| Keggin结构钼磷酸/聚碳酸酯复合物的制备及光致变色性质研究 |
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| 引用本文： | 靳素荣,陈永熙,田多玉,徐钿,明三军,周淑琼.Keggin结构钼磷酸/聚碳酸酯复合物的制备及光致变色性质研究[J].无机化学学报,2002,18(4):383-385. |
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| 作者姓名： | 靳素荣 陈永熙 田多玉 徐钿 明三军 周淑琼 |
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| 作者单位： | 武汉理工大学材料学院,武汉,430070 |
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| 基金项目： | 湖北省重点科技攻关项目(No.992P0321)。 |
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| 摘 要： | 近年来，多酸－有机复合材料的研究，受到了人们的广泛关注犤１犦。杂多化合物是一类含有氧桥的多核配合物，作为高质子酸，可以提供质子与有机给体形成多酸－有机复合物，这类质子化状态的复合物具有良好的光敏性，这种特性在光化学、氧化还原催化等方面显示出重要用途。聚碳酸酯是一种综合性能优良的光学材料，研究以其为基材的杂多酸－有机复合材料的基本性能，对聚碳酸酯的改性、增进对这类复合材料的理论研究以及拓宽聚碳酸酯的应用都有重要的实际意义，迄今为止，尚未见这方面的报道。本文以Keggin结构钼磷酸（简写为PMo１２）和聚…
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| 关 键 词： | 钼磷酸 聚碳酸酯 光致变色 |
| 修稿时间： | 2001年6月19日 |
Preparation,Photochromic Properties of Keggin Type Molybdophosphoric Acid Based on Polycarbonate |
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| JIN Su-Rong,CHEN Yong-Xi,TIAN Duo-Yu,XU Tian,MING San-Jun and ZHOU Shu-Qiong.Preparation,Photochromic Properties of Keggin Type Molybdophosphoric Acid Based on Polycarbonate[J].Chinese Journal of Inorganic Chemistry,2002,18(4):383-385. |
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| Authors: | JIN Su-Rong CHEN Yong-Xi TIAN Duo-Yu XU Tian MING San-Jun and ZHOU Shu-Qiong |
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| Affiliation: | School of Material Science and Engineering, Wuhan University of Technology, Wuhan 430070,School of Material Science and Engineering, Wuhan University of Technology, Wuhan 430070,School of Material Science and Engineering, Wuhan University of Technology, Wuhan 430070,School of Material Science and Engineering, Wuhan University of Technology, Wuhan 430070,School of Material Science and Engineering, Wuhan University of Technology, Wuhan 430070 and School of Material Science and Engineering, Wuhan University of Technology, Wuhan 430070 |
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| Abstract: | A new photochromic complex of Keggin type molybdophosphoric acid/polycarbonate has been synthe-sized.Their properties were investigated by IR spectrum, UV spectrum and 31P NMR. The results of IR spectra and UV spectra indicate that there is interaction between the H3PMo12O40 and polycarbonate.The complex has photo-sensitivity under irradiation of sunlight to result from the interation between the C=O of PC and the H of the molybdophsphoric acid. |
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| Keywords: | molybdophoric acid polycarbonate photochromic |
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