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环氧大豆油丙烯酸酯光固化保护材料的合成
引用本文:王欣,刘丹丹,俞勇杰,于洁,郭文勇. 环氧大豆油丙烯酸酯光固化保护材料的合成[J]. 化学与生物工程, 2014, 0(7): 41-43
作者姓名:王欣  刘丹丹  俞勇杰  于洁  郭文勇
作者单位:江汉大学柔性显示材料与技术湖北省协同创新中心,湖北武汉430074
摘    要:以环氧大豆油和丙烯酸为原料合成环氧大豆油丙烯酸酯(ESOA),对催化剂种类和反应温度进行探讨。以四丁基溴化铵为催化剂、100℃时合成的ESOA预聚体为主体树脂、三羟甲基丙烷三丙烯酸酯(TMPTA)为活性稀释剂、184为光引发剂进行涂膜紫外光固化。结果表明,制得的紫外光固化保护膜材料附着力为1级,硬度为5H,收缩率小且具有良好的柔韧性及耐磨性。

关 键 词:环氧大豆油  环氧大豆油丙烯酸酯  合成条件  UV光固化

Synthesis of Epoxidized Soybean Oil Acrylate Light Curing Protection Materials
WANG Xin,LIU Dan-dan,YU Yong-j ie,YU Jie,GUO Wen-yong. Synthesis of Epoxidized Soybean Oil Acrylate Light Curing Protection Materials[J]. Chemistry & Bioengineering, 2014, 0(7): 41-43
Authors:WANG Xin  LIU Dan-dan  YU Yong-j ie  YU Jie  GUO Wen-yong
Affiliation:(Flexible Display Material and Technology Co-Innovation Center of Hubei, Jianghan University, Wuhan 430074, China)
Abstract:Epoxidized soybean oil acrylate(ESOA)was synthesized from epoxidized soybean oil and acrylic acid.The catalyst type and reaction time were optimized.Then the ESOA film was prepared with the pre-poly-mer synthesized at 100 ℃ with catalysis of tetrabutylammonium bromide as matrix,TMPTA as reactive dilu-ents,184 as light initiator.The results showed that,the film adhesion materials had excellent performance, with level 1 adhesive force,5 H hardness,little shrinkage and good toughness and abrasive resistance.
Keywords:epoxidized soybean oil  epoxidized soybean oil acrylate  synthetic condition  UV light curing
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