| 取代1,1'-联-2-萘酚在铜胺络合物催化作用下的氧化反应 |
| |
| 引用本文： | 王秀珍,陈泳,汪波,庞冀燕,许遵乐.取代1,1'-联-2-萘酚在铜胺络合物催化作用下的氧化反应[J].有机化学,2006,26(4). |
| |
| 作者姓名： | 王秀珍 陈泳 汪波 庞冀燕 许遵乐 |
| |
| 作者单位： | 中山大学化学与化学工程学院,广州,510275 |
| |
| 基金项目： | 广东省自然科学基金(No.011179)资助项目 |
| |
| 摘 要： | 用CuCl2?2H2O与小分子的有机胺形成络合物,模拟氧化还原酶对多米诺式反应(Dominoreaction)进行催化反应,在氧气存在条件下,取代1,1'-联-2-萘酚化合物被氧化为二苯并呫吨类化合物,产物的结构经核磁共振、红外光谱及质谱进行确证.
|
| 关 键 词： | 铜胺络合物 取代联萘酚 二苯并呫吨 多米诺式反应 合成 |
Catalytic Oxidation Reaction of Substituted 1,1'-Bi-2-naphthols with Copper-Amine Complex |
| |
| WANG,Xiu-Zhen,CHEN,Yong,WANG,Bo,PANG,Ji-Yan,XU,Zun-Le.Catalytic Oxidation Reaction of Substituted 1,1'-Bi-2-naphthols with Copper-Amine Complex[J].Chinese Journal of Organic Chemistry,2006,26(4). |
| |
| Authors: | WANG Xiu-Zhen CHEN Yong WANG Bo PANG Ji-Yan XU Zun-Le |
| |
| Affiliation: | WANG,Xiu-Zhen CHEN,Yong WANG,Bo PANG,Ji-Yan XU,Zun-Le* |
| |
| Abstract: | The complex of CuCl22H2O with small molecular amine as a catalyst for Domino reaction, which was a mimic to oxidoreductase, was reported. Substituted 1,1'-bi-2-naphthols were oxidized into dibenzoxanthenoids in the presence of O2. The structures of these compounds were characterized with 1H NMR, IR and FAB-MS spectra. |
| |
| Keywords: | copper-amine complex substituted 1 1'-bi-2-naphthol dibenzoxanthenoid Domino reaction synthesis |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
