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老化油乳化液在高频/高压脉冲交流电场下的破乳脱水实验研究
引用本文:李玮健,陈家庆,张明,尚超,孟浩,王春升.老化油乳化液在高频/高压脉冲交流电场下的破乳脱水实验研究[J].石油炼制与化工,2018,49(11):45-49.
作者姓名:李玮健  陈家庆  张明  尚超  孟浩  王春升
作者单位:1. 北京石油化工学院机械工程学院 2.深水油气管线关键技术与装备北京市重点实验室 3. 中海石油(中国)有限公司北京研究中心
基金项目:中海石油(中国)有限公司北京研究中心科研项目;“十三五”国家科技重大专项子课题“高效原油脱水处理技术研究”
摘    要:基于中海油深圳分公司流花11-1油田老化油配制的W/O型乳化液,采用静态静电聚结破乳实验,并辅助以离心机强化脱水,针对高频/高压脉冲AC电场下电场强度、频率、电压波形、含水率等因素对老化油乳化液电场破乳脱水效果的影响进行研究。结果表明:老化油乳化液的反相点位于40%~50%之间,W/O型老化油乳化液破乳脱水的最优电场参数为电压6 kV、频率2 kHz、波形为矩形波;以含水率40%较稳定老化油乳化液为例,其脱水率可达74.074%;改变乳化液含水率,最优电场破乳参数不变。上述研究结果为流花油田老化油处理流程的改造提供设计参考,并可为生产运行参数的改进提供依据。

关 键 词:老化油  高频/高压脉冲交流电场  W/O型乳化液  电场破乳  离心脱水  
收稿时间:2018-03-05
修稿时间:2018-06-12

DEMULSIFICATION AND DEHYDRATION OF AGING OIL EMULSION UNDER HIGH FREQUENCY AND HIGH VOLTAGE PULSED ELECTRIC FIELD
Abstract:In this paper, based on the prepared aging oil W/O emulsion from Liuhua 11-1 oilfield, the influence of electric field intensity, frequency, waveform and moisture content on electric demulsification and dehydration under high frequency and high voltage electric field was investigated. A static electrostatic coalescing device with a centrifuge assisted to enhance the dehydration rate. The experiment results indicated that the phase inversion point of aging oil emulsion is between 40% and 50%, the optimal electric field parameter for W/O emulsion demulsification and dehydration is field strength (voltage) of 6 kV, frequency 2 kHz and AC square wave. The dehydration efficiency of stable W/O emulsion is 74.074% when the moisture content reaches 40%. These optimal electric field parameters do not vary with moisture content. This study can provide design references for the modification of aging oil treatment process in Liuhua oil field and a foundation for the improvement of production.
Keywords:aging oil  high voltage and high frequency pulsed AC electric field  W/O emulsions  electric demulsification  centrifugal dehydration  
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