喷射电沉积Cu-Al2O3复合电铸层性能研究

利用喷射电沉积工艺制备了Cu-A l2O3纳米复合铸层,分析了纳米A l2O3颗粒添加量,阴极电流密度以及电铸液喷射速度对复合电铸层中纳米颗粒复合量的影响,采用扫描电镜(SEM)及其附带的能谱仪(EDS)对复合电铸层的微观形貌和铸层成分进行了分析,研究了复合电铸层中纳米颗粒复合量对其显微硬度的影响。结果表明,铜沉积层具有纳米晶微观结构,平均晶粒尺寸约为50 nm;纳米A l2O3颗粒在沉积层中的复合量可达14.43(at%);纳米复合铸层的显微硬度有明显提高,约为普通粗铜的10.5倍.     

喷射电沉积Ni-Al2O3纳米复合镀层的组织及性能

利用喷射电沉积工艺制备了Ni-Al2O3纳米复合镀层,分析了纳米Al2O3颗粒添加量、阴极电流密度以及电解液喷射速度对复合镀层中纳米颗粒含量的影响,采用扫描电镜(SEM)以及X-射线衍射仪对复合镀层的微观形貌进行了分析,研究了复合镀层中纳米颗粒含量对其显微硬度、结合强度、耐腐蚀性的影响。结果表明,镍沉积层具有纳米晶微观结构,平均晶粒尺寸约为50nm;纳米Al2O3颗粒在沉积层中的含量可达12.2at%;随Al2O3含量的提高,镀层显微硬度逐渐提高,结合强度和耐腐蚀性先提高后有所降低。     

镍-铁-磷/金刚石复合沉积工艺与性能研究

以三元合金为基体的复合电沉积层综合了一般耐磨镀层的性能和所镶嵌的固体微粒的性能.为开发新型多元非晶态合金耐磨复合沉积层,以复合沉积层耐磨减摩性为主要衡量指标并综合考虑其他性能指标,用正交试验法进行了镍-铁-磷/金刚石复合电沉积工艺与性能的研究.结果表明,在试验所采用的复合电沉积工艺控制范围内,可获得金刚石微粒弥散分布的镍-铁-磷/金刚石复合电沉积层,通过调整沉积工艺参数,能得到不同金刚石微粒复合量的复合电沉积层;在镀态下该复合沉积层(基质)呈非晶态结构;较佳综合性能复合层的电沉积工艺参数为:镀液中金刚石微粒(0.5～1.0 μm)含量6 g/L;NaH2PO2·H2O含量2 g/L;FeSO4·7H2O含量70 g/L,其对制备具有良好摩擦学特性的镍-铁-磷/金刚石复合沉积层具有重要的参考价值.     

超声电沉积法制备Ni-Y_2O_3纳米复合镀层的工艺

Y2O3-Ni复合电沉积层性能优异,用途颇多,但目前有关这方面的研究报道较少.采用超声波技术电沉积制备了Ni-Y2O3纳米复合镀层,考察了制备工艺参数对复合镀层中Y2O3含量和镀层硬度的影响,采用环境扫描电子显微镜(ESEM)对纳米复合镀层的表面形貌进行了分析.结果表明,Y2O3添加量20g/L、Jc 2 A/dm2、超声波功率300 W时,复合镀层的表面组织均匀致密、晶粒细小且显微硬度较高;超声波空化作用产生的微射流可以减少纳米颗粒团聚,提高镀层的性能.     

纳米SiO2化学复合镀镍工艺研究

采用正交试验法,通过测试镀层孔隙率、结合强度和盐雾试验耐蚀性,筛选了Ni-P-纳米SiO2化学复合镀工艺.考察了溶液pH值和温度对镀层质量的影响,确定了纳米SiO2微粒的加入方法.结果表明,该工艺稳定性好,纳米SiO2微粒在镀液中分散均匀,在pH=4.1～4.6,温度85～90℃范围内所得Ni-P-纳米SiO2化学复合镀层结合强度达到GB/T 13913-92要求,无孔隙,镀层耐蚀性能明显提高.     

纳米SiC复合镀层制备工艺的研究

在A3钢板上制备了含有纳米SiC的镍基复合镀层，在MM－200摩擦磨损试验机上对镀层进行磨损试验，研究了阴极电流密度、镀液温度、SiC浓度和pH值等主要工艺参数对镀层耐磨性能的影响，以确定工艺参数范围，并采用正交试验方法分析得到最佳的工艺参数。结果表明，纳米SiC复合镀层的最佳工艺参数为：电流密度3A／dm^2，温度30℃，SiC含量5g/L,pH=3.5。     

Cr颗粒含量对Ni-Cr纳米复合镀层组织结构的影响

使用Ni与纳米Cr颗粒共沉积方法制备Ni-Cr纳米复合镀层,研究了镀液中Cr颗粒浓度、搅拌强度和阴极电流密度等工艺参数对镀层中沉积Cr量的影响.结果表明:镀层中纳米Cr颗粒的复合改变了电沉积Ni的生长方向,Ni晶粒由原来沿(200)晶面取向生长,转变为沿(200)、(111)和(220)晶面均匀生长.镀层中Cr复合量越多,Ni晶粒的形核位置越多,Ni晶粒越细化.也探讨了Ni-Cr纳米复合镀的沉积机理.     

机械球磨制备纳米Fe/卡拉胶复合粉末的研究EI北大核心

在常温常压环境下,采用食品添加剂卡拉胶为助磨剂,用机械球磨方法制备纳米Fe/卡拉胶复合粉末。采用正交试验法对高能球磨制备的复合粉末的工艺参数进行了研究,并利用X射线衍射(XRD)和扫描电镜(SEM)等测试分析手段,对球磨后的复合粉末相结构、组织形貌、颗粒大小的变化进行了研究。结果表明:以卡拉胶为助磨剂机械球磨后的纳米复合粉末粒度小、纯度高、稳定性好;随着球料比增加,粉末颗粒尺寸减小;随着球磨时间的增加,粉末颗粒尺寸减小。     

电沉积工艺参数对Ni-TiN-CeO2二元纳米复合镀层中粒子复合量的影响

采用超声-脉冲电沉积法制备了Ni-TiN-CeO2二元纳米复合镀层,研究了工艺参数对镀层中CeO2及TiN粒子复合量的影响,并对镀层的表面形貌及成分进行了测试和分析。结果表明,超声-脉冲电沉积Ni-TiN-CeO2纳米复合镀层的最佳工艺参数为阴极电流密度4A/dm2,TiN粒子添加量15g/L,CeO2粒子添加量40g/L,正向脉冲占空比20%,超声波功率180W。在该工艺条件下,可获得CeO2质量分数为3.3%、TiN质量分数为4.4%的Ni-TiN-CeO2二元纳米复合镀层。同时,TiN与CeO2二元纳米粒子的加入,充分发挥了两种纳米粒子复合的协同效应,优化了粒子与基质金属的共沉积方式,大大改善了镀层质量。     

纳米颗粒大小对Ni-P合金镀层性能的影响及镀层制备工艺参数优化

为了提高农业刀具的使用寿命,在65Mn钢试件基体表面上,采用电沉积技术制备Ni-P-BN(h)纳米复合镀层,研究不同直径大小的BN(h)颗粒对镀层显微组织、硬度及摩擦磨损性能的影响;并通过正交试验,确定制备复合镀层的最优工艺参数。结果表明:随着BN(h)颗粒直径的增大,复合镀层有晶化的趋势;镀液中加入直径100 nm的BN(h)颗粒所制备的镀层表面胞体均匀致密、硬度最大、耐磨损性能最好;镀层形成过程中,纳米颗粒相互碰撞几率增大,导致晶核分布不均,影响表面质量并且减小耐磨损性能;制备Ni-P-BN(h)纳米复合镀层最优工艺参数为电流密度4.308 A/dm~2,BN(h)浓度15.00 g/L,施镀温度60℃,施镀时间3 h,所得硬度和磨损量分别为621.664 HV_(2N),2.665 8×10~(-3)mm~3,相较于65Mn基体硬度提升了1.2倍,磨损量降低86.5%。     

Tribological behaviour of mechanically synthesized titanium-boron carbide nanostructured coating

In this paper, titanium-boron carbide (Ti/B4C) nanocomposite coatings with different B4C nanoparticles contents were fabricated by surface mechanical attrition treatment (SMAT) method by using B4C nanoparticles with average nanoparticle size of 40 nm. The characteristics of the nanopowder and coatings were evaluated by microhardness test, scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Friction and wear performances of nanocomposite coatings and pure titanium substrate were comparatively investigated, with the effect of the boron carbide content on the friction and wear behaviours to be emphasized. The results show the microhardness, friction and wear behaviours of nanocomposite coatings are closely related with boron carbide nanoparticle content. Nanocomposite coating with low B4C content shows somewhat (slight) increased microhardness and wear resistance than pure titanium substrate, while nanocomposite coating with high B4C content has much better (sharp increase) wear resistance than pure titanium substrate. The effect of B4C nanoparticles on microhardness and wear resistance was discussed.     

Electrodeposition and mechanical and corrosion resistance properties of Ni-W/SiC nanocomposite coatings

Ni-W/SiC nanocomposite coatings with various contents of SiC nano-particulates were prepared by electrodeposition in Ni-W plating bath containing SiC particulates. The influences of the SiC nano-particulates concentration, current density and stirring rate of the plating bath on the composition of the nanocomposite coatings were investigated. The surface morphologies of the Ni-W alloy and Ni-W/SiC nanocomposite coating were observed using a scanning electron microscope (SEM). The morphology of Ni-W/SiC nanocomposite coating is smoother than that of Ni-W alloy coating. The microhardness of composite coatings increases with the increasing content of the SiC nano-particulates in the coatings. The corrosion behavior of Ni-W alloy and Ni-W/SiC nanocomposite coatings was evaluated by the anodic polarization curves in 0.5 mol/L NaCl solution at room temperature. It shows that Ni-W/SiC nanocomposite coating has better corrosion resistance than the Ni-W alloy coating.     

Electrodeposition of Ni/WC nano composite in sulfate solution

Metal matrix composite coatings have gained great attention due to their exclusive properties. They have shown the properties of a metallic host material modified by addition of a second phase. In electrodeposition of Ni/WC nano composite, nickel was deposited on the substrates by DC electrodeposition in Watt's based bath containing nickel sulfate, nickel chloride, boric acid and sodium dodecyl sulfate. WC content in the coating was determined by different parameters such as current density, powder content and surfactant amount. Mechanism of electrodeposition was analyzed by cyclic voltammetry and was confirmed by Guglielmi model. Surface morphology was studied by scanning electron microscopy. Hardness, scratch resistance and corrosion resistance of Ni/WC composite coating were also determined.     

超声场中脉冲电沉积Ni-CeO_2纳米复合镀层的耐蚀性

在超声场中用脉冲电沉积法制备了Ni-CeO2纳米复合镀层,考察了镀层中CeO2含量及表面形貌,研究了镀层在10wt%HCl溶液中的耐蚀性,分析了超声作用下脉冲参数对镀层耐蚀性的影响.结果表明:脉冲参数和超声波对镀层中CeO2含量和微观组织均有影响,适宜的脉冲参数可以提高镀层中CeO2含量,细化镀层晶粒,而超声波可促使镀层晶粒进一步细化;Ni-CeO2纳米复合镀层的耐蚀性与镀层中CeO2含量、镀层晶粒大小及组织致密程度有关;在占空比0.2、脉冲频率1000Hz时超声作用下制备的镀层中CeO2含量较高,镀层晶粒细小、组织致密,腐蚀速率最低,表现出优良的耐蚀性.     

Nano /spl alpha/-Fe/epoxy resin composite absorber coatings fabricated by thermal spraying technique

In this paper, the low temperature high velocity air fuel (LTHVAF) spraying technique was applied to prepare the /spl alpha/-Fe/epoxy resin nanocomposite coatings. The composite powders were mixed with different mass fractions, and the microstructure and reflectivity coefficient of coatings were tested. The results show that the microstructure of coatings is dense and low porosity; nano metal particles are dispersed in the coatings. The coatings are closely combined with substrate. In these coatings, the volume fraction calculated with density, component distribution, properties of metal particle, and coating thickness can affect the microwave absorption ability of the coatings. The reflectance coefficient of 70 mass% nano /spl alpha/-Fe/epoxy resin composite coatings is lower than others. In these nanocompsite absorber coatings, the relationship of the reflectivity coefficient and the coating structure were constructed with permittivity, permeability, and thickness. The optimal mass fraction of absorber coatings is about 0.3. It is analyzed with self-bonding strength and reflectivity coefficient. This means that the change of the coating structure affects the performance of the nanocomposite coatings.     

n-Al2O3/Ni复合电刷镀层的接触疲劳行为

为研究纳米颗粒复合电刷镀层的接触疲劳行为,通过在镍盐溶液中加入纳米氧化铝(n-Al2O3)颗粒,采用电刷镀技术制备了含n-Al2O3颗粒的镍基复合镀层(n-Al2O3/Ni),采用接触疲劳试验机评价了镀态和热处理态的n-Al2O3/Ni复合镀层的抗接触疲劳性能,并与纯镍刷镀层进行了性能对比.借助SEM和TEM对复合刷镀层的组织进行了分析,探讨了复合刷镀层的接触疲劳失效过程以及纳米颗粒等对刷镀层疲劳失效过程的影响.研究表明:n-Al2O3/Ni复合镀层在镀态下的接触疲劳寿命超过100万周次,明显高于纯镍镀层;退火后n-Al2O3/Ni复合镀层接触疲劳寿命为45.9万次,为纯镍镀层的1.62倍;复合镀层的接触疲劳失效过程分为裂纹萌生、裂纹扩展和镀层断裂3个阶段;纳米颗粒在复合镀层接触疲劳失效过程中起到阻碍位错滑移的作用,从而抑制塑性变形和裂纹扩展,使复合镀层具有较高的接触疲劳寿命.     

脉冲电流密度对Ni-WC/Co纳米复合镀层摩擦磨损性能的影响

目前,通过脉冲电沉积制备Ni-WC/Co复合镀层的研究报道较少。为了探究Ni-WC/Co纳米复合镀层对材料表面摩擦性能的影响,采用脉冲电沉积制备Ni-WC/Co纳米复合镀层,研究脉冲峰值电流密度对复合镀层晶体结构、晶粒尺寸和硬度的影响;室温下,在MM-W1B立式万能摩擦磨损试验机上测试复合镀层的摩擦磨损性能,分析其磨损机理。结果表明:随着峰值电流密度的增加,复合镀层晶粒尺寸先减小后增大,硬度则是先增大后减小,复合镀层的摩擦系数和磨损量都是先降低后升高;当峰值电流密度为10 A/dm2时,复合镀层的平均晶粒尺寸最小,硬度最高,摩擦系数和磨损量最低,耐磨性能最佳,复合镀层表面主要呈现轻微的划痕,且磨痕较窄,无疲劳磨损。     

WC/Co含量对Ni-WC/Co纳米复合镀层摩擦学性能的影响

为了探究Ni-WC/Co纳米复合镀层对材料表面摩擦学性能的影响,采用脉冲电沉积制备出Ni-WC/Co纳米复合镀层,研究镀液中WC/Co含量对复合镀层晶体结构、晶粒尺寸和硬度的影响;室温下,在MM-W1B立式万能摩擦磨损试验机上测试复合镀层的摩擦学性能,分析其磨损机理。结果表明:随着镀液中加入WC/Co颗粒含量的增加,复合镀层平均晶粒尺寸先减小后增大,硬度则是先增大后减小,镀层的摩擦系数和磨损速率都是先降低后升高;当WC/Co含量为30.0 g/L时,复合镀层的平均晶粒尺寸最小,硬度最高,摩擦系数和磨损速率最低,耐磨性能最佳,复合镀层表面只呈现出轻微划痕,是由磨料磨损造成的,没有犁削和黏着磨损的特征。     

Pulse electrodeposition and corrosion properties of Ni–Si3N4 nanocomposite coatings

The development of modern technology requires metallic materials with better surface properties. In the present investigation; Si₃N₄-reinforced nickel nanocomposite coatings were deposited on a mild steel substrate using pulse current electrodeposition process employing a nickel acetate bath. Surface morphology, composition, microstructure and crystal orientation of Ni and Ni–Si₃N₄ nanocomposite coatings were investigated by scanning electron microscope, energy dispersive X-ray spectroscopy and X-ray diffraction analysis, respectively. The effect of incorporation of Si₃N₄ particles in the Ni nanocomposite coating on the micro hardness, corrosion behaviour has been evaluated. Smooth composite deposits containing well-distributed silicon nitride particles were obtained and the crystal grains on the surface of Ni–Si₃N₄ composite coating are compact. The crystallite structure was face centred cubic (fcc) for electrodeposited nickel and Ni–Si₃N₄ nanocomposite coatings. The micro hardness of the composite coatings (720 HV) was higher than that of pure nickel (310 HV) due to dispersion-strengthening and matrix grain refining and increased with the increase of incorporated Si₃N₄ particle content. The corrosion potential (E _corr) in the case of Ni–Si₃N₄ nanocomposite had shown a negative shift, confirming the cathodic protective nature of the coating.