热变形对高温BTi-62421S钛合金组织及性能影响

对高温BTi-62421S钛合金在不同状态下进行热变形,通过金相组织分析和力学性能测试,研究了变形参数对BTi-62421S钛合金的显微组织与力学性能的影响.结果表明,热变形能明显优化合金的组织和力学性能.其力学性能随变形参数的变化呈规律性变化.变形获得的细等轴组织能得到较优的力学性能.其较优的变形参数为:950℃变形温度、60％变形量.     

BTi-62421S合金高温变形流动应力模型

在Gleeble-3800型热加工模拟实验机上,对BTi-62421S合金在变形程度70%、变形温度850～1 050 ℃、应变速率0.01～30 s-1范围内进行高温压缩实验.通过真应力-真应变曲线,分析流动应力随变形热力参数的变化规律.结果表明:BTi-62421S合金高温变形的流变应力随温度的升高和应变速率的降低而减小;随着应变的增大,合金的真应力-真应变曲线在经历了明显的加工硬化阶段后达到最大值,然后出现流变"软化"现象.以经典的双曲正弦形式模型为基础建立了BTi-62421S合金高温变形的本构方程,同时通过对数据回归处理计算了合金高温变形的应力指数n、应变激活能Q.     

塑性工艺参数对ZTC4钛合金应力-应变和组织的影响

采用不同的塑性工艺参数对铸造Ti-6Al-4V(ZTC4)进行等温变形分析,得出变形应力-应变规律和变形后的内部组织规律;对ZTC4钛合金的原始组织进行了分析,得出原始组织形态的影响规律。     

高温钛合金Ti-55与Ti-60电子束焊接头力学性能

通过研究异种材料高温钛合金Ti-55与Ti-60电子束对接焊接头的微观组织和拉伸力学性能以及焊后热处理对Ti-60接头高温拉伸与持久性能的影响,分析电子束焊接高温钛合金的适用性.采用所选择的电子束焊接工艺焊接高温钛合金,焊缝成形好,表面缺陷少.分别进行了Ti-55,Ti-60,Ti-55+Ti-60焊接接头的室温、高温...     

ZTC4(Ti-6Al-4V)铸造钛合金的退火热处理工艺

介绍了航空航天等工业中大量应用的ZTC4(Ti-6Al-4V)铸造钛合金的退火热处理工艺,包括消除应力退火,普通退火,真空或保护性气氛退火以及真空双重退火.     

Ti—55M高温Ti合金焊缝塑性的改善

考察了Ti-55M高温Ti合金焊接接头力学性能,结果显示焊缝在明显的室脆性,探讨了Ti-55M焊缝室温塑性的各种影响因素,尝试使用调整焊缝化学成分的方法改善Ti-55M焊缝的塑性,选择ELI级Ti-5Al-2.5Sn焊丝、配合脉冲氩弧焊工艺和适当的焊后热处理制度、获得的焊缝塑性接近母材的塑性,接头的室温和高温强度以及高温持久等重要性能能够满足母材技术指标要求。     

气体元素对ZTC4铸造钛合金力学性能的影响

为提高ZTC4钛合金铸件质量,研究了气体元素(H、N、O)含量对ZTC4铸造钛合金力学性能的影响.结果表明,氢、氮、氧在一定范围内能够提高合金的强度;氢控制在0.010％～0.012％,氮控制在0.01％～0.02％,氧控制在0.10％～0.15％时,有利于提高ZTC4钛铸件的综合性能.生产中对自耗电极、铸型、后处理等生产过程进行的技术规范严格控制有利于控制铸件中气体元素含量,获得优质的钛铸件.     

热加工工艺对Ti-38644合金挤压管组织与性能的影响

研究了镦拔工艺、挤压温度以及热处理对Ti-38644钛合金挤压管材显微组织和力学性能的影响。结果表明:Ti-38644合金经过多次镦拔后的挤压管材晶粒得到细化,均匀性更好,从而提高了挤压管材的综合性能。在860℃和930℃挤压Ti-38644合金管材具有良好的力学性能,断面收缩率可以达到60%左右。固溶处理对Ti-38644合金挤压管材的抗拉强度、伸长率和断面收缩率影响不大。860℃挤压Ti-38644合金管经815℃×1 h+550℃×24 h固溶时效热处理后,其抗拉强度大于1116 MPa,伸长率大于15%,断面收缩率大于40%。     

离心力对TC4钛合金铸件孔洞及线收缩率的影响

采用真空石墨型立式离心铸造方法,研究了离心力大小对Ti-6Al-4V(TC4)钛合金铸件内部孔洞率以及铸件宏观尺寸收缩率的影响.结果表明,随着重力系数的增加,铸件中的孔洞率呈指数方式明显减小,给出了两者之间统计关系的表达式;离心转速从0增加到210 r/min时,阶梯铸件长度方向尺寸收缩率呈较明显的减小趋势;同一浇注工艺条件下,与离心力相比,铸型的冷却能力对铸件线收缩率的影响更显著.     

可在400～500℃使用的TC4-B钛合金棒材研制

通过在TC4钛合金中添加Si、O、Mo、Zr、Sn合金元素,研制出名义化学成分为Ti-6Al-4V-0.3Si-0.3Mo-0.3Zr-0.3Sn-0.15O的TC4-B钛合金。并采用两种镦拔组合变形工艺,制备尺寸为?75 mm圆棒和51 mm×85.6 mm扁方棒。结果表明:经"三三一"工艺锻制的TC4-B钛合金棒材显微组织更为均匀;力学性能明显优于经常规工艺锻制的棒材,其室温拉伸强度可达1 000 MPa以上,500℃时拉伸强度可达636 MPa,伸长率为18%,断面收缩率为61%,可在400~500℃高温条件下使用。     

Effects of Post-weld Heat Treatment on Microstructure,Mechanical Properties and the Role of Weld Reinforcement in 2219 Aluminum Alloy TIG-Welded Joints

In as-welded state, each region of 2219 aluminum alloy TIG-welded joint shows diff erent microstructure and microhardness due to the diff erent welding heat cycles and the resulting evolution of second phases. After the post-weld heat treatment, both the amount and the size of the eutectic structure or θ phases decreased. Correspondingly, both the Cu content in α-Al matrix and the microhardness increased to a similar level in each region of the joint, and the tensile strength of the entire joint was greatly improved. Post-weld heat treatment played the role of solid solution strengthening and aging strengthening. After the post-weld heat treatment, the weld performance became similar to other regions, but weld reinforcements lost their reinforcing eff ect on the weld and their existence was more of an adverse eff ect. The joint without weld reinforcements after the post-weld heat treatment had the optimal tensile properties, and the specimens randomly crack in the weld zone.     

The First Phase of the SRIF Industrialized Base in ＂West Area＂ Has Been Put into Operation

After nearly two years＇ tense construction, the first phase of industrialized base of Shenyang Research Institute of Foundry （SRIF）, located at the Tiexi Casting and Forging Industrial Park in the west of Tiexi District, has now been completed and formally put into operation.     

THERMODYNAMICS STUDY ON THE DECOMPOSITION OF CHROMITE WITH KOH

Institute of Process Engineering, Chinese Academy of Sciences, China, has proposed a method for oxidative leaching of chromite with potassium hydroxide. Understanding the mechanism of chromite decomposition, especially in the potassium hydroxide fusion, is important for the optimization of the operating parameters of the oxidative leaching process. A traditional thermodynamic method is proposed and the thermal decomposition and the reaction decomposition during the oxidative leaching of chromite with KOH and oxygen is discussed, which suggests that chromite is mainly destroyed by reactions with KOH and oxygen. Meanwhile, equilibrium of the main reactions of the above process was calculated at different temperatures and oxygen partial pressures. The stable zones of productions, namely, K2CrO4 and Fe2O3, increase with the decrease of temperature, which indicates that higher temperature is not beneficial to thermodynamic reactions. In addition, a comparison of the general alkali methods is carried out, and it is concluded that the KOH leaching process is thermodynamically superior to the conventional chromate production process.     

INFLUENCE OF HEAT TREATMENT ON DAMPING BEHAVIOUR OF THE MAGNESIUM WROUGHT ALLOY AZ61

The effect of isochronal heat treatments for 1h on variation of damping, hardness and microstructural change of the magnesium wrought alloy AZ61 was investigated. Damping and hardness behaviour could be attributed to the evolution of precipitation process. The influence of precipitation on damping behaviour was explained in the framework of the dislocation string model of Granato and Lücke.     

Theoretical Analysis for the Motion and Temperature of Melt Droplets in Spray Degassing Process

The motion of melt droplets in spray degassing process was analyzed theoretically. The height of the treatment tank in spray degassing process could be determined by the results of theoretical calculation of motion of melt droplets. To know whether the melt droplets would solidify during spraying process, the balance temperature of melt droplets was also theoretically analyzed. Then proof experiments for theoretical results about temperature of melt droplets were carried. In comparison, the experimental results were nearly similar to the calculation results.     

Growth Kinetics of Single Inclusion Particle in Molten Melts

On the basis of the single-particle framework, a new theory on inclusion growth in metallurgical melts is developed to study the kinetics of inclusion growth on account of reaction and collision. The studies show that the early growth of inclusion depends on reaction growth and Brawnian motion collision, and where the former is decisive, the late growth depends on turbulence collision and Stokes＇ collision, and where the former is dominant; collision growth is very quick during the smelting process, lessened in the refining process, but nearly negligible in the continuous casting process.     

An Easy Way to Quantify the Adhesion Energy of Nanostructured Cu/X(X=Cr,Ta,Mo,Nb,Zr) Multilayer Films Adherent to Polyimide Substrates

An approach based on film buckling under simple uniaxial tensile testing was utilized in this paper to quantitatively estimate the interfacial energy of the nanostructured multilayer films(NMFs) adherent to flexible substrates. The interfacial energies of polyimide-supported NMFs are determined to be *5.0 J/m2 for Cu/Cr, *4.1 J/m2 for Cu/Ta,*2.8 J/m2 for Cu/Mo, *1.1 J/m2 for Cu/Nb, and *1.2 J/m2 for Cu/Zr NMFs. Furthermore, a linear relationship between the adhesion energy and the interfacial shear strength is clearly demonstrated for the Cu-based NMFs, which is highly indicative of the applicability and reliability of the modified models.     

High-Speed Friction Stir Welding of SiC_p/Al–Mg–Si–Cu Composite

A 17 vol% SiCp/Al–Mg–Si–Cu composite plate with a thickness of 3 mm was successfully friction stir welded(FSWed) at a very high welding speed of 2000 mm/min for the first time. Microstructural observation indicated that the coarsening of the precipitates was greatly inhibited in the heat-affected zone of the FSW joint at high welding speed, due to the significantly reduced peak temperature and duration at high temperature. Therefore, prominent enhancement of the hardness was achieved at the lowest hardness zone of the FSW joint at this high welding speed, which was similar to that of the nugget zone. Furthermore, the ultimate tensile strength of the joint was as high as 369 MPa, which was much higher than that obtained at low welding speed of 100 mm/min(298 MPa). This study provides an effective method to weld aluminum matrix composite with superior quality and high welding efficiency.     

新型的治疗阿尔茨海默氏症药物(1-二甲基磷酰基-2,2,2-三氯)-乙基-1-醇烟酸醋对体外神经细胞的作用

目的: 观察本实验室合成的一种治疗阿尔茨海默氏症(AD)的药物(1-二甲基磷酰基-2, 2, 2 -三氯)-乙基^-1-醇烟酸醋(NMF),对体外培养的皮层神经细胞活性的影响以及对海人藻酸(KA)所致的神经损伤的保护作用。方法: 采用体外培养皮层神经元的方法,解剖分离 15 d胚胎小鼠皮层神经细胞, 接种于 96孔板,48 h 后加药并培养 72 h,以 MIT 法 观察 NMF 对小鼠皮层神经细胞活性的影响;同时将接种于 24 孔板的细胞预先给予 NMF,d 3 时加或不加KA处理后,以台盼蓝染色鉴别并计数死、活细胞,可得出细胞的存活率。结果: NMF 明显促进胎鼠皮层神经元活性,其中 NMF1、0. 1、10nmol·L^-1促进神经元活性增殖率分别高达 34.7%、37.4%、36. 7%, NMF 明显促进正常胎鼠皮层神经元存活卒,与对照组比较,10nmol·L^-1 NMF 对皮层神经元的存活率分别提高 39.3%、73.5%。 NMF能显著 对抗 KA 所致的神经元损伤,与 KA 损伤组相比, NMF0.1、10、10nmol·L^-1对损伤皮层神经元的保护率分别为 77.30%、80.10%、84.15%。结论: NMF 明 显促进胎鼠皮层神经元的洁性、提高正常皮层神经元,的存活卒,并能有效地保护KA所致的神经元损伤,提示 NMF 是一种很有潜力的治疗 AD 的药物。     

A STUDY OF TEMPERATURE-DEPENDENT VALENCE BOND STRUCTURE OF TITANIUM

On the basis of energy and shape method for the determination of the valence bond (VB) structures of crystal, the valence bond structure of titanium is redetermined at room temperature and calculated in the whole temperature range of 0-1943K. The outer shell electronic distribution of Ti is e_c~(2.9907) · (s_c~(0.4980) d_c~(2.4927)) ef1.0093 in crystal. The temperature dependences of the VB structures of hcp and bcc phases are the same. The VB structures of hcp and bcc phases monotonically increase or decrease with the increase in temperature, but show discontinuous changes at the phase-transformation temperature 1155K.