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Fischer-Tropsch合成钴基催化剂研究进展
引用本文:纪玉国,赵震,余长春,段爱军,姜桂元. Fischer-Tropsch合成钴基催化剂研究进展[J]. 化工进展, 2007, 26(7): 927-933
作者姓名:纪玉国  赵震  余长春  段爱军  姜桂元
作者单位:中国石油大学(北京)重质油国家重点实验室,北京,102249;中国石油大学(北京)CNPC催化重点实验室,北京,102249
基金项目:国家重点基础研究发展计划(973计划)
摘    要:综述了近年来钴基催化剂在费托合成反应中的研究进展.重点评述了钴源、负载量、载体、助剂、制备方法、焙烧和还原条件等因素在负载型钴基催化剂制备过程中对催化剂活性、选择性控制等方面的影响,概述了钴基催化剂在费托合成反应中的催化机理,并对今后催化剂的研究提出了一点建议.

关 键 词:Fischer-Tropsch合成  Co  助剂  制备
文章编号:1000-6613(2007)07-0927-07
收稿时间:2007-02-08
修稿时间:2007-02-082007-05-11

Progress of cobalt-based catalysts in Fischer-Tropsch synthesis
JI Yuguo,ZHAO Zhen,YU Changchun,DUAN Aijun,JIANG Guiyuan. Progress of cobalt-based catalysts in Fischer-Tropsch synthesis[J]. Chemical Industry and Engineering Progress, 2007, 26(7): 927-933
Authors:JI Yuguo  ZHAO Zhen  YU Changchun  DUAN Aijun  JIANG Guiyuan
Affiliation:1. State Key Laboratory of Heavy oil Processing, China University of Petroleum, Beijing 102249, China; 2. CNPC Key Laboratory of Catalysis, China University of Petroleum, Beijing 102249, China
Abstract:The recent development of cobalt-based catalysts in the Fischer-Tropsch synthesis is reviewed. Particular attention is paid to the influence of supports, promoters, preparation methods, cobalt precursors, calcination and reduction conditions on the catalytic activity and selectivity control in the preparation of supported cobalt catalysts. In addition, the catalysis mechanism for the F-T synthesis over cobalt-based catalysts is also discussed. Some suggestions to study the catalysts in the future are also given.
Keywords:Fischer-Tropsch synthesis   cobalt   promoters, catalyst preparation
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