共查询到17条相似文献,搜索用时 93 毫秒
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介绍了含氟聚酰亚胺的分类和研究动向,重点介绍了含三氟甲基及六氟丙基的聚酰亚胺的特点和性能。阐述了含氟聚酰亚胺在绝缘涂料中的应用,并对含氟聚酰亚胺在光电材料、复合材料和气体分离膜等领域中的应用进行了概述。 相似文献
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当前,气体分离膜是一种环保绿色的分离技术,本文概括了目前用于去除CO2的商业膜材料(醋酸纤维素、聚酰亚胺和含氟聚合物),对不同膜的物理化学性质,气体渗透特性等进行了介绍。 相似文献
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一种新型的膜材料—聚酰亚胺 总被引:1,自引:0,他引:1
介绍了新型膜材料聚酰亚胺的发展历史及其特性;从3个方面阐述了其作为分离膜的研究进展。从聚酰亚胺膜耐高温、耐腐蚀及选择性好的特点出发,对其在气体分离和渗透蒸发应用前景作了展望。 相似文献
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聚酰亚胺作为结构独特的一类功能性高分子材料,应用广泛。随着人们对材料综合性能要求的提高,含氟聚酰亚胺颇受业界关注。聚酰亚胺结构中引入氟原子既能提高材料溶解性和透光率,还能降低其吸湿率和介电常数。综述了近年来含氟聚酰亚胺在设计、合成和应用性能方面的研究进展,指出其结构设计带来的性能优势。特别是对含氟聚酰亚胺的溶解性、光学性能、热性能等进行了总结。展望了其在柔性显示面板/基板市场的应用发展方向。 相似文献
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聚酰亚胺分离膜(PI)是由芳香二酐和二胺单体缩聚而成的,它是主链含有酰亚胺环的一类高聚物。因其具有良好的气体分离性能、热稳定性、耐溶剂性等特性而受到人们的广泛关注。但是,其气体渗透-选择性的平衡问题限制了其在气体分离领域的广泛应用。因此,研究者们将目光转向了聚酰亚胺膜气体渗透性的改性方面,使其具有良好的气体渗透性,用于混合气体的高效分离。文章综述了近年来研究者对聚酰亚胺气体渗透性的研究进展,详细介绍了共混改性、交联改性和分子结构改性方面的最新研究成果,并总结展望了聚酰亚胺膜今后的研究趋势。为未来高效分离膜的研发提供了参考。 相似文献
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Separation of gases through polymeric membrane by selective transport has immense advantages such as light weight, economical, high process flexibility, and space requirements. Fabrication methods of polymeric membrane (polysulfone, polyimide, polyamide, polycarbonate) and their properties along with fundamental principles for gas separation mechanism are discussed in this review. Polysulfone membranes are fabricated by dry/wet phase inversion process to investigate membrane properties. Polyimide membranes show great potential for gas separation and reveal good selectivity for CO2/N2 and CO2/CH4 gas pairs. Transport characteristics of polycarbonate membrane are improved by functionalization. Superior properties allow potential use of polymeric membranes in large-scale industrial applications. 相似文献
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《分离科学与技术》2012,47(8):1161-1178
Abstract The concentration and separation of the amino acids N-benzyloxycarbonyl L-aspartic acid and L-phenylalanine methyl ester hydrochloride in organic solvents have been investigated using reverse osmosis membranes of two types of cellulose acetate, a nanofiltration membrane of polyamide-polyphenylene sulfone (PA-PPSO) composite and a gas separation membrane of polyimide composite in a stirred batch cell. The organic solvents used included primary, secondary, and tertiary alcohols, an ester, and a ketone. There were significant variations in permeate flux, solute rejection, and membrane stability. Usually the rejection of both amino acids was similar; however, certain membrane-solvent combinations gave significantly different levels of rejection. The highest rejection of amino acids (~0.94) at the lowest pressure of 0.5 MPa was obtained with the PA-PPSO membrane using methanol as a solvent. The cellulose acetate membranes gave reasonable rejection and fluxes but the membrane stability was very poor. The performance of the polyimide composite membrane was good with ethanol but poor with other solvents. The PA-PPSO membrane with methanol as solvent appeared the most promising combination, and the separation performance according to concentration polarization was discussed. 相似文献
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酸性侵蚀性气体分离膜材料研究及应用进展 总被引:1,自引:1,他引:0
综述了CO2、H2S、SO2、Cl2及HCl等酸性侵蚀性气体分离膜材料的最新研究与应用进展,讨论了这类气体膜分离工艺对膜材料的要求,介绍了聚酰亚胺(PI)、聚二甲基硅氧烷(PDMS)、聚四氟乙烯(PTFE)、碳分子筛(CMS)等几种耐蚀分离膜材料的特征结构、特点、适用的气体分离类型及相应的分离机理。 相似文献
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The separation of hydrogen from carbon monoxide (syngas ratio adjustment) with polymeric membranes was investigated in this work. A polyimide hollow fiber membrane module was used for hydrogen separation. This polymer has shown large permeability and selectivity for hydrogen separation (selectivity of ca. 30). Permeation tests were carried out at different feed conditions. Feed flow rates were varied between 150–300 mL/min, temperature was varied in the range of 20–80 °C and feed pressure was varied between 5–9 bar. Mixtures containing 0–50 % carbon monoxide were used when carrying out experiments. Measured membrane permeances for hydrogen and carbon monoxide were about 70–100 GPU (gas permeation units) and 3–5.5 GPU, respectively. In addition, a mathematical model for simulation of gas separation in hollow fiber membrane modules with all flow patterns (crossflow, countercurrent and cocurrent) was presented. This model can be used for calculation of membrane performance or its required surface area for a specific separation. Experimental results have shown good correlation with simulation results. Plasticization, competitive sorption and concentration polarization effect of carbon monoxide on membrane performance is shown with experimental results. This effect reduced hydrogen permeances in mixed gas experiments. 相似文献