INFLUENCE OF CERIUM CONTENT ON DAMPING CAPACITIES OF AS-SPRAY DEPOSITED HIGH SILICON ALLOY ZA27

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DAMPING CAPACITY OF HIGH SILICON ALLOY ZA27 PREPARED BY SPRM DEPOSITION

1.IntroductionInrecentyearscontinuousattemptshavebeenmade,particularlyinareasofalloydesignandadoptionofnovelprocesstechniques,todevelophighperformancematerialsasseriouscompetitorstotraditiona1engineeringalloys.Inparticular,muchattentionhasbeengiventoarapidsolidificationtechnique-spraydeposition.Itiswell-knownthatthisprocesshaJsimprovedthemechanicalpropertie8greatlyThosematerialsofferadvantagesinaPplicationswherehighdampingcapacityhighstrengthandhighstiffnessaxea..primaxyconcern.Highdampingal…     

INFLUENCE OF EXTRUSION ON DAMPING CAMCITIES OF AS-SPRAY DEPOSITED HIGH SILICON ALLOY ZA27 MODIFIED BY CERIUM

1.IntroductionThedampingcapacityofamaterialreferst0itsabilitytoc0nvertmechanicalvibrationenergyint0thermalenergy.Theapplication0fhighdampingmaterialsmayeliminatetheneedforspeciaienergyabs01bers0rdamperst0attenuateundesirablen0iseandmechan-icalvibrati0n.However,m0st0fthefrequentlyusedmetalsandaJl0ysusuallyexhibitalowdampingcapacity,whicharelimitedintheirapplicati0nandperf0rmanceindynamicstructures[l].Accordingly,materialresearchershavesoughtt0improvethedampingcapacityofmetalsandall0ysasseri0us…     

稀土对ZA27合金阻尼性能的影响

研究了稀土对ZA27合金阻尼性能的影响规律。结果表明：稀土变质可提高ZA27合金的阻尼性能，经稀土变质后的试样，其内耗是未变质的试样的1．4倍。ZA27合金为发挥其阻尼作用，在频率高于70Hz时，效果明显，且经稀土变质后的试样强迫振动衰减效果比未变质的试样强。     

EFFECT OF ANNEALING ON DAMPING CAPACITIES OF AS-CAST ZA27 ALLOY

1. Introduction Because ZA27 alloy possesses excellent mechanical properties and high damping capacities, it is widely used in industries. ZA27 alloy has good castability and can be easily cast into various castings by permanent mold casting. The solidification of ZA27 alloy in the permanent mold can be considered to be a nonequilibrium process, and thus the supersaturated aluminum-rich ! phase and unstable copper-rich phase may also be found in the solidified ingot. Those nonequilibrium pha…     

等温处理对半固态ZA27组织演变的影响

采用加入微量元素锆对ＺＡ２７合金进行变质处理,并加热到液－固相区不同温度,采用不同时间进行等温处理,以观察所获得的ＺＡ２７合金半固态组织的演变规律。结果表明,经过变质处理后的合金在液－固相区不同温度保温时,具有以下的组织演变规律,树枝晶,碎块状,颗粒状,球状,晶粒长大。     

细化剂对ZA27合金触变组织的影响

采用半固态等温处理法研究了细化剂Zr加入量对ZA27合金在半固态等温热处理中组织的影响。 结果表明,只要达到0．04％Zr时,就能获得触变成形组织,随Zr量的增加,初生相由发达的树枝晶逐渐演变为细化的短轴晶和等轴晶,但Zr含量不宜超过0．2％;在半固态等温处理后发现初生相细化得愈好,所得到的组织粒度愈小,圆整度愈好。     

SiCp／ZA27复合材料在半固态等温热处理中的组织演变

研究了Zr变质处理的SiCp／ZA27复合材料在半固态温度保温过程中的组织演变情况,并与基体合金作了对比。结果表明：经0．6％Zr处理SiCp/ZA27复合材料在460℃保温30－40min可获得良好的半固态成形所需的组织;复合材料的组织演变速率比基体合金的快,且在长时间保温（＞40min）时,其组织的粗化现象不如基体合金明显。     

MICROSTRUCTURE ANALYSIS AND MECHANICAL PROPERTIES OF Zn—Al ALLOY ROD PRODUCED BY HEATED MOLD CONTINUOUS CASTING

The new technology of continuous casting by heated mold was used to produce directional solidification ZA alloy lines to eliminate the inter defects of these lines and increase their mechanical properties. The results are as follows: (1) The microstruc-ture of the ZA alloy lines is the parallel directional dendritic columnar crystal. Every dendritic crystal of eutectic alloy ZA5 was composed of many layer eutectic β and η phases. The micro structure of hypereutectic ZA alloys is primary dendritic crystal and interdendritic eutectic structure. The primary phase of ZA8 and ZA12 is β, among them, but the primary phase of ZA22 and ZA27 is a. (2) Through the test to the as-cast ZA alloy lines made in continuous casting by heated mold, it is found that the tensile strength and hardness increase greatly, but the elongation decreases. With the increase of aluminum amount from ZA 5 to ZA 12, ZA22 and ZA27, the tensile strength increases gradually. ZA27 has the best comprehensive mechanical properties in these     

均匀化处理对ZA35-0.3Zr合金组织及性能的影响

为了探索均匀化处理对ZA35-0.3Zr合金组织和性能的影响规律,通过组织分析、力学性能、电化学性能测试,确定了ZA35-0.3Zr合金均匀化处理的适宜温度和时间。结果表明,ZA35-0.3Zr合金枝晶偏析明显,晶界上Cu富集严重,存在非平衡β相。随着均匀化处理时间增加,ZA35-0.3Zr合金中CuZn5相逐渐消除,β相共析分解程度加大。对合金进行370℃×12h均匀化处理后,晶界处CuZn5相消除,枝晶偏析大大减少,同时非平衡β相基本消除,抗拉强度为306MPa,伸长率为7.35%。在3.5%的NaCl溶液中,开路电位与未均匀化处理合金相比变正,腐蚀电流密度减小了33.1%,耐腐蚀性增强。ZA35-0.3Zr合金适宜的均匀化处理工艺为370℃×12h。     

Effect of Zr on behavior of compressive creep in as cast ZA27 alloy

1　INTRODUCTIONAmongzinc aluminumcastalloy ,ZA2 7alloyex hibitsattractivephysicalandmechanicalpropertiescombinedwith goodfrictionandwearresistance ,makingitabearingalloyreplacementofsomecopperalloys[1,2 ] ,alsothisalloytendstobeusedwidely .Butsomepropertiesofthisalloywhichmustbetakenintoaccountarecomparativelylowresistancetocreepde formation ,poorstrengthatmoderatelyelevatedtem peratures[35] .Additionofsomemodifyingelements ,suchasZr ,Mn ,Li,canindeedimprovetensilestrengthofthealloyatroo…     

Effect of rare earths on phase transformation in as-cast ZA27 alloy dur-ing compressive creep

The effect of the mixed rare earths of Ce on the phase transformation in as cast ZA27 alloy during compressive creep was investigated under 37 MPa and at 160℃ by X-ray diffraction technique and SEM. The results showed that the as cast microstructure of ZA27-RE alloy consisted of a dendritic Al-rich a' surrounded by Zn-rich β' phase, interdendritic ε phase and Zn-rich η phase together with a complex Z phase which was a complex constitute compound, (RE,Cu)Al5Zn16, dispersed in crystal interfaces or branch crystal interfaces and stable during compressive creep test at 160'C. The phase transformations of ZA27-RE alloy, decomposition of β' phase and four transformation, were delayed by the addition of rare earths, also the lamellar structure and the spheroidized structure in ZA27-RE alloy were finer than in ZA27 alloy during compressive creep test at 160℃ at the same creep time, and the compressive creep resistance of ZA27-RE alloy was higher than that of ZA27 alloy.     

微量锆对Zn—22%Al合金阻尼稳定性的影响

采用自然时效、人工时效等热处理工艺研究了微量锆对Ｚｎ２２％Ａｌ合金阻尼性能（内耗）的影响。结果表明，微量锆可提高Ｚｎ２２％Ａｌ合金的阻尼稳定性。运用电子显微镜和Ｘ射线衍射仪对未加锆和加锆的试样进行观察和分析，明确了锆减缓Ｚｎ２２％Ａｌ合金时效后阻尼性能（内耗）降低的原因     

Ce对Zn-Al合金组织性能的影响

研究了Ｃｅ对ＺｎＡｌ合金（ＺＡ２７、ＺＡ４３）的力学性能、淬火时效特性及耐磨性的影响。结果表明,Ｃｅ能明显细化合金的铸态组织,提高其强度和塑性。当ＺＡ２７和ＺＡ４３中含Ｃｅ量分别为０．１０％和０．１５％时,获得最佳的力学性能。提出了Ｃｅ细化ＺｎＡｌ合金的机理,加Ｃｅ后成分过冷效应所引起的枝晶熔断脱落对细化α相起主要作用。     

变质剂对ZA27合金半固态等温热处理组织的影响

研究了变质剂Ti、B－Ti及Zr对ZA27合金铸态组织和半固态等温热处理组织的影响。结果表明：Zr的变质效果最好,下来依次是B－Ti,Ti经半固态等温热处理后都可获得触变成形所需的半固态非枝晶组织、但变质组织越细,越易获得良好的非枝晶组织,变质效果越差,需要热处理的时间越长或温度越高。     

La对ZA27合金组织,机械性能及摩擦磨损特性的影响

研究了Ｌａ对ＺＡ２７合金组织、常温机械性能的影响，并测定了ＺＡ２７（Ｌａ）合金的摩擦磨损特性。结果表明：Ｌａ可以细化合金初生ａ′相，改善共晶相的形貌与分布，提高合金的塑性和韧性指标；ＺＡ２７（Ｌａ）合金的摩擦磨损特性优于ＺＱＳｎ６－６－３     

Zr对ZA35合金电化学腐蚀行为的影响

为了探索Zr对ZA35合金电化学腐蚀性能的作用规律,采用开路电位测定、动电位扫描技术对不同Zr含量的ZA35合金的耐蚀性进行了研究.结果表明,电化学腐蚀条件下,在3.5％NaCl溶液中,与ZA35合金相比,添加0.2％ Zr的ZA35-0.2％Zr合金的开路电位变正,腐蚀电流密度减小59.4％,耐腐蚀性增强.Zr对ZA35合金晶粒的细化和改变电极反应生成有保护性的腐蚀产物是提高ZA35合金耐电化学腐蚀性的主要因素.     

锰元素对锌基硅相复合材料性能的影响

研究了在硅相球化的ZA27、ZA35及ZA45合金中加入不同量的Mn时，对ZA合金硬度及耐磨性的变化规律。结果表明：在ZA27合金中Mn的加入量对其综合性能影响不大；在ZA35合金中锰的加入量为0.5％时。材料的综合性能较好；在ZA45合金中Mn的加入量≤1.0％时，其综合性能比较好。     

STUDY ON THE FRACTURE PROCESS OF AN AS CAST Zn 27WT% Al ALLOY

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Corrosion behaviour of thixoformed and heat-treated ZA27 alloys in NaCl solution

The influence of corrosion on the microstructure of thixoformed and heat-treated ZA27 alloys was investigated. The microstructure of ZA27 alloy was affected by heat treatment. The process of electrochemical corrosion occurs in both ZA27 alloys through the area of η phase. According to the results of immersion test and electrochemical measurements, the corrosion rate of the thixoformed ZA27 alloy is at least 50% lower than that of the thixoformed and thermally processed alloy. This indicates the unfavourable influence of applied heat treatment (T4 regime) on the corrosion resistance of the thixoformed ZA27 alloy.