基于ATR技术的有机聚合物二次电光系数的测量

二次电光效应是有机聚合物材料一种重要的电光特性,利用这种特性可以制备有机聚合物电光调制器等电光器件.有机聚合物材料的二次电光系数是衡量其二次电光效应的一个重要参数,其可以用一个6×6阶的张量来表示.利用该张量的对称特性、各个元素之间的已知关系以及折射率椭球公式,本文提出了一种基于衰减全反射(ATR)技术的测量有机聚合物二次电光系数的方法.在测量中,通过选用TM偏振光以及TE偏振光作为测量光束,可以分别获得二次电光系数张量中S11以及S12元素.利用已知关系,可以计算得到S44以及直流克尔系数.从而得到二电光系数张量中所有元素的值.     

300MHz 衰减全反射型有机聚合物电光调制器

基于衰减全反射原理的反射型有机聚合物电光调制器,具有成本低、插入损耗低、受聚合物本征损耗影响小、工作波长范围宽等优点。本文采用了溅射,旋转涂覆,电晕极化等方法来制作电极,并通过减小衰减全反射型有机聚合物电光调制器上下两电极的重叠面积,提高了器件的调制带宽,在实验上实现了300MHz射频信号的调制。     

有机二阶非线性光学材料的材料设计研究进展

综述了有机二阶非线性光学材料的材料设计研究进展，详细讨论了插层材料，极化有机聚合物和有机无机复合材料的研究现状和未来的研究方向。     

极化聚合物薄膜电光系数的实时测量

提出了一种极化聚合物薄膜电光系数的实时测量方法。实验结构由耦合棱镜和依次制备在棱镜底面的四层薄膜组成,这四层薄膜分别是金属层（作为上电极）、极化聚合物,缓冲层和下电极。包含导波共振角并具有一定角度的入射光线会聚于棱镜底面,然后用CCD探测拍摄反射光斑,当外加电场作用于上下电极时,就可从光斑暗线位置的变化测量极化聚合物薄膜的电光系数。在测量过程中,使用了计算机图像处理方法和光学空间滤波技术。     

栅极偏压对电光聚合物电晕极化的影响

实验研究了带栅极的电晕放电极化系统的性能。比较了不同栅极偏压下的电晕放电特性。分析了极化电压、栅极偏压和极化电场分布等相关问题。实验结果显示,栅极偏置电晕放电极化系统的电光聚合物极化效果较无栅极时好得多。     

光折变聚合物的研究进展

近年来，聚合物光折变材料越来越受到人在关注，因为民无机材料相比，聚合物材料有较高的电光系数，较高的光损伤阈值，低的直流电常数，而且易于加工，所以光折变聚合物材料显示光明的应用前景，文中介绍了光折变产生的简单的机理，以及目前国际上所研究的各类材料及发展状况。     

具有激发态性质的新型有机半导体材料

高度评价了国内在三线态有机电致发光材料、有机半导体复合材料中的光伏极性反转、共轭聚合物中的光致极化反转的研究中取得的创新性成果，旨在增加研究者对有机半导体材料激发态及其性质的研究这一新兴领域的了解和认识，引起学术界对激发态有机半导体材料的深思与讨论，共同探索有机光电信息材料研究领域中创新的源头。     

光漂白对极化聚合物薄膜非线性效应的影响

利用Cerenkov倍频辐射对极化聚合物薄膜在光漂白下二阶非线性效应的变化进行了研究。 实验表明光漂白能破坏有机聚合物中极化分子的取向稳定性,造成其二阶非线性效应衰减。实验测得漂白后交联型材料的二阶倍频信号衰减了28%,而侧链型材料则衰减了75%。     

非线性光学活性分子的线性电光效应

报道了反射型电光调制法研究６种偶氮化合物的线性电光效应,分析了给体－受体强度、掺杂浓度对线性电光系数的影响。结果表明,掺杂偶氮化合物４－「２－羟乙基苯甲氨基」－４－硝基偶氮苯的极化聚合物薄膜具有较强的线性电光效应,其线性电光系数随参杂浓度的增大而增大。     

溶剂法制备聚合物分散液晶膜

用溶剂法制备了聚合物分散液晶膜。采用偏光显微镜、扫描电子显微镜和电光仪对相分离和聚合物分散液晶材料的电光性能作了初步探讨。研究结果表明，升温速度和聚合物含量对PDLC膜的相分离结构和响应电压有显著的影响。     

Ultraviolet photobleaching process of azo dye doped polymer and silica films for fabrication of nonlinear optical waveguides

We describe the effect of UV photobleaching of poled polymer and silica films and the application of UV photobleaching to waveguide-type optical devices. Disperse Red 1-doped poled polymer and silica films with large and stable second-order nonlinearity were used as nonlinear optical materials. We investigated the mechanism of UV photobleaching of poled films by the changes in absorption spectrum and nonlinearity and refractive index. Moreover, simple fabrication of both the channel waveguide and the chi((2)) diffraction grating based on UV photobleaching is demonstrated.     

聚酰亚胺基二阶非线性光学材料的研究进展

由于极化聚合物在集成光电子学领域的潜在应用前景已经引起广泛关注 ,而聚酰亚胺由于其优异的热稳定性、电性能和机械性能以及在微电子工业的广泛应用 ,使得聚酰亚胺基二阶非线性光学材料倍受重视。本文在简要介绍极化聚合物基本知识的基础上 ,综述了近几年来聚酰亚胺基二阶非线性光学材料的研究进展 ,主要介绍了聚酰亚胺及其生色团的设计与合成 ,其极化方法和松弛机理的研究     

Polymer optical fibers and nonlinear optical device principles

Basic principles of the present optoelectronic research activities at Hoechst AG are presented in this contribution. Within the diversified broad band spectrum of optoelectronic materials and applications our interest is focused on new types of polymer optical fibers and nonlinear optical device principles using organic Langmuir–Blodgett films and electrically poled polymers. The basic principles and the limits of the present research and development activities which, have a high market potential are outlined.     

Comparison of parallel-plate and in-plane poled polymer films for terahertz sensing

We have performed calculations and measurements of the efficacy of two poling geometries of poled electro-optic (EO) polymer films for use in sensing terahertz (THz) radiation via EO sampling. Taking reflective and absorptive losses into consideration, we find that a parallel-plate (PP) poled film has a sensitivity maximum when oriented at 55 degrees to the incident probe and THz beams. In addition, we show that our in-plane (IP) poled polymer films are comparable in sensitivity to PP-poled films and discuss the potential for improving IP-poled polymer devices.     

一种新型二阶非线性光学聚合物材料

报导了一种新型含有五员呋喃杂环非线性光学生色团,并且引入到聚甲基丙烯酸甲酯侧链中。旋转涂膜后,采用电晕极化、紫外－可见光谱研究表明色团虽然具有较大共轭长度,其截止吸收波长却很小。同是该聚合物聚向稳定性很好。     

Single-pulse ultraviolet laser recording of periodically poled structures in polymer thin films

A simple fabrication technique for nonlinear polymeric optical waveguide patterns is introduced based on the two-beam interference method. We determined that the second-order nonlinearity of poled polymer films is erased by single-pulse ultraviolet (UV) laser irradiation. The erasure mechanism for second-order nonlinearity is discussed. To form a periodic structure in an optical polymer waveguide, two types of optical configuration of two-beam interference were arranged, and a single-pulse UV laser was exposed directly onto poled films. We prove that this method provides a simple way to fabricate volume-type and ridge-type periodically poled structures, i.e., chi((2)) gratings, from the submicrometer to the millimeter range.     

Improvement of the interferometric method for measuring electro-optic coefficients of poled polymer thin films

The interferometric method for measuring the linear electro-optic coefficients of polymer films has been improved. This improved method is based on using the antipiezoelectric effect of a quartz crystal to compensate for the change in the optical path length that is due to the electro-optic effect of a polymer film. The electro-optic coefficients of six kinds of new poled polymer film have been determined at a wavelength of 633 nm by this new method. This technique offers a simple, rapid, and highly sensitive method for measuring the electro-optic coefficients of polymer films.     

非线性光学聚合物薄膜DCDHF-2-V/PMMA的特性

将新型有机非线性光学分子DCDHF-2-V按一定比例掺入聚甲基丙烯酸甲酯(PMMA)中,采用旋涂方法制备聚合物薄膜。为了得到宏观二阶非线性光学特性,在90℃对薄膜进行电晕极化,形成各向异性。对极化前后的薄膜进行紫外/可见光吸收频谱分析和原子力显微镜分析。采用RHF方法在6-31G基组上对DCDHF-2-V/PMMA薄膜体系中的DCDHF-2-V分子和PMMA进行闭壳层Hartree-Fock理论计算,得到它们的一阶超极化率β分别为60.278755×10-30esu和10.902267×10-34esu。     

Efficient poling of electro-optic polymers in thin films and silicon slot waveguides by detachable pyroelectric crystals

Pyroelectric crystals are used as a conformal and detachable electric field source to efficiently pole electro-optic (E-O) polymers in both parallel-plate (transverse) and in-plane (quasi-longitudinal) configurations. Large Pockels coefficients in poled thin films and high tunability of resonance wavelength shift in hybrid polymer silicon slot waveguide ring-resonator modulators have been achieved using this method.