POLAROGRAPHIC CHARACTERIZATION OF AROMATIC STRUCTURES IN COAL LIQUID PRODUCTS

Reducible aromatic species in coal liquid products from five major processes (Synthoil, FMC COED, HRI H-Coal, PAMCO SRC, and Catalytic Inc. SRC) together with solvent elution chromatography fractions of a selected asphaltene has been evaluated. The half-wave potentials measurments are found to be consistant with other methods. The total polarographic reduction of measurement per average molecule for Synthoil solvent fractions, as measured by diffusion constant (i_d/C), increases in the following manner: gas oil → resin → asphaltene → carbene → carboid. The same trend was observed when color indices (I) and refractive indices (n₂₅) were individually studied.