis, it was found that the adsorption of CR dye onto SD fits well to the Langmuir model and the adsorption pattern on CTAB modified sawdust (CTAB/SD) followed the Freundlich isotherm which is indicative of heterogeneity of the adsorption sites on the surfactant-modified sawdust. The maximum adsorption capacity of SD and CTAB/SD were found to be 5.2 and 9.1?mg?g^?1, respectively, according to the Langmuir model. However, much higher differences in sorption capacities were observed for CTAB/SD and SD in the column system (66.73?mg?g^?1). In order to find out the possibility of the exhausted column for frequent use, a regeneration study was also carried out. It was found that the dye uploaded column can be easily regenerated with a high performance using ethanol as the washing solution.     

Modification and characterization of amberlite XAD-2 with calcein blue for preconcentration and determination of copper(II) from environmental samples by atomic absorption spectroscopy

A chelating resin is produced by coupling a dye calcein blue to Amberlite XAD-2 through an azo spacer. The resulting resin has been characterized by FT-IR, elemental analysis, thermogravimetric analysis (TGA) and scanning electron microscopy (SEM) studied for the preconcentration and determination of trace Cu(II) from solution samples. The optimum pH for adsorption of copper ions was 6. The sorption capacity of functionalized resin is 27 mg·g⁻¹. The chelating resin can be reused for 10 cycles without any significant changes in sorption capacity. A recovery of 100% was obtained for Cu(II) when eluted with 0.5 M nitric acid. Scatchard analysis revealed that homogeneous binding sites were formed in the resin. The equilibrium adsorption data of Cu(II) on modified resin were analyzed by Langmuir, Freundlich and Temkin models. Based on equilibrium adsorption data the Langmuir, Freundlich and Temkin constants were determined 0.036, 2.196 and 0.348 at pH 6 and 20 °C, respectively. The method was applied for Cu(II) assay in environmental samples.     

Adsorption equilibria of formic acid by weakly basic adsorbent Amberlite IRA-67: Equilibrium, kinetics, thermodynamic

Formic acid is an important chemical and biochemical compound used in various industries. It is important to separate this acid from wastewater streams. In this study, adsorption of formic acid was studied from aqueous solution by using weakly basic adsorbent (Amberlite IRA-67) at three different temperatures (298 K, 318 K, and 328 K). Adsorption of formic acid was investigated in terms of equilibrium, kinetics and thermodynamic conditions. Optimal amount of IRA-67 was determined as 1.00 g. The most used isotherms, Freundlich and Langmuir, were applied to experimental data. Langmuir isotherm gave good results with R² value over 0.99 at different temperatures. Pseudo-second-order model was fitted for this adsorption system. Thermodynamic parameters, , and , were calculated.     

Adsorptive removal of congo red dye (CR) from aqueous solution by Cornulaca monacantha stem and biomass-based activated carbon: isotherm,kinetics and thermodynamics

Cornulaca monacantha stem (CS) and biomass stem-based activated carbon (CS^AC) were explored for the removal of congo red (CR) dye from water system. The biomaterial was characterized using Fourier transform infrared spectroscopy (FTIR), Brunauer-Emmett-Teller (BET) and field emission scanning electron microscope (FESEM). The BET surface area of biomass stem-based activated carbon (CS^AC) was recorded to be 304.27 m²/g. The influence of different parameters such as initial CR concentration, adsorbent dosage, contact time, adsorbate pH and temperature onto CR adsorption were studied.The maximum adsorption of CR dye 97.19% and 86.43% were achieved at 55°C using CS^AC and CS adsorbents, respectively. The isotherm, kinetics and thermodynamic study were also investigated to explore the adsorption mechanism. The adsorption isotherm closely follow the Langmuir model (R² = 0.99) suggesting the monolayer adsorption of CR dye. Kinetic results indicated that pseudo second-order and Elovich model provide the better regression coefficient. Thermodynamic study revealed the feasible, spontaneous and endothermic nature of adsorption process. The regeneration study implies that adsorbent was efficiently recovered from CR dye with 0.01 mol/L NaOH solution. The CS^AC adsorbent possesses 75.75% uptake for CR dyes after 6th cycles of desorption-adsorption, respectively. .     

Sorption of ruthenium by dipropylmethyl-2-(N,N-diisobutyl) acetamidoammonium iodide impregnated Amberlite XAD-4 resin from nitric acid medium

Dipropylmethyl-2-(N,N-diisobutyl)acetamidoammonium iodide has been impregnated on Amberlite XAD-4 resin and investigated for sorption of Ru from nitric acid medium. Equilibrium sorption data for Ru uptake were represented well by the Langmuir isotherm equation (R² = 0.98) compared to Freundlich isotherm equation (R² = 0.86). The maximum monolayer coverage (Q₀) value of 6.25 mg/g as obtained from Langmuir isotherm was close to the experimental value (5.63 mg/g). The heterogeneity parameter (1/n) = 0.37 obtained from the slope of Freundlich isotherm indicates slight heterogeneity in sorption process. Aqueous solutions of 5% ammonia or 10% sodium hydroxide were found suitable for desorption. The method can be applied for separation of Ru from acidic waste solutions.     

Adsorptive removal of fluoride from water by activated carbon derived from CaCl2-modified Crocus sativus leaves: Equilibrium adsorption isotherms,optimization, and influence of anions

A central composite design using response surface methodology was applied for the experimental design and optimization of fluoride adsorption on an activated carbon derived from calcium chloride-modified Crocus sativus leaves (AC-CMCSL). Fluoride removal efficiency as function of independent variables, such as initial fluoride concentration, pH, adsorbent dose, and time has been investigated. The maximum percentage removal of fluoride at optimum conditions (initial fluoride concentration?=?6.5?mg?L^?1, pH?=?4.5, adsorbent dose?=?15?g?L^?1 and time?=?70?min) was 85.43%. By comparing adsorption isotherm, the Freundlich model provided the best correlation (R²?=?0.99) for the adsorption of fluoride on AC-CMCSL. The maximum adsorption capacity from the Langmuir model (q_max) was 2.01?mg?g^?1. The influence of the co-existing anions on fluoride adsorption was in the following order: PO₄^3??>?SO₄^2??>?Cl^??>?NO₃^?. The results of the present study showed that activated carbon derived from the leaves of calcium chloride-modified Crocus sativus has a good potential for fluoride removal from aqueous solution.     

Evaluation of polystyrene anion exchange resin for removal of reactive dyes from aqueous solutions

The Amberlite IRA-900 resin was tested to remove C.I. Reactive Black 5, C.I. Reactive Red 2 and C.I. Reactive Red 120 dyes from solutions. Batch adsorption studies concerning effects of the phase contact time, pH, temperature, the presence of salts and surfactants were run. A pseudo second-order kinetic model was used to evaluate the rate constants. The Langmuir equation provided good fit for the experimental data of the equilibrium adsorption. The studies of dyes uptake using the dynamic method were run. The treatment efficiency of Amberlite IRA-900 to model wastewaters was tested. Desorption experiments by the batch method were performed.     

Synthesis,characterization, and application of amberlite XAD‐2‐ salicylic acid‐ iminodiacetic acid for lead removal from human plasma and environmental samples

A new chelating resin is prepared by coup‐ling Amberlite XAD‐2 with salicylic acid (SAL) through an azo spacer. Then the polymer support was coupled with iminodiacetic acid (IDA). The resulting sorbent has been characterized by FT‐IR, elemental analysis, thermogravimetric analysis (TGA), and scanning electron microscopy (SEM) and studied for the preconcentration and determination of trace Pb (II) ion from human biological fluid and environmental water samples. The optimum pH value for sorption of the metal ion was 5. The sorption capacity of functionalized resin is 67 mg g⁻¹. The chelating sorbent can be reused for 20 cycles of sorption–desorption without any significant change in sorption capacity. A recovery of 95% was obtained for the metal ion with 0.5M nitric acid as eluting agent. The profile of lead uptake on this sorbent reflects good accessibility of the chelating sites in the Amberlite XAD‐2‐SAL/IDA. Scatchard analysis revealed that the homogeneous binding sites were formed in the polymers. The equilibrium adsorption data of Pb (II) on modified resin were analyzed by Langmuir, Freundlich, Temkin, and Redlich‐Peterson models. Based on equili‐brium adsorption data the Langmuir, Freundlich, and Temkin constants were determined 0.428, 20.99, and 7 × 10⁻¹² at pH 5 and 20°C. The method was successfully applied for determination of lead ions in human plasma and sea water sample. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

Heavy metals adsorption on some iminodiacetate chelating resins as a function of the adsorption parameters

The adsorption properties of some novel chelating resins (CRs) bearing iminodiacetate groups for removal of heavy metal ions like: Cu(II), Co(II) and Ni(II) from aqueous solutions comparative with the commercial resin Amberlite IRC-748 have been studied in this work by a batch equilibrium technique. Quantitative analysis for adsorption was conducted using UV–vis spectroscopy to investigate the kinetics, adsorption isotherm and thermodynamics of the removal process considering equilibration time, pH, metal ion concentration and temperature as controlling parameters. The metal adsorption capacities, at pH 5, were in the order Cu(II) > Ni(II) > Co(II), for both the CR with 10 wt.% DVB (CR-10) and the commercial resin Amberlite IRC-748. The adsorption capacities on CR-10 were higher for Ni(II) and Co(II) ions, but lower for Cu(II) ions compared with Amberlite IRC-748. Both Freundlich and Langmuir isotherms well fitted on the adsorption results of Cu(II), Ni(II) and Co(II) ions on all iminodiacetate resins.     

Weak Base Anion Exchanger Amberlite FPA51 as Effective Adsorbent for Acid Blue 74 Removal from Aqueous Medium – Kinetic and Equilibrium Studies

In this work, the macroporous anion exchange resin – Amberlite FPA51, is proposed as the effective adsorbent for the removal of Acid Blue 74 from aqueous solutions. The sorption mechanism was investigated under static conditions taking into account the phase contact time, solution pH, initial dye concentration, and temperature. The equilibrium data were fitted to the Langmuir, Freundlich, and Dubinin-Radushkevich isotherm models. The maximum monolayer capacity Q ₀ was 123.8 mg/g. The adsorption kinetics was found to follow the pseudo-second order model. The sorption energy was equal to 14.5 kJ/mol and indicated that the adsorption process of the dye may be described via a chemical anion-exchange mechanism.     

Synthesis, characterization and application of allyl phenol modified amberlite XAD-4 resin for preconcentration and determination of copper in water samples

A new chelating resin was prepared by coupling Amberlite XAD-4 with phenol through an azo spacer, then modified by allyl bromide and characterized (by elemental analysis and IR) and studied for preconcentration of Cu(II) using flame atomic absorption spectrometry (FAAS) for metal monitoring. The optimum pH value for sorption of the above mentioned metal ion was 4.5. The resin was subjected to chemical evaluation through batch binding and column chromatography of Cu(II). The chelating resin can be reused for 15 cycles of sorption-desorption without any significant change in sorption capacity. A recovery of 98% was obtained for the metal ion with 0.5 M HNO₃ as eluting agent. The equilibrium adsorption data of Cu(II) on modified resin were analyzed by Langmuir, Freundlich and Temkin models. Based on equilibrium adsorption data the Langmuir, Freundlich and Temkin constants were determined to be 0.061, 0.193 and 0.045 at pH 4.5 and 25 °C. The method was applied for the copper determination from industrial waste water sample.     

TEMPERATURE EFFECT ON ION EXCHANGE SORPTION OF PHOSPHATE

Phosphate sorption on the strong basic anion exchanger Amberlite IRA-400 (Cl^? form) is studied as a function of temperature ( 25^°C–50^°C), at two initial pH values (5 and 9 ) in the concentration range 120–190 ppm. Chloride released/phosphate sorbed ratios increase with the increase both in temperature and pH and decrease with the increase in the concentration of solution. It is suggested that phosphate sorption takes place initially as HPO₄ ^2? followed by H₂PO₄ ^?. The data is explained with the help of a modified Langmuir and mass law action equations. Various thermodynamic parameters (ΔG^°,ΔH^° and ΔS^°) are presented. The differential isosteric heat of adsorption, is computed at different temperatures, showing the sorption of phosphate to be endothermic on the anion exchanger Amberlite IRA-400.     

Application of Full Factorial Design for Removal of Polycyclic Aromatic Dye from Aqueous Solution Using 4A Zeolite: Adsorption Isotherms,Thermodynamic and Kinetic Studies

In this study, removal of the cationic dye acridine orange (AO) from aqueous solution using 4A zeolite was studied. The adsorption experiments were performed using batch system, and full factorial design was employed for investigating the condition of removal efficiency of dye. The four most important operating variables were the initial pH of the solution, the concentration of dye, the contact time, and the temperature. The 18 experiments were required to investigate the effect of variables on removal of the dye. The results were statistically analyzed to define important experimental variables and their levels using the analysis of variance (ANOVA). A regression model that considers the significant main and interaction effects was suggested and fitted the experimental data very well. Model predictions were found to be in good agreement (R² = 99.99%, adjusted R² = 99.86%) with experimental data. The optimized conditions for dye removal were at initial pH 3.0, 20.0 mg L^?1 dye, temperature 298.0 K and 80.0 min adsorption time. The experimental data were analyzed by the Langmuir, Freundlich, Temkin and Sips adsorption models. The maximum predicted adsorption capacities for AO was obtained as 29.851 mg g^?1. The adsorption thermodynamic parameters, namely ΔH°_ads, ΔG°_ads and ΔS°_ads, were determined. Furthermore, the kinetic of AO adsorption on the 4A zeolite was analyzed using pseudo-first- and second-order kinetic models and the results showed that the removal was mainly a pseudo-second-order process.     

Adsorption of anionic textile dye Acid Green 9 from aqueous solution onto weak or strong base anion exchangers

The aim of this work is to study the thermodynamic and kinetic studies with regard to the adsorption of Acid Green 9 (AG9) on the most efficient resin, namely, acrylic weak base anion exchange resin with ethylenediamine‐functional groups (A1) selected from several anion exchange resins. The influence of the various experimental parameters such as, pH, initial dye concentration, contact time, temperature, and adsorbent dose was investigated by batch experiments. The extent of the dye adsorption increased with the decrease of the initial dye concentration and the increase of the contact time, temperature, and amount of the adsorbent. Adsorption process was quantitative and very fast at low concentrations of the dye. To investigate the mechanism of the adsorption and potential rate‐controlling steps, pseudo first‐ and second‐order, as well as intraparticle diffusion kinetic equations have been used. The adsorption kinetic of AG9 dye from aqueous solution onto A1 could be described by the pseudo second‐order reaction model. The obtained results are in agreement with the Langmuir and Freundlich models. In the optimum conditions established, an adsorption capacity of 500 mg textile dye (72% purity) g^?1 adsorbent (at 293 K) was reached. Desorption experiments by batch and dynamic methods were performed using a solution of 0.05 mol L^?1 NaOH. A series of 13 adsorption–desorption cycles were carried out by the dynamic method with a quantitative adsorption and the desorption efficiency higher than 95%. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009     

Adsorptive removal of dibenzothiophene from petroleum distillates using pomegranate leaf (Punica granatum) powder as a greener adsorbent

In this study, adsorption performance of pomegranate leaf powder (PLP) for the removal of dibenzothiophene (DBT) from petroleum distillates is presented. Morphology and elemental composition, surface chemistry, and textural property of the PLP were checked using scanning electron microscopy (SEM) equipped with energy dispersive X-ray (EDX), Fourier transform infrared spectroscopy (FTIR), and N₂ physi-sorption at 77?K, respectively. Model oil contained 0.1?g DBT in 100?mL hexane was used for the performance evaluation and conducted in batch mode. The results show DBT removal of 70.55%, with the adsorbent retaining about 97.81% of its capacity after fourth cycle of usage. Results from SEM-EDX and FTIR indicate that DBT was adsorbed on the surface of PLP. Adsorption isotherm data fitted onto Freundlich and Langmuir isotherms models show very good coefficient of determination (R²) values of 0.9952 (for Langmuir) and 0.9979 (for Freundlich), indicating suitability of the models to describe the process. The adsorption kinetics of DBT onto PLP follows pseudo-second-order kinetics and the experimental q_e (53.66?mg/g) values obtained is very close to the model-estimated value q_e (55.55?mg/g). The negative value of ΔG^o and the positive values of ΔH^o obtained in the thermodynamic studies indicate that adsorption of DBT onto the PLP is an endothermic and spontaneous process at the temperatures studied.     

Equilibrium Isotherms,Thermodynamics, and Kinetic Studies for the Adsorption of Food Azo Dyes onto Chitosan Films

The adsorption of FD&C red 2 and FD&C yellow 5 onto chitosan films (CFs) was evaluated by equilibrium isotherms, thermodynamics, and kinetic studies. The effects of temperature (298–328 K), initial dye concentration (50–300 mg L^?1), stirring rate (50–350 rpm), and contact time (0–120 min) were investigated at pH of 2.0 and 100 mg L^?1 of CFs. The dye concentration was determined by spectrophotometry. Freundlich and Langmuir models were used to represent the equilibrium data. The Langmuir model was the more adequate to represent the equilibrium data (R² > 0.99 and average relative error <2.50%) and the maximum adsorption capacities were 494.13 and 480.00 mg g^?1 for FD&C red 2 and FD&C yellow 5, respectively, obtained at 298 K. The R_L values ranged from 0.044 to 0.145. The adsorption was exothermic, spontaneous, and favorable. For the FD&C red 2, 90% of saturation was attained at 120 min and the Elovich model was the more appropriate. For the FD&C yellow 5, 95% of saturation was attained at 20 min and the pseudo first-order model was the more adequate to fit the kinetic data. CFs were easily separated from the liquid phase after the adsorption process, providing benefits for industrial applications, and its application range can be extended for azo dyes.     

Application of nitroso-R-salt in modification of strongly basic anion-exchangers Amberlite IRA-402 and Amberlite IRA-958

The batch method was applied in order to determine the influence of phase contact time, solution pH and temperature as well as HCl concentration on nitroso-R-salt (NRS) deposition on the strongly basic anion-exchangers Amberlite IRA-402 and Amberlite IRA-958. The equilibrium sorption of NRS from 1 × 10^− 4 mol/dm³ solution was achieved after 60 min. The amount of NRS adsorbed decreased with increasing hydrochloric acid concentration. A significant increase of NRS uptake is observed with the increase of initial solution pH up to 3 for Amberlite IRA-402. Amberlite IRA-402 and Amberlite IRA-958 in chloride form as well as modified by means of NRS were used for recovery of Pd(II) ions from 0.1, 0.5 and 1.0 mol/dm³ HCl solutions.The studied anion-exchangers in NRS form as far as their application in removal of Pd(II) chlorocomplexes is concerned can be presented in the order: Amberlite IRA-402 > Amberlite IRA-958.     

The application of a natural chitosan/bone char composite in adsorbing textile dyes from water

Colored wastewaters are one of the common waste contaminants which are derived from various industries, threatening aquatic environments. Thus, it is necessary to treat them before discharge. Among various remediation technologies, adsorption is one of the popular treatment methods because of its simplicity and cost-efficiency. So, in the present study, the adsorption potential of a natural chitosan/bone char composite was investigated in adsorbing the Direct Brown 166 dye (DB-166) from aqueous solution. To investigate the adsorption potential of the chitosan/bone char composite, the effects of influencing parameters were studied. Accordingly, the optimum removal efficiency was determined at an initial pH of 3, a contact time of 60?min, an initial dye concentration of 20?mg/L, an adsorbent dosage of threatening 4?g, a mixing speed of 150?rpm, and a temperature of 55°C. Also, the maximum adsorption efficiency and capacity were obtained to be 99.8% and 21.18?mg/g, respectively. To evaluate the equilibrium and dynamics, isotherm and kinetic models were investigated. As a result, the Langmuir isotherm (R²?=?0.996) and pseudo-second-order kinetic model (R²?=?0.999) fitted the experimental data well. These results revealed that the chitosan/bone char composite can be used as an efficient adsorbent for the decolorization of aquatic solutions.