不同处理方法下铁氧体出气性能的研究

为减少加速器束流快引出元件铁氧体材料真空出气量,对铁氧体材料进行真空除气、镀膜以及烘烤工艺处理。采用旁路切换法(SPP)测量不同处理条件下的出气率。结果表明,铁氧体材料经真空除气后镀TiN膜,在测试罩中经烘烤,冷却后充氮气测得的出气率最低。     

以废旧干电池电解质为原料制备Mn-Zn铁氧体及磁性能研究

以废旧干电池电解质、氧化铁为原料,固相法成功地制备Mn-Zn铁氧体粉体。通过X射线衍射仪、场发射电子显微镜和激光粒度分析仪等测试手段分析了其物相、微观结构和形貌,用振动样品磁强计测量其室温下磁性能。结果表明:650℃煅烧3h,废旧干电池电解质主要组成为ZnMn2O4。基于Mn-Zn铁氧体的化学计量比,称取废旧干电池电解质和氧化铁,900℃煅烧3h,可以获得尖晶石型Mn-Zn铁氧体粉体,平均颗粒尺寸约2μm。室温下,样品磁滞回线显示了典型软磁材料特性,其比磁饱和强度和矫顽力分别为17.68A·m2/kg和203A/m。     

纳米Mn-Zn铁氧体的制备研究进展

Mn-Zn铁氧体是应用最广泛的软磁铁氧体材料.目前,电子器件及产品逐渐向小型化、轻量化和高性能化方向发展,因此要求Mn-Zn铁氧体粉体接近或达到纳米级.作为一种新材料,纳米Mn-Zn铁氧体的研究已经成为磁性材料研究的热点领域.综述了纳米级Mn-Zn铁氧体制备的有效方法,包括化学共沉淀法、水热法、溶胶-凝胶法、喷雾热解法、回流法、超临界法等,介绍了作者在纳米Mn-Zn铁氧体制备方面的最新工作.结合相关技术的发展,展望了纳米Mn-Zn铁氧体制备方法的发展趋势.     

微波烧结Mn-Zn 铁氧体的微观结构演变特征

以传统氧化物法合成的Mn-Zn铁氧体前驱体和外购前驱体为实验原料,经压制成形后用频率为2.45 GHz的微波在1 200~1 400℃烧结制备Mn-Zn铁氧体软磁材料.对烧结过程样品的微观结构和形貌进行了研究,并探究了烧结过程致密化特性及微波加热温度对Mn-Zn铁氧体密度的影响.研究表明:微波烧结的Mn-Zn铁氧体具有典型的尖晶石结构,样品主体相为Mn0.4Zn0.6Fe2O4;用SEM观察样品形貌,发现在1 350~1 400℃烧结的样品结晶状况良好,晶界平直,烧结组织均匀;微波烧结温度对密度有较大影响,在1 200~1 400℃,随着烧结温度升高样品密度增高,密度为4.80~5.28 g/cm3,在1 400℃烧结样品比较致密.微波烧结可以实现样品的快速致密.     

高能球磨法制备Mn-Zn铁氧体材料的研究

以Fe2O3、Mn3O4和ZnO为原料,采用高能球磨法成功制备了Mn-Zn铁氧体,并利用XRD、SEM以及VSM等测试技术对样品进行了表征.研究了预烧温度对铁氧体相的形成过程以及烧结铁氧体材料的显微结构和磁性能的影响.结果表明,随着预烧温度的升高,预烧粉体的颗粒尺寸逐渐增大,起始磁导率和饱和磁化强度均呈现先增大后减小的趋势.适宜的预烧温度为850℃,高于或低于此温度,烧结铁氧体材料的显微结构和磁性能都会恶化.     

我国Mn-Zn铁氧体的现状及发展前景

Mn-Zn铁氧体的产量约占软磁铁氧体总产量的70％，是当前软磁材料中最受关注和最为活跃的领域。多年来相关工作者对其生产技术的发展和应用研究倾注了极大的精力，使我国铁氧体产业得到了迅猛发展。     

CaO对Mn-Zn铁氧体微观结构与磁性能的影响

采用传统氧化物陶瓷工艺制备了CaO-Bi2O3-MoO3-Nb2O5复合掺杂高磁导率Mn-Zn铁氧体材料,利用扫描电子显微镜(SEM)、B-H测试仪和阻抗分析仪等对材料结构和磁性能进行了表征,研究了不同添加量CaO对高磁导率Mn-Zn铁氧体的微观结构和磁性能的影响.结果表明,添加适量的CaO可以细化晶粒、提高材料的频率特性和品质因数Q,降低材料的损耗;当质量分数CaO=0.030%时,材料具有最佳的综合性能:μi=9 772.22,L200/L10=99.36%,室温PCV=435.14mW/cm3.     

当前Mn-Zn铁氧体及其原材料的市场形势

Mn—Zn铁氧体的产量占软磁铁氧体总产量的比例已近90％，其在国民经济与现代科技领域中的作用不言而喻。近年来由于铁矿石与有色金属的涨价风，造成了Mn-Zn铁氧体原材料价格连锁上涨，但是由于种种原因，Mn-Zn铁氧体制品的价格却难以上涨，这给Mn—Zn铁氧体制造商的生产与经营带来很大的压力。     

抗电磁干扰Mn-Zn铁氧体的应用及发展

电磁干扰(EMI)随着电子设备的高速发展成为越来越突出的问题,电子市场已经出台相应的电磁兼容(EMC)市场准入认证.今后的电子元器件及电子设备必须符合相应的市场准入认证.所以,Mn-Zn铁氧体作为电子行业的重要基础材料之一,必须加强抗EMI性能的研究.由于其本身具有吸收和衰减电波的电磁能量性质,成为民用和军事方面抗EMI的重要研究和应用材料.论述了抗EMI Mn-Zn铁氧体材料的主要性能指标,目前国内外已有的该类材料的主要种类,以及相关磁芯的种类及其应用领域.提出今后可能的主要研究或发展方向的见解,认为抗EMI Mn-Zn铁氧体材料和元器件应成为我国目前的重点发展方向.     

电子材料

<正>日立金属开发出新型磁芯材料日立金属公司开发出了高频特性出色的锰锌(Mn-Zn)类铁氧体磁芯材料"ML95S"和"ML90S"。新材料在几兆赫兹高频范围内的磁芯损耗较小,可使网络设备、汽车以及智能手机配备的部件实现小型化和节能化。此前也有过在0.5~5MHz的高频范围采用镍锌(Ni-Zn)类铁氧体材料的讨论,日立金属此次通过组合使用粉末控制技术和热处理技术,实现了与Ni-Zn类铁氧体材料相比饱和磁通密度更高、磁芯损耗更小的Mn-Zn类铁氧     

Interface reactions between glass melts containing transition metal oxides and ferrites

The interface reactions between SiO₂-PbO-MO melts (M = Fe, Mn, Zn and Ni) and Mn-Zn and Ni-Zn ferrites were studied using electron probe microanalysis and X-ray diffraction. Ni ions in the glass melt containing NiO were localized at the interface between the glass and Mn-Zn ferrite. The Ni-rich layer was also detected at the interface between NiO containing glass melt and Ni-Zn ferrite; the composition of this layer was thought to be close to NiFe₂O₄. Pb₈NiSi₆O₂₁ crystal was deposited as the product of the reaction with the glass melt and Mn-Zn ferrite at 700 °C. As compared with Mn-Zn ferrite, no reaction products were formed in Ni-Zn ferrite at various temperatures. The dissolution length of Mn-Zn ferrite in SPN5 glass melt was found to be smaller than for other melts, and it is concluded that the NiO-rich layer at the surface of the ferrite is chemically very durable to the glass melts.     

雷达吸波包装膜的研究初探

采用2种不同的铁氧体(复合铁酸锌锰及复合铁酸镍锰)与线性低密度聚乙烯(LLDPE)共混制备了雷达吸波包装膜,分别对热压工艺、介电性能、透湿性能及力学性能进行了研究,结果发现粉末状的LLDPE与铁氧体的混合效果优于颗粒状的LLDPE,铁氧体的加入能明显提高LLDPE的介电损耗,但会使LLDPE的透湿率变大,力学性能变差.当复合铁酸锌锰/复合铁酸镍锰的重量比为45/55,且总含量为30%(质量分数)时,制备出的LLDPE膜具有最佳的隐身及综合力学性能.     

Using a Single Toroidal Sample to Determine the Intrinsic Complex Permeability and Permittivity of Mn–Zn Ferrites

Analysis of the principle of the published lumped circuit methods for determination of the intrinsic complex permeability and permittivity of the Mn-Zn ferrites reveals that as long as the electric and the magnetic field distributions in the core(s) in two measurements are different, the two intrinsic values can be determined. Using this principle, we developed a set of general lumped circuit methods based on a toroidal Mn-Zn ferrite core as the measurement sample. We examined two possible different excitation modes: magnetic field excitation and electric field excitation. The two different excitation modes result in significantly different field distributions in the sample. Thus, high accuracy can be guaranteed in principle. For the magnetic field excitation, we present in this paper a general finite-difference method to solve the fields in the core and the impedance of the ferrite core inductor. To avoid the stray capacitance among the coils of the ferrite core winding inductor in the measurement, we made a set of short-ended coaxial test fixtures. We performed experiments to determine the intrinsic complex permeability and permittivity of a Mn-Zn ferrite core up to 10 MHz by using the two general methods and validated the measured intrinsic values experimentally.     

Experimentally Verified Mn–Zn Ferrites' Intrinsic Complex Permittivity and Permeability Tracing Technique Using Two Ferrite Capacitors

After setting up a mathematical model for rectangular-shaped Mn-Zn ferrite capacitors, this paper investigates dimensional effects on the intrinsic complex permittivity and the measured apparent complex permittivity of Mn-Zn ferrite blocks. The simple block structure of the samples guarantees their easy and precise preparation. Above a few hundred kilohertz, dimensional effects make the measured apparent complex permittivity deviate from its intrinsic value. This paper uses a Newton-Raphson based method to trace the intrinsic complex permittivity and permeability from the measured impedances of two rectangular-shaped Mn-Zn ferrite capacitors in the frequency range from a few hundred kilohertz to 40 MHz. From the traced intrinsic complex permittivity and permeability, the apparent complex permittivity of a third sample with different dimensions is then calculated theoretically. The papers also presents results of experiments carried out to measure the apparent complex permittivity of the third sample; agreement between the measured and the calculated values is very good. This justifies the validity of the method presented in this paper, when used to determine the dimension-independent intrinsic complex permittivity and permeability of Mn-Zn ferrites     

铁氧体与水泥复合吸波材料的研究

以碳酸锰、氧化锌和氧化铁为原料,经球磨、煅烧得到锰-锌铁氧体,然后与水泥复合制得水泥基复合吸波材料,研究铁氧体吸波剂掺量、胶凝材料品种和试样表面形状对复合材料吸波性能的影响及其力学性能.结果表明:铁氧体在水泥材料中较稳定,其用量和复合材料的表面形状对吸波性能均有较大程度的影响;在8～12.5GHz频率范围内,掺35%铁氧体的水泥基复合材料的反射率基本上都＜-6dB,而粗糙面试样的反射率均＜-7dB,最小反射率达-10.5dB;其28d强度与纯水泥样品相比约有下降.     

Pulsed laser deposition of Mn-Zn ferrite thin films

Mn-Zn ferrite thin films were deposited on sapphire substrates by pulsed laser deposition from sintered Mn_{1 – x}Zn _x Fe₂O₄ ceramic targets. A full stoichiometric transfer from targets to substrates was achieved. Magnetic inplane measurements in two perpendicular directions were carried out and the macromagnetic properties of films were determined. The hysteresis loops obtained are rectangular and the values of the coercive force, the saturation, and the remanent magnetization are comparable to the same parameters of the bulk Mn-Zn ferrite. The films were characterized using a vibrating sample magnetometer (VSM), a scanning electron microscope (SEM) and by X-ray photoelectron spectroscopy (XPS).     

A practical method to determine intrinsic complex permeabilities and permittivities for Mn-Zn ferrites

Mn-Zn ferrite cores present high permeability within the kilohertz-to-megahertz frequency range. They also present high permittivities within the same frequency range. High permeabilities lead to significant permittivity measurement errors when the conventional two-parallel-electrode method is used. In contrast, high permittivities result in the deviations of measured permeabilities from their intrinsic values. This paper presents a field-circuit coupled method to study each of these two phenomena by examining a ferrite toroid with rectangular cross section. The same toroid is used to construct an inductor and a capacitor, respectively. Analytical expressions for electric and magnetic fields in, and complex power supplied to the inductor and capacitor are formulated. Results are obtained, which show that the measured permeabilities and permittivities for Mn-Zn ferrites deviate from their intrinsic values significantly. A Newton-Raphson method is then introduced to determine the intrinsic permeabilities and permittivities based on their measured values.     

Hot-pressed Mn-Zn ferrite for magnetic recording heads

Hot-pressed ferrites have been studied in connection with fabrication of a high quality head material. A two-step hot-pressing technique has enabled the preparation of hot-pressed ferrite with a porosity lower than 0.1 percent and an adjusted average grain size between 0.1 μm and 500 μm. The largest available ingot of hot-pressed ferrite is 120 mm in diameter and 20 mm in thickness. A hot-pressed Mn-Zn ferrite with an adjusted microstructure can be made with a μmof 40 000 and an Hclower than 0.02 Oe. A hot-pressed Mn-Zn ferrite of another composition will have a Bmgreater than 5000 G and a μ0of 700 at 10 MHz. The effect of mechanical working on magnetic properties of hot-pressed ferrites, single-crystal ferrites, and high-density ferrites is also described. The lapping characteristics and the wear problems in a ferrite head of hot-pressed, single-crystal, and high-density ferrite are also discussed.     

Characteristics of powder and sintered bodies of hydrothermally synthesized Mn-Zn ferrites

To improve the sinterability of powders fabricated by the conventional mixed-oxides method, ultrafine Mn-Zn ferrite powders were hydrothermally synthesized from metal nitrates solution using ammonia as a precipitant. The R value (alkalinity) was introduced to adjust the amount of added OH^– in the reaction suspension. The characteristics of the powders synthesized at different hydrothermal conditions and the properties of the sintered bodies were investigated. The results show that the R value and hydrothermal time have a great effect on the compositions and phases of hydrothermally synthesized Mn-Zn ferrite powders. Powders synthesized from a starting suspension with a higher content of Zn ions (or lower content of Mn²⁺) may approach to a stable spinel structure with a lower Mn/Zn ratio as the hydrothermal time is longer. Factors affecting the position of the diffraction angle (2) of the spinel Mn-Zn ferrite (311) of powders may include both the compositions of spinel ferrite structure and crystallite sizes (or particle sizes) of powders. Some possible reasons were suggested to explain the dependence of composition and phase of hydrothermally synthesized Mn-Zn ferrite powders on the R value and hydrothermal time. The temperature that the green compact begins to shrink at increases with increasing R value, and ranges from 510°C (R = 2) to 650°C (R = 6). After being sintered at 950°C for 2 h in N₂ atmosphere, the relative sintered density of each specimen reaches a value of 94.5–99.8%.