Mechanism of carrier generation and recombination in conjugated polymers |
| |
Affiliation: | 1. Power Electronics, Machines and Control Group, University of Nottingham, NG7 2RD, UK;2. Dipartimento di Ingegneria e Architettura, University of Parma, Parma, Italy |
| |
Abstract: | Transient excited-state absorption measurements in the spectral region spanning the infrared active vibrational active (IRAV) modes in prototypical luminescent polymers, poly(phenylene vinylene) (PPV), and poly2-methoxy-5-(2-ethyl-hexyloxy)-(phenylene vinylene)] (MEH-PPV), reveal charge carrier generation within 100 fs after photoexcitation. The photocarrier quantum efficiency in MEH-PPV is φ0≈0.1 in zero applied electric field. There is no correlation between the temporal behavior of the photoinduced IRAV signals and the exciton lifetime. Thus, carriers are photoexcited directly and not generated via a secondary process from exciton annihilation. Our data indicate that the carrier recombination rate is sensitive to the strength of the interchain interaction. |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |
|