| SYNTHESIS of(η~5-C_9H_7)Ln(η~8-C_8H_8)·2THF AND CRYSTAL STRUCTURE OF(η~5-C_9H_7)Pr(η~8-C_8H_8)·2THF |
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| 作者姓名： | Ke WEN Zhong Sheng JIN Wen Qi CHEN |
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| 作者单位： | Changchun Institute of Applied Chemistry Academia Sinica Changchun 130022 |
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| 摘 要： | The reaction of LnCl_3 with K _9H_7(C_9H_7=indenyl)andK_2C_8H_8(C_8H_8=cyclooctatetraene)in tetrahydrofuran(THF)give thecorresponding complexes(η~5-C_9H_7)Ln(η~8-C_8H_8)·2THF.The synthesis of(η~5-C_9H_7)Ln(η~8-C_8H_8)·2THF(Ln=Pr,Nd)and crystal structure of(η~5-C_9H_7)Pr(η~8-C_8H_8)·2THF are described.
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SYNTHESIS of(η5-C9H7)Ln(η8-C8H8)·2THF AND CRYSTAL STRUCTURE OF(η5-C9H7)Pr(η8-C8H8)·2THF |
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| Ke WEN,Zhong Sheng JIN,Wen Qi CHEN.SYNTHESIS of(η5-C9H7)Ln(η8-C8H8)·2THF AND CRYSTAL STRUCTURE OF(η5-C9H7)Pr(η8-C8H8)·2THF[J].Chinese Chemical Letters,1991,2(9):693-696. |
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| Authors: | Ke WEN Zhong Sheng JIN Wen Qi CHEN |
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| Affiliation: | Changchun Institute of Applied Chemistry Academia Sinica Changchun 130022 |
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| Abstract: | The reaction of LnCl3 with KC9H7(C9H7=indenyl) and K2C8H8 (C8H8=cyclooctatetraene) in tetrahydrofuran (THF) give the corresponding complexes(η5-C9H7) Ln(η8-C8H8)·2THF.The synthesis of(η5-C9H7) Ln(η8-C8H8)·2THF（Ln=Pr, Nd）and crystal structure of (η5-C9H7) Pr(η8-C8H8)·2THF are described. |
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