Analytical and experimental investigations of nanoparticles embedded phase change materials for cooling application in modern buildings

This paper presents the analytical and experimental investigations of the phase change heat transfer characteristics and thermodynamic behavior of spherically enclosed phase change material (PCM) with dispersion of nanoparticles for latent thermal energy storage (LTES) system in buildings. In this study, the heat transfer characteristics in terms of the transient temperature variations, moving interface positions, complete rate of solidification and melting were analyzed for the six different PCMs considered in pure form and with dispersed nanoparticles as well. The heat transfer characteristics of the PCMs considered were analytically modeled and experimentally evaluated for the steady state and transient conditions for various heat generation parameters during freezing and melting cycles of the LTES system. The experimental results infer that for the same thermal load conditions the rate of solidification for the PCMs decreased with the increased mass fractions of nanoparticles while compared to the pure PCMs. For the same operating conditions of the LTES system, similar heat transfer characteristics were observed for the six PCMs considered. In this paper, the analytical model solutions and experimental results for the 60% n-tetradecane: 40% n-hexadecane PCM are presented. The solidification time for the 60% n-tetradecane: 40% n-hexadecane PCM embedded with the aluminium and alumina nanoparticles were expected to reduce by 12.97% and 4.97% than at its pure form respectively. Besides, the test results indicate that by increasing the mass fraction of the nanoparticles beyond the limiting value of 0.07 the rate of solidification was not significant further. Furthermore, the rate of melting was improved significantly for the PCMs embedded with the dispersed nanoparticles than the pure PCMs. The analytical solutions obtained for the pure and dispersed nanoparticles based PCMs were validated using the experimental results. The deviations observed between the analytical solutions and the experimental results were in the range of 10%-13%. Based on the analytical and experimental results the present nanoencapsulated LTES system can be regarded as a potential substitute for the conventional LTES system in buildings for achieving enhanced heat transfer characteristics and energy efficiency.     

Solar thermal energy discharging from a multiple phase change materials storage tank

In this work we have studied numerically the charging and the discharging of solar thermal energy stored (TES) using latent heat from a storage unit contains PCMs. We have also studied the improvement of the heat transfer between fluid which is the water and the PCMs by adding the fins to our storage unit with various configurations, including in-line fins and staggered fins. Then, we studied the assembly of two PCMs in our storage unit. In addition, an experimental work has been validated. The ANSYSFLUENT 15 code was used to solve the formulation of the fusion/solidification processes, where three users define have been developed to describe the thermo-physical properties of the PCMs.     

Energy storage and solidification of paraffin phase change material embedded with graphite nanofibers

Phase change materials (PCMs) are known to be excellent candidates for thermal energy storage in transient applications. However, enhancement of the thermal conductivity of a paraffin-based PCM is required for effective performance, particularly during solidification where diffusion is the dominant heat transfer mode. This study experimentally examines the effect that graphite nanofibers (GNFs), aspect ratio and power density have on both thermal storage and solidification time of a PCM which is embedded between two sets of aluminum fins. Additionally, a figure of merit is introduced in order to quantify the effectiveness of each of these three parameters with respect to solidification time. GNF enhancement was shown to reduce the maximum temperature in the thermal containment unit (TCU) by 48%. It was also found that for aspect ratios of 1, the GNF enhancement shortens solidification time by as much as 61% over the paraffin samples. This research indicates that GNF impregnation into phase change materials is an effective method for the enhancement of the thermal energy storage and the solidification of paraffin-based phase change materials.     

Heat Transfer Enhancement for PCM Thermal Energy Storage in Triplex Tube Heat Exchanger

Thermal energy storage is critical for reducing the discrepancy between energy supply and energy demand, as well as for improving the efficiency of solar thermal energy systems. Among the different types of thermal energy storage, phase-change materials (PCM) thermal energy storage has gained significant attention recently because of its high energy density per unit mass/volume at nearly constant temperature. This study experimentally investigates the using of a triplex tube heat exchanger (TTHX) with PCM in the middle tube as the thermal energy storage to power a liquid desiccant air-conditioning system. Four longitudinal fins were welded to each of the inner and middle tubes as a heat transfer enhancement in the TTHX to improve the thermal performance of the thermal energy storage. The average temperature of the PCM during the melting process in the TTHX with and without fins was compared. The PCM temperature gradients in the angular direction were analyzed to study the effect of the natural convection in the melting process of the thermal storage. The energy storage efficiency of the TTHX was determined. Results indicated that there was a considerable enhancement in the melting rate by using fins in the TTHX thermal storage. The PCM melting time is reduced to 86% by increasing of the inlet heat transfer fluid. The average heat storage efficiency calculated from experimental data for all the PCMs is 71.8%, meaning that 28.2% of the heat actually was lost.     

三套管式相变蓄热器强化传热研究

基于三套管式相变蓄热器的特点,提出应用T字形翅片来强化相变蓄热器的传热性能。研究结果表明:添加翅片可有效地降低蓄热器中相变材料的凝固和融化时间,直翅片和T字形翅片的混合强化结构能使凝固过程比未强化结构节省74%的时间,使融化过程节省60%的时间。因此直翅片和T字形翅片的混合使用可以达到进一步强化传热的目的。     

Review on heat transfer analysis in thermal energy storage using latent heat storage systems and phase change materials

Thermal energy storage (TES) is a technology that stocks thermal energy by heating or cooling a storage medium so that the stored energy can be used later for heating and cooling applications and for power generation. TES has recently attracted increasing interest to thermal applications such as space and water heating, waste heat utilisation, cooling, and air conditioning. Phase change materials (PCMs) used for the storage of thermal energy as latent heat are special types of advanced materials that substantially contribute to the efficient use and conservation of waste heat and solar energy. This paper provides a comprehensive review on the development of latent heat storage (LHS) systems focused on heat transfer and enhancement techniques employed in PCMs to effectively charge and discharge latent heat energy, and the formulation of the phase change problem. The main categories of PCMs are classified and briefly described, and heat transfer enhancement technologies, namely dispersion of low‐density materials, use of porous materials, metal matrices and encapsulation, incorporation of extended surfaces and fins, utilisation of heat pipes, cascaded storage, and direct heat transfer techniques, are also discussed in detail. Additionally, a two‐dimensional heat transfer simulation model of an LHS system is developed using the control volume technique to solve the phase change problem. Furthermore, a three‐dimensional numerical simulation model of an LHS is built to investigate the quasi‐steady state and transient heat transfer in PCMs. Finally, several future research directions are provided.     

增强石蜡相变材料传热性能的实验研究

添加高导热颗粒和增大换热面积是当前增强石蜡相变材料传热性能的主要研究方向。以此为基础搭建试验台结合数据采集系统对石蜡在圆管外的熔化凝固过程进行了实验测试,并对各测点的温度变化趋势进行分析,研究了添加不同纳米颗粒和加入金属肋片对换热过程的影响。结果表明:在石蜡溶液中添加纳米颗粒能够起到减小过冷度的效果同时有效增强相变材料的传热性能,添加纳米氧化铜颗粒的传热性能增强效果要优于添加氧化锌颗粒和二氧化硅颗粒;在储热系统中加入肋片能够显著提高相变储能系统的热性能,强化换热过程。     

Review of latent thermal energy storage systems for solar air-conditioning systems

Solar air conditioning is an important approach to satisfy the high demand for cooling given the global energy situation. The application of phase-change materials (PCMs) in a thermal storage system is a way to address temporary power problems of solar air-conditioning systems. This paper reviews the selection, strengthening, and application of PCMs and containers in latent thermal storage system for solar air-conditioning systems. The optimization of PCM container geometry is summarized and analyzed. The hybrid enhancement methods for PCMs and containers and the cost assessment of latent thermal storage system are discussed. The more effective heat transfer enhancement using PCMs was found to mainly involve micro-nano additives. Combinations of fins and nanoadditives, nanoparticles, and metal foam are the main hybrid strengthening method. However, the thermal storage effect of hybrid strengthening is not necessarily better than single strengthening. At the same time, the latent thermal storage unit has less application in the field of solar air-conditioning systems, especially regarding heat recovery, because of its cost and thermal storage time. The integration of latent thermal storage units and solar air-conditioning components, economic analysis of improvement technology, and quantitative studies on hybrid improvement are potential research directions in the future.     

Convective Heat Transfer in a Vertical Rectangular Duct Filled with a Nanofluid

An analysis is performed to study natural convective heat transfer in a vertical rectangular duct filled with a nanofluid. One of the vertical walls of the duct is cooled by a constant temperature, while the other wall is heated by a constant temperature. The other two sides of the duct are thermally insulated. The transport equations for a Newtonian fluid are solved numerically with a finite volume method of second‐order accuracy. The influence of pertinent parameters such as Grashof number, Brinkman number, aspect ratio and solid volume fraction on the heat transfer characteristics of natural convection is studied. Results for the volumetric flow rate and skin friction for Copper and Diamond nanoparticles are also drawn. The Nusselt number for various types of nanoparticle such as silver, copper, diamond and titanium oxide are also tabulated. The results indicate that inclusion of nanoparticles into pure water improves its heat transfer performance; however, there is an optimum solid volume fraction which maximizes the heat transfer rate.     

Approximate analytical solutions for the solidification of PCMs in fin geometries using effective thermophysical properties

Heat transfer enhancement of phase change materials (PCMs) is essential in order to achieve high charge and discharge powers of latent heat storage systems. The utilisation of highly conductive fins is an effective method to improve heat transfer. In the presented paper, solidification times of two fundamental geometries are examined by analytical modelling and numerical computation. These geometries are the finned plane wall and a single tube which is radial-finned on the outside. The paper describes approximate analytical solutions based on the effective medium approach which include the boundary conditions, as well as material and geometric parameters.     

Thermal Energy Storage Performance of Fatty Acids as a Phase Change Material

Thermal energy storage performance of fatty acids and a eutectic mixture as phase change materials (PCMs) has been investigated experimentally. The selected PCMs for this study were palmitic acid, myristic acid, stearic acid, and a mixture of stearic and myristic acids in eutectic combination ratio of 65.7 wt% myristic acid and 34.3 wt% stearic acid. The PCMs have a melting temperature range of 50.0°C to 61.20°C and a latent heat range of 162.0 J/g to 204.5 J/g. The inlet temperature and the mass flow rate of heat transfer fluid (HTF) were selected as experimental parameters to test the thermal energy storage performance of the PCMs. The transition times, temperature range, propagation of the solid-liquid interface, as well as heat flow rate characteristics of the employed cylindrical tube storage system were studied at varied experimental parameters. The experimental results show that the melting front moves to inward in the radial directions as well as in the axial directions from the top toward to the bottom of the PCM tube. It was observed that the convection heat transfer in the liquid phase plays an important role in the melting process. The changes in the studied HTF parameters have more effect on the melting processes than the solidification processes of the PCMs. The average heat storage efficiency calculated from data for all the PCMs is 51.5%, meaning that 48.5% of the heat actually was lost somewhere.     

Buoyancy Induced Heat Transfer Flow Inside a Tilted Square Enclosure Filled with Nanofluids in the Presence of Oriented Magnetic Field

This paper analyzes heat transfer and fluid flow of natural convection in an inclined square enclosure filled with different types of nanofluids having various shapes of nanoparticles in the presence of oriented magnetic field. The Galerkin weighted residual finite element method has been employed to solve the governing non-dimensional partial differential equations. In the numerical simulations, water, ethylene glycol, and engine oil containing copper, alumina, titanium dioxide nanoparticles are considered. The effects of model parameters such as Rayleigh number, Hartmann number, nanoparticles volume fraction, magnetic field inclination angle, geometry inclination angle on the fluid flow and heat transfer are investigated. The results indicate that increment of the Rayleigh number and nanoparticle volume fraction increase the heat transfer rate in a significant way, whereas, increment of the Hartmann number decreases the overall heat transfer rate. It is also observed that a blade shape nanoparticle gives higher heat transfer rate compared to other shapes of nanoparticles. The critical geometry inclination angle at which the maximum heat transfer rate is achieved depends on the nanoparticle volume fraction as well as on the magnetic field orientation. These results are new and have direct applications in solar thermal collectors and thermal insulator of buildings.     

Numerical simulations on performance enhancement of a cross-flow latent thermal energy storage heat exchanger

基于列管式换热器具有传热面积大、结构紧凑、操作弹性大等优点,使其在相变储能领域具有广阔的应用前景。本文建立一种新型列管式相变蓄热器模型,在不考虑自然对流的情况下,利用Fluent软件对相变蓄热器进行二维储热过程的数值模拟。本文主要研究斯蒂芬数、雷诺数、列管排列方式、肋片数以及相变材料的导热系数对熔化过程的影响,并对熔化过程中固液分界面的移动规律进行了分析。模拟结果表明,内肋片强化换热效果明显,特别是对应用低导热系数相变材料[导热系数小于1 W/(m·K)]的列管式蓄热器,相对于无肋片结构,加入肋片（N_fn=2）可缩短熔化时间52.6%。     

Tetradecane and hexadecane binary mixtures as phase change materials (PCMs) for cool storage in district cooling systems

As the demand for refrigeration and air-conditioning has increased during the last decade, district cooling systems have been introduced in some major European cities. In a district cooling system, the combination of central cooling facilities and cool storage systems provides economic advantages over older conventional cooling plants. A cool storage system can meet the same total cooling load as a non-storage system over a given period of time with a smaller chiller. Cool storage systems using Phase Change Materials (PCMs) have a low temperature range and high energy density in the melting solidification of PCMs compared to sensible heat storage. Thus they are advantageous in reducing the storage volume, heat loss, and size of the chilling equipment. In this paper we describe some paraffin waxes and their binary mixtures. We discuss the thermal properties of laboratory-grade tetradecane, hexadecane and their binary mixtures, and we demonstrate their potential for use as PCMs for cool storage. The thermal properties include freezing point, the heat of fusion, thermal stability and volume expansion during the phase change process. In the study, a Differential Scanning Calorimeter (DSC) was used to determine the heat of fusion of these materials and to generate thermal data for study and analysis. The results show that these materials are attractive candidates as potential PCMs for cool storage in district cooling systems. However, because of the high cost of laboratory-grade materials, technical-grade materials must be used for cool storage.     

Review of thermal energy storage for air conditioning systems

Thermal energy storage is very important to eradicate the discrepancy between energy supply and energy demand and to improve the energy efficiency of solar energy systems. Latent heat thermal energy storage (LHTES) is more useful than sensible energy storage due to the high storage capacity per unit volume/mass at nearly constant temperatures. This review presents the previous works on thermal energy storage used for air conditioning systems and the application of phase change materials (PCMs) in different parts of the air conditioning networks, air distribution network, chilled water network, microencapsulated slurries, thermal power and heat rejection of the absorption cooling. Recently, researchers studied the heat transfer enhancement of the thermal energy storage with PCMs because most phase change materials have low thermal conductivity, which causes a long time for charging and discharging process. It is expected that the design of latent heat thermal energy storage will reduce the cost and the volume of air conditioning systems and networks.     

Effect of nanoparticle shape on the heat transfer and thermodynamic performance of a shell and tube heat exchanger

Nanofluid is a heat transfer fluid that can improve the performance of heat exchanger systems. Different parameters such as particle size, shape, and volume concentration affect the performance of these systems. The objective of this paper is to study the effect of different nanoparticle shapes (such as cylindrical, bricks, blades, platelets, and spherical) on the performance of a shell and tube heat exchanger operating with nanofluid analytically. Boehmite alumina (γ-AlOOH) nanoparticles of different shapes were dispersed in a mixture of water/ethylene glycol as the nanofluid. The thermodynamic performance of the shell and tube heat exchanger that is used in a waste heat recovery system was analysed in terms of heat transfer rate and entropy generation. Established correlations were used to measure the thermal conductivity, heat transfer coefficient and rate and entropy generation of nanofluid. The results show an increase in both the heat transfer and thermodynamic performance of the system. However, among the five nanoparticle shapes, cylindrical shape exhibited better heat transfer characteristics and heat transfer rate. On the other hand, entropy generation for nanofluids containing cylindrical shaped nanoparticles was higher in comparison with the other nanoparticle shapes. However, the increased percentage of entropy was below 1%. Therefore, this greater entropy generation could be deemed negligible and cylindrical shaped nanoparticles are recommended to be utilized in heat exchanger systems working with nanofluids.     

Experimental research on thermal characteristics of PCM thermal energy storage units

To explore thermal management integration in electric vehicles (EVs), a phase change materials (PCMs) thermal energy storage unit using flat tubes and corrugated fins is designed. The investigation focuses on the thermal characteristics of the PCM unit, such as the temperature variation, heat capacity, and heat transfer time, etc. Meanwhile, the heat storage and release process will be influenced by different inlet temperature, liquid flow rate, melting point of the PCM, and the combination order of the units. Under the same inlet temperature and flow rate condition, the PCM unit with higher melting point enters the latent heat storage stage slowly and enters the phase change melting release stage quickly. Furthermore, the heat storage and release rates increase with increasing liquid flow rates, but the effects are diminishing in the middle and later periods. The multiple PCM units with different melting temperatures are cascaded to help recycle low-grade heat energy with different temperature classes and exhibit well heat storage and release rates.     

Thermal performance enhancement of melting and solidification process of phase‐change material in triplex tube heat exchanger using longitudinal fins

Efficient application of intermittent renewable energy sources, like solar, waste heat recovery, and so forth, depends on a large extent on the thermal energy storage methods. Latent heat energy storage with the use of phase‐change material (PCM) is the most promising one because it stores large energy in the form of latent heat at a constant temperature. The current study investigates melting and solidification of PCM in the triplex tube heat exchanger (TTHX) numerically. The two‐dimensional numerical model has been developed using Ansys Fluent 16.2, which considers the effects of conduction as well as natural convection. To overcome the limitation imposed by the poor thermal conductivity of PCM, use of fins is the better solution. In the current study, longitudinal fins are used for better performance of TTHX, which increases heat‐transfer area between PCM and heat‐transfer fluid. The effects of location of fins, that is, internal, external, and combined internal‐external fins, are observed. All three configurations improve melting as well as solidification process. During the melting process, internal and combined internal‐external fins are equally efficient, in which maximum 59% to 60% reduction in melting time is achieved. For solidification, internal‐external fins combination gives maximum 58% reduction in solidification time.     

Heat transferential study on a heat storage container with phase change material

This paper presents heat transfer characteristics of a heat storage container utilizing latent heat storage material, calcium chloride hexahydrate (melting point 28°C). The heat storage container is consisted of a vertical cylindrical pipe with a vertical heat transfer tube at the center and the latent heat storage material containing into the cylindrical pipe. The heat release and heat transfer characteristics during the solidification of the latent heat storage material are experimentally studied. The following results are obtained. The relation between the time and total heat flow rate, that is, the heat release characteristics have the following three stages: (1) the stage of sensible heat release from liquid heat storage material, (2) the latent heat release stage, (3) the stage of sensible heat release from solid heat storage material. The actually measured values of thermal resistance show a tendency similar to that of the theoretical values, but their absolute values are smaller than those of theoretical values by about 40%. This is because the solidified crystals of heat storage material do not grow in circular shape concentric with the heat transfer pipe but grow in dendritical shape, and dendritical crystallized portions function as fins.     

Thermal energy storage using saturated salt solutions

In order to reduce the volume required to store low grade thermal energy in water, various systems using phase change materials (PCMs) have been proposed. However, in order to overcome the poor heat transfer characteristics associated with the solidification of the PCM on heat transfer surfaces, large surface areas need to be provided. This is often achieved by encapsulation in either large or small containers, which has the effect of increasing the cost and reducing the effective energy density. Furthermore PCMs can only accept and release heat at one particular temperature. In an attempt to overcome these limitations thermal energy storage using saturated salt solutions has been examined. The energy density for a number of promising salts has been calculated and confirmed by experiment. Energy density increases of up to 4 times that of water are possible, depending on the salt used and the temperature swing permitted. The deposition of crystals from the solution on heat exchanger surfaces has been overcome by the use of a novel self-cleaning technique.