共查询到19条相似文献,搜索用时 109 毫秒
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溶胶—凝胶法制备莫来石晶须 总被引:3,自引:0,他引:3
用正硅酸乙酯,硝酸铝为原料,采用溶胶-凝胶工艺制备了Al2O3-SiO2干凝胶,通过高温热处理制得了直径为0.5-2.5μm,长径比为5-40的莫来石晶须。采用XRD,SEM,TEM和SADP等手段研究了莫来石晶须的晶相组成,形貌与生长方向,发现莫来石晶须是沿其c轴方向生长的。 相似文献
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PZTS系凝胶玻璃及玻璃陶瓷的结构研究 总被引:3,自引:0,他引:3
采用溶胶凝胶工艺在低温下合成均匀透明的PZTS新型多组元凝胶玻璃,并在凝胶玻璃中成功地析出PbTiO3,Pb(Zr,Ti)O3纳米微晶。利用IR谱分析了凝胶玻璃中Si-O-Si,Si-O-Ti等化学键在成胶过程中的形成以及在热处理过程中的变化,根据Kissinger原理估算了PTS凝胶玻璃的析晶活化能。借助XRD较系统地研究了凝胶玻璃在高温下的结晶结构。探讨了在PZS、PZTS体系中ZrO2和Si 相似文献
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以Ba(OH)2.8H2O,Al(NO3)3.9H2O,TEOS为原料,采用溶胶-凝胶法制备BaO-Al2O3-SiO2三元系粉末,研究了不同因素对生成稳定溶胶和胶化时间的影响,用TG-DTA,XRD研究了溶胶-凝胶的热处理过程,用TEM观察了粉体的粒径。 相似文献
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本研究用溶胶-凝胶法制备了含AgX(X:Cl^-、Br^-、I^-)的变色凝胶及玻璃。利用X射线衍射,差热-失重分析,红外吸收光谱和紫外-可见光谱分析,对SiO2凝胶的变色机理进行了研究。本研究为用溶胶-凝胶法制备光致变色玻璃提供了依据。 相似文献
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采用拟薄水铝石和非晶态超细SiO_2微粉为原料。以溶胶-凝胶工艺制取莫来石凝胶,通过干燥、煅烧研制得片状结晶莫来石粉。初步研究了凝胶法莫来石粉在钛酸铝陶瓷和烧结刚玉砖中的应用。实验结果表明:凝胶粉起到了促进烧结、降低烧成温度的作用,并使钛酸铝——莫来石复相陶瓷和刚玉砖的强度得到了显著提高。 相似文献
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用凝胶法制备片状莫来石粉及其应用 总被引:1,自引:0,他引:1
用拟薄水铝石和非晶态SiO_2微粉为原料,用溶胶-凝胶工艺制取了莫来石凝胶。通过干燥、煅烧,制得片状结晶莫来石粉.初步研究了凝胶法莫来石粉在钛酸铝陶瓷和烧结刚玉砖中的应用。实验结果表明,片状莫来石起了促进烧结、降低烧成温度的作用,并使钛酸铝-莫来石复相陶瓷和刚玉砖的强度得到显著提高. 相似文献
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Mullite fibres were synthesised from a mixture of aluminium, aluminium chloride and acidic silica solutions as monophasic salts using a sol–gel technique. The viscosity and rheological behaviour of the mullite precursor sol were examined. Mullite fibres were synthesised using both conventional and microwave sintering techniques. The samples were characterised by X-ray diffraction and scanning electron microscopy. Pure mullite fibres were synthesised by microwave sintering at a relatively low temperature of 1200°C. The grain size of the fibre samples sintered using the microwave technique was finer than that produced by conventional sintering. These results show that microwave sintering is a promising technique for processing mullite fibres. 相似文献
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Debasis Roy Biswajoy Bagchi Alakananda Bhattacharya Sukhen Das Papiya Nandy 《International Journal of Applied Ceramic Technology》2014,11(6):1054-1060
By sol‐gel process, mullite samples doped with 0.002M, 0.02M, 0.1M, 0.15M, and 0.2M of iron, nickel, and copper are prepared. Prepared gels were then dried, grinded, pressed into pellets, and sintered at temperatures 1000°C and 1300°C for 4 h. Mullite densification behavior was analyzed. Our intention is to study the role of metal ions in influencing mullitization behavior in the case of the sol‐gel reaction process, to provide useful information of mullite. This study deals with the effect of metal ions on mullite formation, microstructure, and densification behavior in single‐phase sol‐gel‐derived mullite. 相似文献
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Mullite Whiskers from Precursor Gel Powders 总被引:1,自引:0,他引:1
Mohamed G. M. U. Ismail Hiroshi Arai Zenjiro Nakai Tokuji Akiba 《Journal of the American Ceramic Society》1990,73(9):2736-2739
A mullite precursor sol was prepared by mixing boehmite and silica sols. On addition of 3.5 wt% F− ion as a 47% solution of HF, the mullite sol was gelled. The dried gel was ball-milled and calcined at 1400°C for 1 h in an airtight container. Mullite whiskers grew on the (111) plane along the 〈001〉 direction. 相似文献
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以硝酸和正硅酸乙酯为主要原料,采用溶胶-凝胶法制备莫来石粉末,并利用DSC技术和XRD技术研究了莫来石的形成过程、物相组成,制定出合理的煅烧温度。 相似文献
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《Journal of the European Ceramic Society》1999,19(9):1777-1787
Hot-pressing of mullite and SiC–mullite matrix composites was performed at temperatures and pressures between 1500 and 1650°C and 5 and 15 MPa, respectively. Composites were produced using different precursors; sol–gel derived mullite and kaolinite/α-alumina. The precursor did not strongly affect the optimum density achieved, reaching 97·5% of theoretical for a 20 vol% SiC addition in both cases. The SiC platelet addition impaired densification kinetics in all composites compared to mullite monoliths. Fracture toughness, measured by the indentation strength in bending technique, was marginally higher for the sol–gel precursor material in both monolith and composite. Fracture toughness increased with SiC content for both materials. For example, for the sol-gel precursor material it increased from 2.9±0.1 MPa m1/2 for the monolith to 3.9±0.1 MPa m1/2 for the 20 vol% SiC composite. Similarly, hardness increased with SiC addition for both materials, but the hardness of the sol–gel material was greater than that of the kaolinite+α-alumina material for all compositions. The relationship between microstructure and mechanical properties is discussed. 相似文献
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Hybrid Gels for Homoepitactic Nucleation of Mullite 总被引:2,自引:0,他引:2
Hybrid gels, defined as gels from mixtures of polymerically and colloidally derived sols, offer many opportunities for crystalline microstructure development upon heating. In this study, hybrid mullite gels are formed by mixing a colloidal boehmite—silica sol with a polymeric aluminum nitrate—tetraethoxysilane-derived sol. The polymeric gel crystallizes in situ to form mullite that acts as seed crystals for homoepitactic nucleation during the subsequent transformation of the colloidal component of the hybrid gel. Compared with the entirely colloidal gel, the introduction of a 30 wt% polymeric gel fraction results in an increase in apparent nucleation frequency from ∼5x1011 to ∼1x1014 nuclei / cm3 at 1375°C, a reduction in high-temperature grain size from 1.4 to 0.4 μm at 1550°C, and an increase in the degree of microstructural homogeneity, as evidenced by intragranular pore removal. 相似文献