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中温锌-钙系黑色磷化膜的耐蚀性能
引用本文:仝晓刚,陈琳,罗宏,赵蛟.中温锌-钙系黑色磷化膜的耐蚀性能[J].材料保护,2009,42(3).
作者姓名:仝晓刚  陈琳  罗宏  赵蛟
作者单位:四川理工学院材料与化学工程系,四川,自贡,643000
摘    要:黑色磷化膜的耐蚀性、微观结构和组成成分的系统研究相对较少.为了获得耐蚀性能较好的中温锌.钙系黑色磷化膜,从游离酸度(FA)、温度、时间等方面考察了黑色磷化膜的耐蚀性,通过扫描电镜、x射线衍射分析对膜层的性能进行了表征,测试了黑色磷化膜层的电化学极化性能.结果表明:当磷化液的游离酸度为4~10点,温度为60~75℃,时间为10~20 min时,黑色磷化膜层的耐腐蚀性较好;黑色磷化膜的腐蚀电位比Q235钢基体高0.2313 V.

关 键 词:黑色磷化  锌-钙系  中温  耐蚀性

Corrosion Resistance of Black Phosphating Coating of Zn-Ca System at Medium Temperature
TONG Xiao-gang,CHEN Lin,LUO Hong,ZHAO Jiao.Corrosion Resistance of Black Phosphating Coating of Zn-Ca System at Medium Temperature[J].Journal of Materials Protection,2009,42(3).
Authors:TONG Xiao-gang  CHEN Lin  LUO Hong  ZHAO Jiao
Affiliation:TONG Xiao-gang,CHEN Lin,LUO Hong,ZHAO Jiao (Depart-ment of Materials , Chemical Engineering,Sichuan University of Science , Engineering,Zigong 643000,China)
Abstract:Black phosphating coating with superior corrosion resistance was prepared from a Zn-Ca sys-tem at medium temperature. The factors such as free acidity,temperature and phosphating time on the corrosion resistance of the black phosphating coating were investigated. The microstrue-ture and phase composition of the black phosphating coating were analyzed by means of scanning electron microscopy (SEM) and X -ray diffraction (XRD). And the potential -time curve of the coating was measured as well. Results show th...
Keywords:black phosphating coating  Zn-Ca system  medium temperature  corrosion resistance  
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