Reaction of halogens with copper(II) bis(diethyldithiocarbamate) |
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| Authors: | G M Larin G A Zvereva V V Minin Yu V Rakitin |
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| Affiliation: | (1) N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow |
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| Abstract: | Conclusions It was established by EPR spectroscopy that the reaction of halogens with Cu(dtc)2 has redox character in polar and nonpolar solvents. However, the ligand is oxidized in a polar solvent, and new complexes of copper(II), the coordination sphere of which is formed via different combinations of solvent molecules, halide ions, and dtc–, are formed as a result of intraspheral transformations.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2484–2488, November, 1988. |
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