Progress in improving thermodynamics and kinetics of new hydrogen storage materials |
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Authors: | Li-fang Song Chun-hong Jiang Shu-sheng Liu Cheng-li Jiao Xiao-liang Si Shuang Wang Fen Li Jian Zhang Li-xian Sun Fen Xu Feng-lei Huang |
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Affiliation: | 1. Materials and Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China 2. Graduate School of the Chinese Academy of Sciences, Beijing, 100049, China 3. Faculty of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, 116029, China 4. Beijing Institute of Technology, State Key Laboratory of Explosion Science & Technology, Beijing, 100081, China
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Abstract: | Hydrogen storage material has been much developed recently because of its potential for proton exchange membrane (PEM) fuel cell applications. A successful solid-state reversible storage material should meet the requirements of high storage capacity, suitable thermodynamic properties, and fast adsorption and desorption kinetics. Complex hydrides, including boron hydride and alanate, ammonia borane, metal organic frameworks (MOFs), covalent organic frameworks (COFs) and zeolitic imidazolate frameworks (ZIFs), are remarkable hydrogen storage materials because of their advantages of high energy density and safety. This feature article focuses mainly on the thermodynamics and kinetics of these hydrogen storage materials in the past few years. |
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Keywords: | ammonia borane hydrogen storage materials hydrides kinetics metal organic frameworks thermodynamics |
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