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PVP对球形铝粉进行表面包覆改性的研究
引用本文:胡楠,钟景明,孙本双,何力军,王立惠. PVP对球形铝粉进行表面包覆改性的研究[J]. 中国粉体技术, 2011, 17(5). DOI: 10.3969/j.issn.1008-5548.2011.05.002
作者姓名:胡楠  钟景明  孙本双  何力军  王立惠
作者单位:1. 宁夏大学物理电气信息学院,宁夏银川750021;西北稀有金属材料研究院,宁夏石嘴山753000
2. 西北稀有金属材料研究院,宁夏石嘴山,753000
3. 宁夏大学物理电气信息学院,宁夏银川,750021
摘    要:为防止球形铝粉在空气中腐蚀变质,采用溶液聚合法,通过硅烷偶联剂KH-550对超细铝粉进行预处理,在引发剂偶氮二异丁晴的作用下,用聚乙烯吡咯烷酮(PVP)对球形铝粉进行表面改性,形成了PVP-Al复合粒子。利用扫描电镜、能谱以及红外光谱对改性前后的铝粉进行表征分析;利用光电子能谱对复合粒子的形成原理进行分析。结果表明:复合粒子为具有核-壳结构的球形粒子,致密的PVP壳层包覆铝粒子;复合粒子的沉降率及耐腐蚀性优于原料铝粉。

关 键 词:球形铝粉  包覆  复合粒子

Study on Modification of Superfine Al Particles Coated with PVP
Hu Nan,Zhong Jingming,Sun Benshuang,He Lijun,Wang Lihui. Study on Modification of Superfine Al Particles Coated with PVP[J]. China Powder Science and Technology, 2011, 17(5). DOI: 10.3969/j.issn.1008-5548.2011.05.002
Authors:Hu Nan  Zhong Jingming  Sun Benshuang  He Lijun  Wang Lihui
Abstract:In order to improve the anti-corrosionof superfine aluminum powders in water,the superfine aluminum particles coated with a polyer membrane were investigated through copolymerazation,which used PVP as modifier,ABIN as initiator.The PVP-Al particles were analyzed by scanning electron microscope(SEM),electron dispersive spectrum(EDS) and infrared spectrum(IR).The experimental principle was analyzed by XPS.It was shown that the PVP-Al composite particles were spherical with core-shell structure.A PVP-Al composite particle was composed of dense PVP shell and Al core.The anti-resistance and hydrolysis rate of PVP-Al particles were improved insignificantly by comparing with the raw Al powders.
Keywords:superfine aluminum powders  coating  composite particles
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