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液液界面法测超滤膜孔径及孔径分布 总被引:9,自引:2,他引:9
本采用液液界面法,利用毛细管现象测定了截留分子量为2×10^4和5×10^4聚砜超滤膜PS-2,PS-5的孔径及孔径分布。结果表明,利用水-正丁醇体系能测定超滤膜的孔径及孔径分布,并且具有操作简便,测试压力接近膜工作压力的优点,对于PS-2超滤膜,测试压力达0.5MPa即能得到膜完整的孔径分布曲线。 相似文献
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研究了中空纤维膜孔径及其分布的测定方法.液液置换法。通过研究建立了能够准确描述跨膜压差与流体通量的数学模型,采用不同的液液体系(正丁醇.纯净水、正戊醇.纯净水和正己醇一纯净水)测定了膜孔径为0.2μm的中空内压疏水膜的孔径及其分布,并对测试结果进行比较分析。实验研究结果与电镜扫描结果符合较好,研究表明液液置换法装置简单、易操作、是一种理想的膜孔径分布表征方法。 相似文献
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不同标准物表征超滤膜截留性能的比较 总被引:7,自引:1,他引:6
本文用蛋白,聚乙二醇和葡聚糖三种不同溶质对聚砚,聚砚酰胺及磺化聚砚三种超滤膜的截留率-分子量曲线进行了测定。对同一种膜,具有相同分子量的不同溶质来说,它们的截留率是不同的。膜对蛋白的截留率高于它对聚乙二醇和葡聚糖的截留率。 相似文献
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超滤膜孔径及其分布的测定方法:I.常用测定方法讨论 总被引:3,自引:0,他引:3
讨论了超滤膜孔径的物理意义,指出其与固体表面吸附体系中孔径概念的区别,讨论了现行各种测定方法的原理及在超滤膜孔径测定中的适用性。 相似文献
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The pore size distribution(PSD)measured by the gas bubble point(GBP)method ofceramic microfiltration(MF)membranes prepared by suspension technique was found to be signifi-cantly influenced by the membrane thickness.A culm-like model for pore structure was introduced tocharacterize the membrane pores instead of the conventional model which does not reflect the radiusvariation along the pore passages and is unable to explain the thickness effect on the membrane PSD.A laminate structure,taking the culm-like model for pore structure into consideration,was hypoth-esized for ceramic MF membranes.A mathematical model was then established to quantitativelydescribe the relationship between the membrane number PSD and the membrane thickness.Goodresults were obtained for the correlation of mean pore size and simulation of the PSD for ceramicMF membranes. 相似文献
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热等离子体制备的超细球形氧化铝具有表面致密光滑、分散性好等特点,本工作以超细球形氧化铝为原料,通过浸渍提拉烧结法,制备了孔径分布窄、渗透通量高的陶瓷超滤膜,研究了烧结温度对陶瓷膜微孔结构的演化、孔径分布和渗透通量的影响。随后对1250℃下烧结的陶瓷膜进行了纳米硅水分散液过滤处理,采用不同堵塞模型分析了陶瓷膜过滤纳米硅水分散液的膜污染过程。结果表明,通过调节烧结温度调控陶瓷膜的微孔结构,当烧结温度为1250℃时,陶瓷膜的孔径分布较窄,孔径大小为25?65 nm,渗透通量为986.4 L/(m2?h)。超细球形氧化铝粒径分布较窄及表面致密光滑有助于1250℃下烧结形成均匀的烧结颈,提供了陶瓷膜较窄的孔径分布。对1250℃下烧结的陶瓷膜进行了纳米硅水分散液过滤处理后其浊度下降为0.231 NTU,浊度去除率达99.96%。采用不同堵塞模型分析了陶瓷膜过滤纳米硅水分散液的膜污染过程,结果表明,纳米硅水分散液的堵塞模型是滤饼过滤,属于可逆污染。 相似文献
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Dong Zou Xuebin Ke Minghui Qiu Xianfu Chen Yiqun Fan 《Ceramics International》2018,44(17):21159-21169
Ceramic microfiltration membranes (MF) with narrow pore size distribution and high permeability are widely used for the preparation of ceramic ultrafiltration membranes (UF) and in wastewater treatment. In this work, a whisker hybrid ceramic membrane (WHCM) consisting of a whisker layer and an alumina layer was designed to achieve high permeability and narrow pore size distribution based on the relative resistance obtained using the Hagen-Poiseuille and Darcy equations. The whisker layer was designed to prevent the penetration of alumina particles into the support and ensure a high porosity of the membrane, while the alumina layer provided a smooth surface and narrow pore size distribution. Mass transfer resistance is critical to reduce the effect of the membrane layers. It was found that the resistance of the WHCM depended largely on the alumina layer. The effect of the support and whisker layer on the resistance of the WHCM was negligible. This was consistent with theoretical calculations. The WHCM was co-sintered at 1000?°C, which resulted in a high permeability of ~?645?L?m?1 h?1 ;bar?1 and a narrow pore size distribution of ~?100?nm. Co-sintering was carried out on a macroporous ceramic support (just needed one sintering process), which greatly reduced the preparation cost and time. The WHCM (as the sub-layer) also showed a great potential to be used for the fabrication of ceramic UF membranes with high repeatability. Hence, this study provides an efficient approach for the fabrication of advanced ceramic MF membranes on macroporous supports, allowing for rapid prototyping with scale-up capability. 相似文献
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颗粒粒径和膜孔径对陶瓷膜微滤微米级颗粒悬浮液的影响 总被引:9,自引:0,他引:9
通过测定颗粒悬浮液通过陶瓷微滤膜时的参透通量及污染阻力,确定了陶瓷膜处理微米级颗粒悬浮液时,颗粒粒径和膜孔径对微滤过程的影响和膜污染机理,获得了微米级颗粒悬浮液微滤过程中膜孔径的选择方法。 相似文献
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A sol-gel method for preparing selective layers of ceramic ultrafiltration membranes based on titania hydrosols is considered. The characteristics of the pore structures of the selective layers are considered as a function of the initial composition and the firing temperature. All of the selective layers have a narrow range of the pore size distribution and meet the requirements imposed on ultrafiltration membranes. 相似文献
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将碳化硅(SiC)粉体和一定量聚碳硅烷(polycarbosilane,PCS)、蒸馏水、聚丙烯酰胺(polyacrylamide,PAM)、聚丙烯酸(polypropylene acid,PAA)混合球磨以制备水性SiC浆料并测定了SiC粒子的动电位及粘度;将浆料均匀涂在SiC支撑体上,在1100℃真空条件下烧成,制备了SiC陶瓷膜并测定陶瓷膜的孔径分布及纯水通量及观察其形貌.研究结果表明:涂膜所用的浆料在pH值为11左右时,SiC粒子动电位最大达到-40 mV,浆料表观粘度最小为20 mPa·s,制备的陶瓷膜孔径大小集中在1μm左右,纯水通量达40 m3/(m2·h). 相似文献
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The determination of the pore size, porosity, number of pores, molecular weight cutoff (MWCO), and morphology of an ultrafiltration membrane is necessary for predicting the performance of a membrane for a specific application. For ultrafiltration membranes prepared from cellulose acetate and sulfonated polysulfone in the presence and absence of various concentrations of the additive poly(ethylene glycol) 600, pore statistics and MWCOs were determined in studies with dextrans of different molecular weights. Surface and cross‐sectional morphologies of the membranes were analyzed with scanning electron microscopy at different magnifications. The pore size increased with increasing concentrations of sulfonated polysulfone and additive in the casting solution. Similarly, the MWCOs of the membranes ranged from 19 to 150 kDa, depending on the various polymer blend compositions and additive concentrations. Results from scanning electron microscopy provided qualitative evidence for the trends observed for the pore statistics and MWCO results. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 430–444, 2002; DOI 10.1002/app.10414 相似文献
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本文描述了醋酸纤维素-纤维素大孔增强超滤膜的结构特征一分离性能之间的关系。详细论述了膜材料含量和粘连剂含量及其分子量对膜结构和性能的影响。论述了不同配方铸膜液的膜,其孔径,水通量和截留率随操作压力的变化规律。实验证明这种高强度的CAC膜经多次重复使用后,其结构性能保持完好。 相似文献