共查询到18条相似文献,搜索用时 286 毫秒
1.
Cdln2O4和Cd2SnO4薄膜X—光电子能谱研究 总被引:1,自引:1,他引:1
研究了在Ar-O2混合气氛中从Cd-In和Cd-Sn合金靶射频反应溅射而的CdIn2O4和Cd2SnO4膜的X-光电子能谱。实验结果表明了粉末Cd,In,Sn,SnO2,In2O3和CdIn2O4,Cd2SnO4膜的Cd,In,Sn3D3/2和3d5/2XPS峰值位置的形状的区别,并讨论了O1s。XPS峰随氧浓度的变化。当氧浓度增加时,O1s分为两个峰。 相似文献
2.
利用AES方法研究了CdIn2O4膜的成分分布。膜中的Cd、In和O成份随O浓度的变化而变化,并对膜的电学性质有重要影响。 相似文献
3.
射频反应溅射CdIn2O4膜制备过程中氧浓度对光学性质的影响 总被引:4,自引:0,他引:4
采用射频反应溅射方法在Ar+O2气氛中制备了CdIn2O4薄膜,报道了在没氧浓度下该膜的透射率和随波长的变化关系。发现氧浓度越高,膜透射率赵低,而消光系数1、折射率相应地越大。对这些结果从CIO膜的晶格常数、载流子浓度等角度进行了理论分析。 相似文献
4.
La2O3对CH4氧化的催化机制 总被引:2,自引:0,他引:2
本文研究了La2O3对CH4氧化燃烧和氧化偶联的催化机制。实验采用的是分子束技术,以及俄歇电子能谱(AES),四极柱质谱(QMS)和X射线光电子能谱(XPS)等表面分析技术。实验结果表明CH4分子的平动能和La2O3表面的晶格氧(O2-)是催化氧化CH4的两个关键因素。燃烧室内壁涂以稀土氧化物催化层将会提高燃烧效率和减少废气污染。 相似文献
5.
用电子束加热真空蒸发法(EBV法)制备了厚度为350nm的ZnIn2S4薄膜。研究了最佳成膜工艺条件和最新电子能谱分析结果;通过不同气氛处理可以控制材料的导电类型,典型膜的电阻率为2.5×10^-1Ω.cm,Hall迁移率为52cm^2.V^-1.s^-1,载流子浓度为1.42×10^17cm^-3,禁带宽度为2.13eV。探讨了ZnIn2S4膜的导电机理,并制作了ZnIn2S4-Si太阳电池。 相似文献
6.
研究了热处理气氛对用无电沉积方法制备的Cd2SnO4导电膜的化学态结构和导电率的影响。X射线光电子能谱和室温电阻率测量结果表明,以氢气为热处理气氛时,薄膜中的氧空位最高,导电性好,真空处理次之,以氧气为热处理气氛时,氧空位少,薄膜的导电性能差。 相似文献
7.
8.
采用金属反射膜和介质膜相结合的方法,研制了三种太阳光控膜系,即ZnS/Ag,In2O3;SnAg和SiO2/Ag,并给出各自的光蛮 相似文献
9.
张其土 《火花塞与特种陶瓷》1998,(1):34-38,56
采用sol-gel的方法在热压Si3N4陶瓷材料的表面涂上一层SiO2涂层或3Al2O3.2SiO2涂层,并用X光电子能谱的方法检测了涂层后的Si3N4陶瓷材料表面。 相似文献
10.
在等离子体化学气相沉积系统中采用高氢稀释硅烷加乙烯法制备了nc-SiCx:H薄膜。系统研究了C2H4/(C2H4+SiH4)(Xc)气体流量比对nc-SiCx:H薄膜的晶化和其它不龟性能的影响。 相似文献
11.
12.
利用射频反应溅射Cd-In合金靶沉积的CdIn_2O_4薄膜是n型高兼并半导体,其红外反射率随溅射气体中氧浓度的不同而有异,相同氧浓度下沉积的薄膜经过退火处理后红外反射率也会发生变化。原因是不同氧浓度下沉积薄膜的氧空位不同,其自由载流子浓度也就不同,从而使薄膜有不同的吸收系数。实验结果与理论计算值符合较好。 相似文献
13.
Hyesun YooJunHo Kim 《Solar Energy Materials & Solar Cells》2011,95(1):239-244
We fabricated Cu2ZnSnS4 (CZTS) thin films using two different methods, spray pyrolysis and sulfurization of Cu-Zn-Sn metallic films. Spray pyrolysis was carried out under air ambient with modified ultrasonic spray system. Sulfurizations of metallic Cu-Zn-Sn films were done for stacked metallic films, Cu/Sn/Zn/glass, Cu/Sn/Cu/Zn/glass and Sn/Cu/Zn/glass, which were prepared by sputtering method in high vacuum chamber. The sprayed films were not observed to be grown well with good crystallinity, compared with CZTS films made by sulfurization of stacked metallic films. However, it was found that application of additional sulfurization to sprayed CZTS films induced great improvement of crystallinity to the level of the sulfurized metallic films. This implicates that spray pyrolysis with additional sulfurization is a good method for fabrication of CZTS films, especially as a low-cost fabrication technique. All CZTS films were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and Raman spectroscopy measurements. 相似文献
14.
Kunihiko Tanaka Yuki FukuiNoriko Moritake Hisao Uchiki 《Solar Energy Materials & Solar Cells》2011,95(3):838-842
The properties of Cu2ZnSnS4 (CZTS) thin films deposited by sol-gel sulfurization were investigated as a function of the chemical composition of the sol-gel solutions used. The chemical composition ratio Cu/(Zn+Sn) of the sol-gel solution was varied from 0.73 to 1.00, while the ratio Zn/Sn was kept constant at 1.15. CZTS films deposited using sol-gel solutions with Cu/(Zn+Sn)<0.80 exhibited large grains. In addition, the band gaps of these Cu-poor CZTS thin films were blue shifted. Solar cells with the structure Al/ZnO:Al/CdS/CZTS/Mo/soda lime glass were fabricated under non-vacuum conditions. The solar cell with the CZTS layer deposited using the sol-gel solution with Cu/(Zn+Sn)=0.80 exhibited the highest conversion efficiency of 2.03%. 相似文献
15.
16.
17.
Kazuya MaedaKunihiko Tanaka Yuki FukuiHisao Uchiki 《Solar Energy Materials & Solar Cells》2011,95(10):2855-2860
Cu2ZnSnS4 (CZTS) thin films prepared by a non-vacuum process based on the sulfurization of precursor coatings, consisting of a sol-gel solution of Cu, Zn, and Sn, under H2S+N2 atmosphere were investigated. The structure, microstructure, and electronic properties of the CZTS thin films as well as solar cell parameters were studied in dependence on the H2S concentration. The sulfurization process was carried out at 500 °C for 1 h in an H2S+N2 mixed-gas atmosphere with H2S concentrations of 3%, 5%, 10%, and 20%. As the H2S concentration decreased from 20% to 5%, the S content of the CZTS thin films decreased. However, when the H2S concentration was decreased below 3%, the S content of the films began to increase. A CZTS thin film prepared with an H2S concentration of 3% had grains in the order of 1 μm in size, which were larger than those of films prepared at other H2S concentrations. Furthermore, the most efficient solar cell, with a conversion efficiency of 2.23%, was obtained from a sample sulfurized at an H2S concentration of 3%. 相似文献
18.
本文建立了以铁酸镍(NiFe2O4)为载氧体的生物质半焦化学链燃烧模型,利用HSC Chemistry 5.0软件对生物质半焦和NiFe2O4载氧体之间的化学链燃烧反应进行了热力学计算,模拟载氧体被半焦还原以及载氧体被空气氧化两个步骤的氧化还原过程,得到燃料反应器的优化操作参数为:载氧体和生物质半焦的摩尔比(O/BC)为1.5,燃料反应器的温度为800℃。热力学分析显示,NiFe2O4在化学链燃烧反应中是按照NiFe2O4→Ni-Fe2O3→ Ni-Fe3O4→Ni-FeO→Ni-Fe的顺序逐级被还原的。氧化过程的模拟说明,在空气气氛中,失去的晶格氧可以恢复到初始的程度,而实验手段得到的氧化产物的X射线衍射图则证明,通过氧化,被还原的载氧体可以大部分恢复到NiFe2O4尖晶石结构。 相似文献