| 生物质基呋喃衍生物选择氢解制备戊二醇和己二醇研究进展 |
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| 引用本文： | 高芳芳,陈静,黄志威,夏春谷.生物质基呋喃衍生物选择氢解制备戊二醇和己二醇研究进展[J].分子催化,2018,32(3):276-293. |
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| 作者姓名： | 高芳芳 陈静 黄志威 夏春谷 |
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| 作者单位： | 中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室;中国科学院大学 |
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| 基金项目： | 国家自然科学基金（21473224）；中国科学院青年创新促进会（2016371）；苏州科技发展计划（SYG201626） |
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| 摘 要： | 生物质基呋喃衍生物来源广泛,利用生物糠醛、5-羟甲基糠醛及他们的衍生物选择氢解制备戊二醇、己二醇具有重要的研究价值和意义.根据原料和催化剂体系不同对生物质基呋喃衍生物选择氢解制备高碳二元醇的代表性工作进行了归纳总结,对影响催化剂活性和选择性的关键因素如活性金属、载体、助剂及反应溶剂等进行了分析讨论,对反应可能涉及的路径和机理进行了阐述,并对未来的研究方向和发展趋势作了展望.
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| 关 键 词： | 生物质 呋喃衍生物 选择氢解 戊二醇 己二醇 |
| 收稿时间： | 2017/12/20 0:00:00 |
| 修稿时间： | 2018/3/10 0:00:00 |
Recent Advances in the Selective Hydrogenolysis of Biomass-based Furan Derivatives to Pentanediols and Hexanediol |
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| GAO Fang-fang,CHEN Jing,HUANG Zhi-wei and XIA Chun-gu.Recent Advances in the Selective Hydrogenolysis of Biomass-based Furan Derivatives to Pentanediols and Hexanediol[J].Journal of Molecular Catalysis (China),2018,32(3):276-293. |
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| Authors: | GAO Fang-fang CHEN Jing HUANG Zhi-wei and XIA Chun-gu |
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| Affiliation: | State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics(LICP), Chinese Academy of Sciences, Lanzhou 730000, Gansu, China;University of Chinese Academy of Sciences, Beijing 100049, China,State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics(LICP), Chinese Academy of Sciences, Lanzhou 730000, Gansu, China,State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics(LICP), Chinese Academy of Sciences, Lanzhou 730000, Gansu, China and State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics(LICP), Chinese Academy of Sciences, Lanzhou 730000, Gansu, China |
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| Abstract: | The selective hydrogenolysis of abundant biomass-based furan derivatives in nature, including furfural (FA), 5-hydroxymethylfurfural (5-HMF) and their derivatives, into pentanediols and hexanediol is significant for academic research and industrial application. The representative works on the selective hydrogenolysis of biomass-based furan derivatives into high-carbon glycols were summarized according to the different raw materials and catalyst systems. The important factors for activity and selectivity consisting of active metal, carrier, additives and solvents were remarked. The possible reaction pathways and mechanism were demonstrated, and prospect for the research directions as well as future development was proposed. |
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| Keywords: | biomass furan derivatives selective hydrogenolysis pentanediols hexanediol |
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