共查询到18条相似文献,搜索用时 484 毫秒
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建立了碱熔分解样品、碲共沉淀分离,电感耦合等离子体发射光谱法(ICP-AES)测定含钌二次资源物料中钌含量的方法。对样品分解、钌的分离和测定、方法准确度和精密度进行了研究。约0.5 g粉末样品与5 g的过氧化钠混匀,于730 ℃马弗炉中熔融25 min,冷却后用水浸出,盐酸酸化,加氧化剂使钌保持较高价态,用碲共沉淀法分离钌,ICP-AES测定钌含量。样品加标回收率98.8%~99.8%,相对标准偏差(RSD,n=9)为:0.3%~1.0%,方法快速、简便,已应用于生产测定。 相似文献
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利用四氧化钌易挥发的特点,将钌溶液用高氯酸冒烟去除钌,用ICP-AES测定样品中杂质元素。对钌基体干扰、高氯酸用量、杂质元素分析谱线、仪器分析参数等进行了研究,确定了最佳实验条件。结果表明,采用高氯酸冒烟,可将试液中钌含量降低至50 μg/mL以下,有效消除钌对杂质元素的光谱干扰。方法具有较宽的测定范围,对三氯化钌样品中20个杂质元素测定的相对标准偏差(RSD,n=9)为2.0%~3.5%,加标回收率在86.3%~118.0%之间,可满足钌化合物中杂质元素的测定要求。 相似文献
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碱熔解-硫脲比色法快速测定钌碳催化剂中的钌 总被引:1,自引:0,他引:1
建立了碱熔解-硫脲比色法快速测定钌碳催化剂中钌的方法;对样品的预处理和显色条件进行了改进,将精密度和准确度与传统法的进行了比较。结果表明:采用过氧化钠熔解钌、盐酸转化试液、在4 mol/L盐酸介质中和60~80℃水浴保持10m in后,可较好的进行硫脲比色法测定钌;本法和传统法测得钌的质量分数和相对标准偏差分别为4.30%、4.30%和1.02%、1.21%,本法测得样品加标准回收率为98.01%~102.12%;2种方法分析结果的精密度和准确度吻合,但本法快速、简便,满足日常样品的分析要求。方法已应用于废钌碳催化剂中钌的测定。 相似文献
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In this paper, FeCrNiBSiMox (x = 1.0, 1.5, 2.0, 2.5) stainless steels were successfully prepared using a laser melting deposition technology, with the aim to investigate the effect of Mo content on microstructure and corrosion behaviors. The results showed that the as-deposited specimens were composed mostly of α-Fe and a small amount of (Cr, Mo)7C3, and (Cr, Mo)7C3 existed in the inter-dendritic (ID) region. As the Mo content increased, grain refinement could be clearly observed, and the area of the ID region increased from 27% to 54%. The low-angle boundaries accounted for 60–70% of the grain boundaries of the as-deposited specimens. Increasing the content of Mo improved the microhardness of the as-deposited specimens from 652 HV to 813 HV. The corrosion current density of the as-deposited specimens with the Mo mass fractions of 1.0%, 1.5%, 2.0%, and 2.5% were 1.37 × 10−6, 1.02 × 10−7, 6.19 × 10−7, and 3.06 × 10−7 A/cm2, respectively. The as-deposited specimen with Mo content of 1.5% had lower cumulative erosion loss and erosion loss rate than other as-deposited specimens. The FeCrNiBSiMox (x = 1.5) specimen exhibited excellent resistance to electrochemical corrosion and cavitation erosion. 相似文献
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Planar and rotary tungsten targets were fabricated by low pressure plasma spraying (LPPS). Relative density, oxygen content by mass, microstructure, micro-hardness and ultimate tensile strength (UTS) of LPPS tungsten targets were all influenced by vacuum pressure. Compared with 1.3 × 104 Pa and 6.5 × 104 Pa, a vacuum pressure of 3.9 × 104 Pa was optimal for preparing high-quality tungsten targets. Oxygen content by mass, porosity, average grain size, micro-hardness and UTS of LPPS target fabricated under 3.9 × 104 Pa were about 0.18%, 2.8%, 0.9 μm, 377.8HV0.025 and 201.1 MPa, respectively. Electron backscattered diffraction (EBSD) from the LPPS sample (fabricated under 3.9 × 104 Pa) showed that proportions of 〈001〉, 〈011〉 and 〈111〉 oriented grains were 10.6%, 21.0% and 12.3% of the total, respectively. The tungsten target possessed excellent magnetron sputtering performance since most tungsten grains with a size <1.0 μm were irregularly distributed without preferred orientation. Rapid sputtering and uniform thinning on the surface of LPPS tungsten targets took place with nano-scaled sputtering pits being formed during magnetron sputtering. Smooth and continuous tungsten thin films with thickness about 320 nm can be deposited by magnetron sputtering from the LPPS samples. XRD spectra of tungsten thin films with body centered cubic structure showed that the intensity of the (110) diffraction peak was much higher than those of the (200), (211) and (220) peaks. 相似文献
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It is shown that the ductility of lamellae-structured Fe30Ni20Mn35Al15 (in at. %), which consists of B2 and f.c.c. phases, is influenced by testing environment. Tensile tests performed in air at strain rates ranging from 3 × 10?6 to 3 × 10?1 s?1 showed that the elongation to fracture and ultimate tensile strength (UTS) increased with increasing strain rates below 3 × 10?3 s?1, and were independent of strain rate at ~10.5% and 840 MPa for strain rates ≥ 3 × 10?3 s?1. In order to understand this strain-rate sensitive behavior, tensile tests were also performed in either dry oxygen or 4% hydrogen + nitrogen at different strain rates. The elongation and UTS in oxygen were insensitive to strain rate and close to those tested at 3 × 10?3 s?1 in air, whereas the elongation in hydrogen was 4% for strain rates ≤3 × 10?3 s?1 and increased to ~10.8% at 3 × 10?1 s?1. The reduction of ductility in air and hydrogen-charged environment at low strain rate is attributed to hydrogen embrittlement. 相似文献
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王金忠 ;E.ElANGOVAN ;N.FRANCO ;A.ALVESE ;A.REGO ;R.MARTINS ;E.FORTUNATO 《中国有色金属学会会刊》2010,20(12):2326-2330
N-doped ZnO films were radio frequency(RF)sputtered on glass substrates and studied as a function of oxygen partial pressure(OPP)ranging from 3.0×10-4 to 9.5×10-3 Pa.X-ray diffraction patters confirmed the polycrystalline nature of the deposited films.The crystalline structure is influenced by the variation of OPP.Atomic force microscopy analysis confirmed the agglomeration of the neighboring spherical grains with a sharp increase of root mean square(RMS)roughness when the OPP is increased above 1.4×10-3 Pa.X-ray photoelectron spectroscopy analysis revealed that the incorporation of N content into the film is decreased with the increase of OPP,noticeably N 1s XPS peaks are hardly identified at 9.5×10-3 Pa.The average visible transmittance(380-700 nm) is increased with the increase of OPP(from~17%to 70%),and the optical absorption edge shifts towards the shorter wavelength.The films deposited with low OPP(≤3.0×10-4 Pa)show n-type conductivity and those deposited with high OPP(≥9.0×10-4 Pa)are highly resistive(105Ω·cm) 相似文献
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The corrosion behavior of five Fe–xCr–Al alloys with a constant Al content of 10 at.% and Cr contents ranging from 0 at.% to 20 at.% was examined at 600 °C in
a H2–HCl–H2S–CO2 gas mixture providing 3.7 × 10−22 atm O2, 2.4 × 10−14 atm Cl2 and 3.9 × 10−9 atm S2. All the alloys formed duplex scales containing an outermost layer of iron oxide plus an inner layer composed of mixtures
of the oxides of all the alloy components. Besides, a region of internal attack of Al or Al + Cr, whose depth decreased with
increasing Cr content, formed in all the alloys. The simultaneous presence of chlorine and sulfur in the gas mixture significantly
accelerated the corrosion of all the alloys with respect to their oxidation in a simpler H2–CO2 mixture providing the same oxygen pressure, by forming thick and cracked scales. The effect was particularly large for the
high-Cr alloys due to their inability to form external protective alumina scales in the present gas mixture. 相似文献
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The simultaneous oxidation and sulfidation of Cr, Ni-10Cr, Ni-20Cr, and Ni-30Cr was studied at 800°C in three gases falling within the Cr2O3 stability field of the Cr-S-O system. The sulfur partial pressure remained constant at 1×10?6 atm, whereas the oxygen partial pressure varied from 5×1021 to 5×10?20 atm, and the carbon activity varied from 0.108 to 0.416. Reaction kinetics were measured, and the reaction products were characterized by X-ray diffraction, metallography, scanning electron microscopy, and X-ray energy dispersive analysis. Reaction rates decreased with increasing oxygen partial pressure and decreased with increasing chromium content of the alloys. Sulfides always formed along with Cr2O3, even though the gases fell within the oxide stability field. No carburization was observed even though carbon activities were sufficiently high to form carbides. The reaction mechanisms are discussed, and the absence of carburization is analyzed on the basis of a three-dimensional stability diagram. 相似文献
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Effects of vacuum conditions on the oxygen content and microstructure of Mo layers used with Cu gate lines as thin-film transistor-liquid crystal display diffusion barriers were investigated. Mo was deposited using ion-beam sputtering at 1.0 × 10?5 and 7.0 × 10?7 Torr. The Mo layer oxygen content and the microstructure and changes in chemical composition of the Cu/Mo/SiO2/Si layer during annealing were examined. The Mo layer microstructure was influenced by oxygen; increasing concentration increased the energy required for secondary grain growth. Growth was suppressed at high oxygen levels. Therefore, diffusion barrier performance is enhanced by finer Mo layer grain sizes. 相似文献
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The oxidation of stainless steels AISI 304 and 430 was undertaken in the temperature range 450–600°C and oxygen partial pressure range 6.7 × 107 to 1.33 × 10?5 Pa. The composition of the oxide layer formed has been analysed by AES and ESCA. Optimum conditions were determined for the formation of a ~40 nm thick oxide layer with a high chromium content. Attention is drawn to the role of the chromium content of the bulk in the passivation process. 相似文献