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Hydrogen Production from Catalytic Steam Reforming of Bio-Oils: A Critical Review
Authors:Zhongkai Zhao  Yohanes A Situmorang  Ping An  Nichaboon Chaihad  Jing Wang  Xiaogang Hao  Guangwen Xu  Abuliti Abudula  Guoqing Guan
Affiliation:1. Hirosaki University, Graduate School of Science and Technology, 1-Bunkyocho, 036-8560 Hirosaki, Japan

Hirosaki University, Energy Conversion Engineering Laboratory, Institute of Regional Innovation, 2-1-3 Matsubara, 030-0813 Aomori, Japan;2. Hirosaki University, Graduate School of Science and Technology, 1-Bunkyocho, 036-8560 Hirosaki, Japan

Hirosaki University, Energy Conversion Engineering Laboratory, Institute of Regional Innovation, 2-1-3 Matsubara, 030-0813 Aomori, Japan

Shenyang University of Chemical Technology (SYUCT), Institute of Industrial Chemistry and Energy Technology, 110142 Shenyang, China;3. Taiyuan University of Technology, Department of Chemical Engineering, 030024 Taiyuan, China;4. Shenyang University of Chemical Technology (SYUCT), Institute of Industrial Chemistry and Energy Technology, 110142 Shenyang, China;5. Hirosaki University, Graduate School of Science and Technology, 1-Bunkyocho, 036-8560 Hirosaki, Japan

Abstract:In the future, hydrogen will be an important energy carrier and industrial raw material. Catalytic steam reforming of bio-oils is a promising and economically viable technology for hydrogen production. However, during the reforming process, the catalysts are rapidly deactivated due to coke formation and sintering. Thus, maintaining the activity and stability of catalysts is the key issue in this process. Optimized operation conditions could extend the catalyst lifetime by affecting the coke morphology or promoting coke gasification. This article summarizes the recent developments in the field of catalytic steam reforming of bio-oils, focusing on the operation conditions, the properties of the catalysts, and the effects of the catalyst supports. The expected insights into the catalytic steam reforming of bio-oils will provide further guidance for hydrogen production from bio-oils.
Keywords:Bio-oil  Catalyst activity  Catalyst stability  Hydrogen production  Steam reforming
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