A novel zinc tetraphenylporphyrinate substituted in the axial position with one E-stilbazole: Synthesis,structure, and nonlinear optics |
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| Affiliation: | 1. Department of Chemistry, Inorganic Chemistry Section, Jadavpur University, Kolkata 700032, India;2. Department of Physics, Jadavpur University, Kolkata 700032, India;1. Engineering Research Center of Technical Textiles, Ministry of Education, Donghua University, Shanghai 201620, China;2. Key Laboratory of Textile Science & Technology, Ministry of Education, Donghua University, Shanghai 201620, China;3. Zhejiang Provincial Key Laboratory of Novel Textiles Research and Development, Hangzhou 310001, China;4. Laboratory for Clothing Physiology and Ergonomics, National Engineering Laboratory for Modern Silk, Soochow University, Suzhou 215123, China;1. College of Communication Engineering, Jilin University, China;2. School of Computing and Information Systems, Athabasca University, Alberta, Canada;1. Physikalisch-Technische Bundesanstalt (PTB), Bundesallee 100, 38116 Braunschweig, Germany;2. Karlsruhe Institute of Technology (KIT), Kaiserstraße 12, 76131 Karlsruhe, Germany |
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| Abstract: | A novel zinc porphyrin (ZnTPP) derivative bearing an E-stilbazole chromophore in the axial position (ZnTPPL) was designed and prepared. Z-scan studies reveal that this complex exhibits improved nonlinear optical absorption and refraction in comparison with ZnTPP. In addition, the molecular structure of the complex was determined by X-ray diffraction study. |
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