共查询到19条相似文献,搜索用时 125 毫秒
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振动力场下聚合物熔体流变行为的响应与分析——I.毛细管压力降和熔体表观粘度 总被引:1,自引:0,他引:1
在自行设计的恒速型毛细管动态流变装置上,对聚合物熔体进行动态挤出实验。借助已建立的振动力场下聚合物熔体流变行为的表征公式,分别计算振动力场下聚合物熔体在毛细管壁处的剪切应力、剪切速率和表观粘度。与稳态挤出时相比,引入振动力场后,发现毛细管压力降、表观粘度均显著降低,且随着振动频率和振幅的改变呈非线性变化趋势,作者对此进行了深入分析。 相似文献
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基于壁面滑移条件,建立了微小流道内聚合物黏弹三维共挤出流动模型,并运用有限元方法对流动模型进行了模拟计算。为探究壁面滑移条件下聚合物熔体工艺条件和物性参数对成型的影响,分别设置芯、壳层熔体不同的流率比和黏度比,通过分析流道内外的熔体速度分布及层间界面形貌,探究了无滑移和完全滑移两种壁面条件下,熔体流率和黏度对聚合物微共挤成型层间界面的影响规律。结果表明,无滑移壁面条件下,熔体层间界面不稳定,口模内和口模外界面均发生偏移,且在口模出口处发生突变,熔体离开口后存在胀大和变形现象,其胀大和变形程度随着熔体入口流率比和黏度比的变化而变化;完全滑移壁面条件下,口模内熔体层间界面发生偏移,但口模外界面稳定,不存在挤出胀大和变形,且不受熔体入口流率比和黏度比的影响,这对实现聚合物微复合制品的精密成型具有重要意义。 相似文献
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动态挤出对聚合物不稳定流动力为的影响 总被引:1,自引:0,他引:1
与稳态挤出相比,在振动场作用下毛细管动态挤出聚合物熔体时,发生不稳定流动的临界流率得到提高。研究结果表明,振动条件下挤出聚合物能有效地改善挤出时的不流动现象,从而提高挤出时产量和质量,为聚合物的成型国呀带来巨大在的益处。 相似文献
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修正了脉动压力诱导注射成型充模过程浇口流道中熔体壁面表观剪切黏度的数学模型,并介绍了建立在此基础上的通过实时测量并记录螺杆位置变化以及浇口流道两端熔体压力变化来表征脉动压力诱导注射成型充模过程熔体实时表观剪切黏度的方法,通过实验研究发现,脉动压力的引入对熔体的实时表观剪切黏度产生了深刻的影响,且降低了充模过程单振动周期内壁面熔体的平均表观剪切黏度及受到的平均剪切应力。在此过程中,还提出了特定振动参数下熔体剪切应力与剪切速率之间相位角的计算方法。 相似文献
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采用Bagley入口校正等理论计算方法与实验结果相结合,讨论了超声振动对PS熔体流变及黏弹行为的影响。在口模入口处施加超声振动,降低了聚合物熔体的非牛顿性,改变其黏弹行为,使其在毛细管口模中流动时弹性形变及储能减小,形变松弛加快,黏度降低,从而使挤出加工中流动阻力变小,挤出效率得到提高。 相似文献
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A pulse pressure was superimposed on the melt flow in extrusion, called vibration extrusion. A die (L/D = 17.5) was attached to this device to study the rheological properties of an amorphous polymer (ABS) and semicrystalline polymer (PP, HDPE), prepared in the vibration field, and the conventional extrusion were studied for comparison. Results show that the melt vibration technique is an effective processing tool for improving the polymer melt flow behavior for both crystalline and amorphous polymers. The enhanced melt rheological property is also explained in terms of shear thinning criteria. Increasing with vibration frequency, extruded at constant vibration pressure amplitude, the viscosity decreases sharply, and so does when increasing vibration pressure amplitude at a constant vibrational frequency. The effect of vibrational field on melt rheological behavior depends greatly on the melt temperature, and the great decrease in viscosity is obtained at low temperature. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 5292–5296, 2006 相似文献
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The wall slip of linear polymer melts under ultrasonic vibration is investigated by correcting the slip mechanism, and melt flow behaviors in ultrasonic‐assisted micro‐injection molding (UμIM) method are discussed. Based on the effect mechanism of ultrasonic vibration on the melt, theoretical models of the critical shear stresses for the onset of weak and strong wall slip during UμIM are established, and the change in rheological properties due to the onset of wall slip under ultrasonic vibration is experimental investigated by a built measurement system. The results show that the onset of weak and strong wall slip of the melt in micro cavity are promoted by ultrasonic vibration, which agree with the built theoretical models, and the melt filling capability in micro cavity is enhanced by reducing apparent viscosity and releasing shear stress of the polymer melt, which improves the molding quality of micro polymer parts via UμIM method. POLYM. ENG. SCI., 59:E7–E13, 2019. © 2018 Society of Plastics Engineers 相似文献
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《塑料、橡胶和复合材料》2013,42(2):54-58
AbstractThe entire extrusion process of a polymer melt within a capillary was analyzed thoroughly when a sinusoidal vibration of small amplitude was superimposed in parallel on the flow direction of the polymer melt. On the basis of rheological measurement, an equation for a polymer melt under parallel vibration, i.e. the apparent viscosity, was obtained. Calculation of the apparent viscosity was established by making use of novel experimental equipment. After collecting and analyzing the instantaneous data of capillary entry pressure, capillary volume flux and their phase difference in a superimposed vibration, the apparent viscosity of low-density polyethylene (LDPE) within a capillary was calculated. Meanwhile, the relationship of shear stress vs. shear rate for a LDPE melt with and without imposed vibration was presented. 相似文献
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聚合物动态挤出流变行为研究 总被引:30,自引:5,他引:25
本文论述聚合物材料毛细管动态流变行为的测量原理,介绍了自行研制成功的用于合物熔体挤出的毛细管动态流变仪。在该仪器上对LDPE进行了实验研究,发现熔体的粘度与振动源的频率、振幅呈非线性关系。在振动必场作用下LDPE熔体的粘度减小,随振动频率的变化有一最小值。这对矣合物动态塑化挤出工艺过程控制具有十分重要意义。 相似文献