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高分子发光二极管载流子注入过程研究
引用本文:黄文波,彭俊彪.高分子发光二极管载流子注入过程研究[J].物理学报,2007,56(5):2974-2978.
作者姓名:黄文波  彭俊彪
作者单位:(1)华南理工大学高分子光电材料及器件研究所,广州 510640; (2)华南理工大学高分子光电材料及器件研究所,广州 510640;华南理工大学特种功能材料及其制备新技术教育部重点实验室,广州 510640
基金项目:国家自然科学基金;教育部科学技术研究重点项目;国家重点基础研究发展计划(973计划)
摘    要:采用交流阻抗谱,电容-电压,电容-频率等实验方法,研究了共轭高分子MEH-PPV(poly[2-methoxy,5-(2-ethylhexoxy)-1,4-phenylene vinylene])发光二极管的载流子注入过程.对于结构为ITO/PEDOT/MEH-PPV/Ba/Al的发光器件,实验结果表明,电极界面是欧姆接触的,载流子的注入是非平衡的,器件薄膜中存在陷阱容易俘获注入电荷,形成空间电荷区,陷阱密度约为3.75×1016cm-3. 关键词: 高分子发光二极管 交流阻抗谱 cole-cole图 载流子注入

关 键 词:高分子发光二极管  交流阻抗谱  cole-cole图  载流子注入
文章编号:1000-3290/2007/56(05)/2974-05
收稿时间:2006-10-09
修稿时间:10 9 2006 12:00AM

Carrier injection process of polymer light-emitting diodes
Huang Wen-Bo,Peng Jun-Biao.Carrier injection process of polymer light-emitting diodes[J].Acta Physica Sinica,2007,56(5):2974-2978.
Authors:Huang Wen-Bo  Peng Jun-Biao
Affiliation:1.Institute of Polymer Optoelectronic Material and Devices, South China University of Technology, Guangzhou 510640, China; 2. Key laboratory of Specially Functional Materials and Advanced Manufacturing Technology, South China University of Technology, Guangzhou 510640, China
Abstract:The carrier injection process of polymer light-emitting diodes (PLEDs) with MEH-PPV(poly[2-methoxy,5-(2-ethylhexoxy)-1,4-phenylene vinylene]) as the light-emitting layer, was investigated using impedance spectroscopy, capacitance-voltage (C-V) and capacitance-frequency (C-F) techniques. The diodes have the configuration of ITO/PEDOT/MEH-PPV/Ba/Al. The experiments showed that there is an ohmic contact between electrodes and MEH-PPV, and holes and electrons injected from the cathodes are unbalanced. Charged traps in the MEH-PPV result in space-charge under positive bias, and the trap concentration was estimated at about 3.75×1016cm-3.
Keywords:polymer light-emitting diodes (PLEDs)  impedance spectroscopy  cole-cole figure  carrier injection
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