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Synthesis,crystal structure and biological activity of the nickel(II) complex of 2,6-diacetylpyridinedihydrazone
Authors:A. Dilek Azaz  Selma Celen  Hilmi Namli  Onur Turhan  Raif Kurtaran  Canan Kazak  N. Burcu Arslan
Affiliation:(1) Department of Biology and Chemistry, Balikesir University Art & Science Faculty, Cagis, 10145, Balikesir, Turkey;(2) Department of Physics, Faculty of Arts and Sciences, Ondokuz Mayis University, TR-55139 Samsun, Turkey
Abstract:A complex of NiII with 2,6-diacetylpyridinedihydrazone (L) towards nickel(II) has been prepared and characterized by means of elemental analyses, IR, electronic spectra and single crystal X-ray analyses. [NiL2](NO3) was crystallized in the tetragonal space group P-4 21 c. The complex exhibits the expected coordination sphere with six nitrogen atoms coordinated to the central NiII with a deformation from pseudo-octahedral geometry. Antimicrobial activities of the ligand and its complex were investigated.
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