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红外光谱、核磁共振氢谱和质谱证实,以溴代丙烯与N.N-二甲基十六烷基胺为主要原料所合成的产品为阳离子表面活性剂单体N,N-二甲基-N-丙烯基十六烷基溴化胺,并且其纯度很高. 相似文献
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本文研究了二烷基磷(膦)酸酯的化学结构对钴、镍萃取选择性的影响,讨论了不同二烷基磷(膦)酸酯对钴、镍的萃取选择性产生差异的原因。研究结果表明,随着磷原子上的取代基的诱导常数总和|∑σ(?)|函数(或萃取剂离解常数的负指数pKa值)及空间位阻效应的增加,对钴的萃取性能影响不显著、镍的萃取能力则下降。在所研究的萃取剂中钴的萃取选择性按以下次序下降:AMHPA(5709)>EHEHPA>ADiBMPA>NMHPA>NEHPA>D(DiBM)PA>AEHPA>D2EHPA从硫酸溶液中萃取分离钴、镍,AMHPA(5709)是具有应用前景的优良萃取剂。 相似文献
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当前社会对钴资源的需求量激增, 仅从矿产资源中提取钴金属已不能完全满足市场的需求。从钴的二次资源中分离提取钴是解决钴资源供应不足问题的重要途径。本文对含钴资源和废旧催化剂、钴锰废渣、废旧电池等钴锰二次资源的特点进行了分析, 对比介绍了化学沉淀法、溶剂萃取法、离子交换法、膜电解法分离溶液中钴锰离子的工艺、原理及技术效果, 同时综述了适用于溶液中钴锰分离的选冶联合方法研究进展, 其中浮游萃取法兼具界面分选与化工分离的双重优势, 钴锰分离效率高、流程短、成本低, 特别适用于选冶工业中大规模低浓度废液或废水有价金属的分离与富集, 应用前景广阔。 相似文献
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电感耦合等离子体质谱法测定湖泊水中痕量溴、碘 总被引:5,自引:0,他引:5
采用电感耦合等离子体质谱法测定湖泊水中痕量溴、碘,考察了不同酸度对溴、碘测定的影响,测量过程中碘记忆效应的消除,确定合适的工作条件,方法检出限低(Br:0.58 ng/mL、I:0.07 ng/mL),精密度好,为1.21%~2.39%.对武汉市内四个湖泊水样进行了检测,并做了样品加标回收实验,加标回收率在98%~117%范围内.对国家水样标准进行了测定,测定结果与推荐值一致性较好.实验证明,使用ICP-MS测定湖泊水中溴、碘具有简便快速、重复性好、结果准确的优点. 相似文献
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《中国稀土信息(英文版)》2014,(10)
<正>Developing ecological lighting source The world is facing the big problem of energy shortage today and the contradiction between economy development and environmental protection is worsened.Therefore,people are more likely to choose an ecological light source that is more energy efficient and environmental friendly.The choice provides great opportunity for the development of rare earth optical material industry in China.The concept of green lighting positions rare earth luminescent material as a leading player in illumination market.The light source of both rare earth luminescent lamp and LED lamp is ecological and energy saving.This is why 相似文献
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《中国稀土信息(英文版)》2014,(8)
正Galaxy Magnet announced its financial results for the first half of 2014 on August 14.For the first six months ended on 30 June 2014,Galaxy Magnet achieved operation income of RMB 182.3 million,up8.40% over the same period of 2013,and the net profit attributable to the shareholders of the listed company of 34.02 million yuan,increasing 35.49% over the same period of last year.Stable performance increase was led by development of new customers and application market of magnets. 相似文献
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<正>China has rich rare earth resources.Output of rare earth and steel in China ranks the top first in the world.However,there is still certain distance between the steel produced in China and developed countries from the point of varieties and quality.China still has to import some types of steel.Improving the quality should be emphasiZed in future development of steel industry in China.Rare earth can be used to upgrade traditional steel 相似文献
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《中国稀土信息(英文版)》2014,(12)
正November 21~30,2014Due to weak demand from downstream industries,transactions of rare earth in Chinese domestic market were inactive.It was difficult to sell any rare earth products except for dysprosium oxide and terbium oxide.Suppliers lost confidence in recent market.Demand for rare earth products was soft.Consumers continued to take a wait-and-see attitude.Rare earth export market remained slow. 相似文献
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分析了近年来国内外稀散金属产业的生产、应用、资源与市场状况.铟锡氧化物靶材、砷化镓晶片、锗红外材料、铼高温合金和硒在电解锰及玻璃的应用等已成为稀散金属的主要应用领域.稀散金属的产量快速增长达到历史高位而导致了市场的失衡.以GaInP_2/GaAs/Ge,CIGS和CdTe为代表的非硅系太阳能电池是稀散金属的新兴应用领域,将给稀散金属带来日益增长的需求. 相似文献
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<正>Rare earth luminescent material is one of the most important application sectors of rare earths.China enjoys the exceptional advantage to develop rare earth luminescent material for its abundant rare earth resources.After several decades'endeavor,China's rare earth luminescent material industry,headed by rare earth phosphor for lamp and LED and high efficient rare earth energy-saving light source,has been gradually developed into a scale industry.China has become a major production base of rare earth phosphor for lamps and rare earth 相似文献
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《中国稀土信息(英文版)》2014,(6)
正June 1~10,2014Rare earth market remained weak.Quoted price of rare earth products was similar to that in May.There was no sign of recovery in downstream market.The market of NdFeB magnetic materials and phosphor was depressed.Catalyst,polishing powder and ceramic industries remained inactive.Demand from downstream industry was soft.Consumers purchased on their needs.Suppliers had strong intention to sell.Prices of rare earth products 相似文献
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YANG Li 《中国稀土信息(英文版)》2014,(6)
<正>Chinese rare earth-related listed companies have published their 2013 annual reports.It can be understood from their reports that production and operation activities of Chinese rare earth-related companies were still heavily affected by macro economy and industrial policies.They basically followed the steps of national economy.In 2013,world economy recovered slowly but the economy 相似文献
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Gao Wei 《中国稀土信息(英文版)》2014,(11)
正1.Status of rare earth polishing powder Rare earth polishing powder with high content of cerium oxide began to replace iron oxide for glass polishing and became one of the key materials in glass polishing process since 1940.Compared with traditional iron oxide,rare earth polishing powder has many advantages,such as fast polishing rate,high polishing quality and long service life.It can achieve good surface quality and improve operation conditions.For example,in lens polishing,the polishing work that cerium 相似文献
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《中国稀土信息(英文版)》2014,(8)
正Pyrometallurgy Laboratory of Baotou Research Institute of Rare Earths had independently developed a new preparation technology of rare earth alloy for NdFeB.The alloy can remarkably enhance the coercivity of NdFeB magnet but also evidently reduce the production cost of the magnet.The new master alloy was prepared in the kA pilot-scale electrolytic cell by the independent technology.The rare earth master alloy can be used as the raw material for NdFeB.Compared 相似文献