| Studies on synthesis and fluorescent property of rare earth complexes RE（ABMF）2AA and copolymers RE（ABMF）2AA-co-MMA |
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| 引用本文： | 索全伶,吕芳,时建伟,洪海龙,罗吉平. Studies on synthesis and fluorescent property of rare earth complexes RE（ABMF）2AA and copolymers RE（ABMF）2AA-co-MMA[J]. 中国稀土学报(英文版), 2009, 27(1): 28-32. DOI: 10.1016/S1002-0721(08)60184-2 |
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| 作者姓名： | 索全伶 吕芳 时建伟 洪海龙 罗吉平 |
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| 作者单位： | Chemical Engineering College, Inner Mongolia University of Technology, Hohhot 010051, China |
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| 基金项目： | Project supported by the Leaders Project of Inner Mongolia in their chosen field of learning （20041001）, Chun-Hui Cooperated Project for the Chinese Ministry of Education （Z2005-2-01001） |
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| 摘 要： |
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| 关 键 词： | 甲基丙烯酸甲酯 稀土配合物 荧光性能 共聚物 可再生能源 合成 玻璃化转变温度 稀土离子 |
| 收稿时间： | 2007-11-23 |
Studies on synthesis and fluorescent property of rare earth complexes RE(ABMF)2AA and copolymers RE(ABMF)2AA-co-MMA |
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| SUO Quanling,LU Fang,SHI Jianwei,HONG Hailong,LUO Jiping. Studies on synthesis and fluorescent property of rare earth complexes RE(ABMF)2AA and copolymers RE(ABMF)2AA-co-MMA[J]. Journal of Rare Earths, 2009, 27(1): 28-32. DOI: 10.1016/S1002-0721(08)60184-2 |
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| Authors: | SUO Quanling LU Fang SHI Jianwei HONG Hailong LUO Jiping |
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| Affiliation: | ( Chemical Engineering College, Inner Mongolia University of Technology, Hohhot 010051, China) |
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| Abstract: | Four new complexes RE(ABMF)2AA (RE=Sm, Eu, Tb, Dy) were synthesized by the reaction of RECl3·6H2O with acrylic acid (HAA) and 1-(2-furyl)-3-phenyl-1,3-propanedione (ABMF). The copolymerization of the rare earth complexes with methyl methacrylate was studied by using 2,2-azobis-isobutyronitrile as an initiator. The composition and structure of the four complexes were characterized by elemental analysis, UV-vis and FTIR. The glass transition temperature and molecular weight of the copolymers were determined. Photoluminescent measurement showed that ligand ABMF could efficiently transfer the energy to Sm3+ and Eu3+ ions in the complexes and sensitize the luminescence of the rare earth ions, but could not sensitize Tb3+ and Dy3+ ions. As a result, both Sm3+ and Eu3+ complexes emitted the characteristic fluorescence of Sm3+ and Eu3+ ions due to the f-f transitions. The four copolymers could emit strong fluorescence of the rare earth ions. |
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| Keywords: | ternary rare earth complex synthesis copolymerization fluorescence property |
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