| 水作溶剂合成季戊四醇螺环磷酸2-氯苯酚酯 |
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| 引用本文： | 侯旭锋,司红岩,白春梅.水作溶剂合成季戊四醇螺环磷酸2-氯苯酚酯[J].广东化工,2009,36(11):17-18. |
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| 作者姓名： | 侯旭锋 司红岩 白春梅 |
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| 作者单位： | 许昌学院,化学化工学院,河南,许昌,461000 |
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| 基金项目： | 许昌学院校内科研基金青年项目 |
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| 摘 要： | 以季戊四醇、三氯氧磷为原料，探讨了微波作用下季戊四醇双磷酸酯二磷酰氯的制备，用水作溶剂在碱性条件下合成了季戊四醇螺环磷酸2-氯苯酚酯，并确定了适宜的反应条件：温度6-7℃，时间4.5h,产率达56.3%。
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| 关 键 词： | 季戊四醇螺环磷酸2-氯苯酚酯 季戊四醇双磷酸酯二磷酰氯 2-氯苯酚 绿色合成 |
Synthesis of Pentaerythritol Spiro Phosphate 2-chlorophenol Ester with Water as Sovent |
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| Hou Xufeng,Si Hongyan,Bai Chunmei.Synthesis of Pentaerythritol Spiro Phosphate 2-chlorophenol Ester with Water as Sovent[J].Guangdong Chemical Industry,2009,36(11):17-18. |
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| Authors: | Hou Xufeng Si Hongyan Bai Chunmei |
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| Affiliation: | (Department of Chemistry, Xuchang University, Xuchang 461000, China) |
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| Abstract: | An important intermediate--pentaerythritol two double-phosphate phosphorus chloride was prepared from pentaerythritol and phosphorus oxychlofide. With water as solvent, a new type of flame retardant pentaerythritol spiro phosphate 2-chlorophenol ester was synthesized from the intermediate and 2-chlophenol under alkaline condition. The experiment result showed that the temperature was 6-7℃, reaction time was 4.5 h and the yield was 56.3 %. |
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| Keywords: | pentaerythritol phosphate 2-chlorophenol ester pentaerythritol two double-phosph-ate phosphorus chloride 2 - chlorophenol green synthes |
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